ChemInform Abstract: Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols.

ChemInform ◽  
2009 ◽  
Vol 40 (49) ◽  
Author(s):  
Yasushi Obora ◽  
Shintaro Hatanaka ◽  
Yasutaka Ishii
Keyword(s):  
Coupling Reaction ◽  
Primary Alcohols ◽  
Homoallylic Alcohols

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols

2009 ◽  
Vol 11 (15) ◽  
pp. 3510-3513 ◽  
Author(s):  
Yasushi Obora ◽  
Shintaro Hatanaka ◽  
Yasutaka Ishii
Keyword(s):  
Coupling Reaction ◽  
Primary Alcohols ◽  
Homoallylic Alcohols

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 2-Alkynes Leading to Hydroacylation Products

2010 ◽  
Vol 16 (6) ◽  
pp. 1883-1888 ◽  
Author(s):  
Shintaro Hatanaka ◽  
Yasushi Obora ◽  
Yasutaka Ishii
Keyword(s):  
Coupling Reaction ◽  
Primary Alcohols

scholarly journals Alkynes as Allylmetal Equivalents in Redox-Triggered C–C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C–H Oxidative Addition

2014 ◽  
Vol 136 (34) ◽  
pp. 11902-11905 ◽  
Author(s):  
Boyoung Y. Park ◽  
Khoa D. Nguyen ◽  
Mani Raj Chaulagain ◽  
Venukrishnan Komanduri ◽  
Michael J. Krische
Keyword(s):  
Oxidative Addition ◽  
Primary Alcohols ◽  
Homoallylic Alcohols

scholarly journals Carboxylated Chitosan Nanocrystals: Novel Synthetic Route and Application as Superior Support for Gold-Catalyzed Reactions

2020 ◽  
Author(s):  
Tony Jin ◽  
Davis Kurdyla ◽  
Sabahudin Hrapovic ◽  
Alfred Leung ◽  
Sophie Régnier ◽  
...  
Keyword(s):  
Imaging Techniques ◽  
Coupling Reaction ◽  
Primary Alcohols ◽  
X Ray Diffraction ◽  
Catalytic Activities ◽  
Glycosidic Bonds ◽  
Carboxylate Groups ◽  
Transmission Electron ◽  
Nitrophenol Reduction ◽  
Catalyzed Reactions

<p>Chitin nanocrystals (ChNCs) were prepared by partial cleavage of glycosidic bonds in chitin with concurrent oxidation of chitin C6 primary alcohols to produce carboxylate groups on the surface of the ChNCs. Following alkaline deacetylation of the ChNCs in the presence of NaBH<sub>4</sub> to inhibit “end-peeling” afforded chitosan nanocrystals (ChsNCs) with a degree of deacetylation (DDA) >80%. Transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier-transform Infrared (FTIR) spectroscopy were used to determine the morphology and composition of these carboxylated ChNCs and ChsNCs. Subsequently, two methods were used to deposit Au onto the nanocrystals, and the catalytic activities of the resulting biomass-based nanocatalysts were tested for the 4-nitrophenol reduction and the aldehyde-amine-alkyne (A<sup>3</sup>) coupling reaction. In particular, Au nanoparticles over ChsNCs featured the highest turnover frequency value for the 4-nitrophenol reduction reported to date. Spectroscopic and imaging techniques confirmed the importance of controlling precisely the redox state of Au as it is being deposited to afford highly disperse active site on the bio-nano-support. </p>

ChemInform Abstract: Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 2-Alkynes Leading to Hydroacylation Products.

ChemInform ◽  
2010 ◽  
Vol 41 (24) ◽  
pp. no-no
Author(s):  
Shintaro Hatanaka ◽  
Yasushi Obora ◽  
Yasutaka Ishii
Keyword(s):  
Coupling Reaction ◽  
Primary Alcohols

scholarly journals Acetals from primary alcohols with the use of tridentate proton responsive phosphinepyridonate iridium catalysts

RSC Advances ◽  
2016 ◽  
Vol 6 (102) ◽  
pp. 100554-100558 ◽  
Author(s):  
A. R. Sahoo ◽  
F. Jiang ◽  
C. Bruneau ◽  
G. V. M. Sharma ◽  
S. Suresh ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Primary Alcohols ◽  
Iridium Catalysts ◽  
Metallic Precursor ◽  
Dehydrogenative Coupling

The association of the new phosphinepyridonate ligands along with an iridium metallic precursor resulted in the selective acetalization of various primary alcohols via a formal dehydrogenative coupling reaction.

Ni-Catalyzed Formal Carbonyl-Ene Reaction of Terminal Alkenes via Carbon Dioxide Insertion

Synlett ◽  
2017 ◽  
Vol 29 (06) ◽  
pp. 742-746 ◽  
Author(s):  
Masanari Kimura ◽  
Yasuyuki Mori ◽  
Chieko Shigeno ◽  
Ying Luo ◽  
Bun Chan ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Coupling Reaction ◽  
Ene Reaction ◽  
Homoallylic Alcohols ◽  
Terminal Alkenes ◽  
Multicomponent Coupling

Nickel catalyzes the multicomponent coupling reaction of terminal alkenes, carbon dioxide, and organoaluminum reagents, leading to the synthesis of homoallylic alcohols in moderate-to-good yields with excellent regio- and stereoselectivities.

Synthesis of 2-Hydroxymethyl Ketones by Ruthenium Hydride-Catalyzed Cross-Coupling Reaction of α,β-Unsaturated Aldehydes with Primary Alcohols

2010 ◽  
Vol 12 (1) ◽  
pp. 1-3 ◽  
Author(s):  
Aurélien Denichoux ◽  
Takahide Fukuyama ◽  
Takashi Doi ◽  
Jiro Horiguchi ◽  
Ilhyong Ryu
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Primary Alcohols ◽  
Ruthenium Hydride ◽  
Unsaturated Aldehydes ◽  
Cross Coupling Reaction

ChemInform Abstract: Alkynes as Allylmetal Equivalents in Redox-Triggered C-C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C-H Oxidative Addition.

ChemInform ◽  
2015 ◽  
Vol 46 (11) ◽  
pp. no-no
Author(s):  
Boyoung Y. Park ◽  
Khoa D. Nguyen ◽  
Mani Raj Chaulagain ◽  
Venukrishnan Komanduri ◽  
Michael J. Krische
Keyword(s):  
Oxidative Addition ◽  
Primary Alcohols ◽  
Homoallylic Alcohols
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