ChemInform Abstract: Green Oxidation Reactions by Polyoxometalate-Based Catalysts: From Molecular to Solid Catalysts

ChemInform ◽  
2010 ◽  
Vol 41 (49) ◽  
pp. no-no
Author(s):  
Noritaka Mizuno ◽  
Keigo Kamata ◽  
Kazuya Yamaguchi
Keyword(s):  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Green Oxidation ◽  
Green Oxidation Reactions

Green Oxidation Reactions by Polyoxometalate-Based Catalysts: From Molecular to Solid Catalysts

2010 ◽  
Vol 53 (13-14) ◽  
pp. 876-893 ◽  
Author(s):  
Noritaka Mizuno ◽  
Keigo Kamata ◽  
Kazuya Yamaguchi
Keyword(s):  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Green Oxidation ◽  
Green Oxidation Reactions

“Green” oxidation reactions—application to carbohydrate chemistry

2003 ◽  
Vol 5 (6) ◽  
pp. 679-681 ◽  
Author(s):  
Ewan C. Boyd ◽  
Ray V. H. Jones ◽  
Peter Quayle ◽  
Anita J. Waring
Keyword(s):  
Oxidation Reactions ◽  
Carbohydrate Chemistry ◽  
Green Oxidation ◽  
Green Oxidation Reactions

scholarly journals Green Oxidation Reactions of Drugs Catalyzed by Bio-inspired Complexes as an Efficient Methodology to Obtain New Active Molecules

10.5772/13524 ◽  
2011 ◽  
Author(s):  
Emerson Henrique de Faria ◽  
Gustavo Pimenta ◽  
Frederico Matias ◽  
Marcio Luis Andrade e Silva ◽  
Ademar Alves da Silva Filho ◽  
...  
Keyword(s):  
Oxidation Reactions ◽  
Green Oxidation ◽  
Green Oxidation Reactions

Pillared Clay Catalysts in Green Oxidation Reactions

2010 ◽  
pp. 301-318 ◽  
Author(s):  
M.A. Vicente ◽  
R. Trujillano ◽  
K.J. Ciuffi ◽  
E.J. Nassar ◽  
S.A. Korili ◽  
...  
Keyword(s):  
Pillared Clay ◽  
Oxidation Reactions ◽  
Green Oxidation ◽  
Clay Catalysts ◽  
Green Oxidation Reactions

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

scholarly journals General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis

2018 ◽  
Author(s):  
Sabine Valange ◽  
Jacques Védrine
Keyword(s):  
Heterogeneous Catalysis ◽  
Review Paper ◽  
Raw Materials ◽  
Short Review ◽  
Industrial Applications ◽  
Oxidation Reactions ◽  
Total Oxidation ◽  
Solid Catalysts ◽  
Solid Media ◽  
Combined Use

In this short review paper we have assembled the main characteristics of partial oxidation reactions (oxidative dehydrogenation and selective oxidation to olefins or oxygenates, as aldehydes and carboxylic acids and nitriles), as well as total oxidation, particularly for depollution, environmental issues and wastewater treatments. Both gas-solid and liquid-solid media have been considered with recent and representative examples within these fields. We have also discussed about their potential and prospective industrial applications. Particular attention has been brought to new raw materials stemming from biomass and to liquid-solid catalysts cases. This review paper also summarizes the progresses made in the use of unconventional activation methods for performing oxidation reactions, highlighting the synergy of these technologies with heterogeneous catalysis. Focus has been centered on usual catalysts activation methods but also on less usual ones, such as the use of ultrasounds, microwaves, grinding (mechanochemistry) and photo-activated processes, as well as their combined use.

Cesium‐Exchanged Lacunar Keggin Heteropolyacid Salts: Efficient Solid Catalysts for the Green Oxidation of Terpenic Alcohols with Hydrogen Peroxide

2020 ◽  
Vol 5 (6) ◽  
pp. 1976-1986 ◽  
Author(s):  
Daniel Carreira Batalha ◽  
Sukarno Olavo Ferreira ◽  
Rene Chagas Silva ◽  
Márcio José Silva
Keyword(s):  
Hydrogen Peroxide ◽  
Solid Catalysts ◽  
Green Oxidation ◽  
Terpenic Alcohols ◽  
Heteropolyacid Salts

scholarly journals General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 483 ◽  
Author(s):  
Sabine Valange ◽  
Jacques Védrine
Keyword(s):  
Heterogeneous Catalysis ◽  
Review Paper ◽  
Raw Materials ◽  
Industrial Applications ◽  
Oxidation Reactions ◽  
Total Oxidation ◽  
Solid Catalysts ◽  
Solid Media ◽  
Combined Use ◽  
Made In

In this review paper, we have assembled the main characteristics of partial oxidation reactions (oxidative dehydrogenation and selective oxidation to olefins or oxygenates, as aldehydes and carboxylic acids and nitriles), as well as total oxidation, particularly for depollution, environmental issues and wastewater treatments. Both gas–solid and liquid–solid media have been considered with recent and representative examples within these fields. We have also discussed about their potential and prospective industrial applications. Particular attention has been brought to new raw materials stemming from biomass, as well as to liquid–solid catalysts cases. This review paper also summarizes the progresses made in the use of unconventional activation methods for performing oxidation reactions, highlighting the synergy of these technologies with heterogeneous catalysis. Focus has been centered on both usual catalysts activation methods and less usual ones, such as the use of ultrasounds, microwaves, grinding (mechanochemistry) and photo-activated processes, as well as their combined use.

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