ChemInform Abstract: A PEG1000-DAIL[CdCl3]-Toluene Temperature-Dependent Biphasic System that Regulates Homogeneously Catalyzed C-O Coupling of Organic Halides with Phenols and Alcohols under Ligand-Free Conditions.

ChemInform ◽  
2011 ◽  
Vol 42 (38) ◽  
pp. no-no
Author(s):  
Yu Lin Hu ◽  
Xiao Yun Ma ◽  
Ming Lu
Keyword(s):  
Biphasic System ◽  
Temperature Dependent ◽  
Organic Halides ◽  
Ligand Free

A PEG1000-DAIL[CdCl3]–toluene temperature-dependent biphasic system that regulates homogeneously catalyzed C–O coupling of organic halides with phenols and alcohols under ligand-free conditions

2011 ◽  
Vol 89 (4) ◽  
pp. 471-480 ◽  
Author(s):  
Yu Lin Hu ◽  
Xiao Yun Ma ◽  
Ming Lu
Keyword(s):  
Catalytic Activity ◽  
Catalytic System ◽  
Biphasic System ◽  
Temperature Dependent ◽  
Convenient Procedure ◽  
Organic Halides ◽  
Ligand Free

An efficient, experimentally simple, and convenient procedure for the C–O coupling of organic halides with phenols and alcohols in a PEG1000-DAIL[CdCl3]–toluene temperature-dependent biphasic system has been developed. The product can be easily isolated by a simple decantation, and the catalytic system can be recycled and reused without loss of catalytic activity.

Metal extraction with a short-chain imidazolium nitrate ionic liquid

2017 ◽  
Vol 53 (38) ◽  
pp. 5271-5274 ◽  
Author(s):  
Daphne Depuydt ◽  
Arne Van den Bossche ◽  
Wim Dehaen ◽  
Koen Binnemans
Keyword(s):  
Ionic Liquid ◽  
Transition Metals ◽  
Phase Behavior ◽  
Rare Earths ◽  
Permanent Magnets ◽  
Short Chain ◽  
Biphasic System ◽  
Metal Extraction ◽  
Temperature Dependent

The ionic liquid 1,3-dihexylimidazolium nitrate shows temperature-dependent phase behavior of the UCST-type. The biphasic system efficiently separates rare earths from 1st row transition metals, relevant for recycling of batteries (La/Ni) and permanent magnets (Sm/Co).

An organic-ligand-free thermochromic luminescent cuprous iodide trinuclear cluster: evidence for cluster centered emission and configuration distortion with temperature

2015 ◽  
Vol 51 (38) ◽  
pp. 8062-8065 ◽  
Author(s):  
Shi-Li Li ◽  
Fu-Qiang Zhang ◽  
Xian-Ming Zhang
Keyword(s):  
Organic Ligand ◽  
Structural Distortion ◽  
Temperature Dependent ◽  
Trinuclear Cluster ◽  
Ligand Free ◽  
Significant Temperature ◽  
Single Cluster

An organic-ligand-free cuprous iodide trinuclear cluster with significant temperature-dependent structural distortion shows thermochromic luminescence originating from a single cluster-centered triplet.

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