Nitrogen Ligands: The Transition Metal Catalyzed Reaction of Aryl Halides with Olefins (Mizoroki—Heck), Phenylboronic Acid (Suzuki Coupling) and Buchwald—Hartwig Amination, New Catalysts and Effect of Cocatalysts—Aryl Halide Activation. Part 1.

ChemInform ◽  
2006 ◽  
Vol 37 (2) ◽  
Author(s):  
Suresh Iyer ◽  
Girish M. Kulkarni ◽  
C. Ramesh ◽  
Aruna K. Sattar
Keyword(s):  
Transition Metal ◽  
Aryl Halide ◽  
Phenylboronic Acid ◽  
Suzuki Coupling ◽  
Aryl Halides ◽  
Nitrogen Ligands ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition-Metal-Catalyzed Hydroxylation Reaction of Aryl Halide for the Synthesis of Phenols

Synlett ◽  
2021 ◽  
Author(s):  
D. Xue ◽  
L. Yang
Keyword(s):  
Transition Metal ◽  
Aryl Halide ◽  
High Reactivity ◽  
Aryl Halides ◽  
Biologically Active ◽  
Nickel Catalysis ◽  
Aryl Chlorides ◽  
Aryl Bromides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

AbstractPhenols are important components of pharmaceuticals, biologically active natural products, and materials. Here, we briefly discuss recent advances in catalytic hydroxylation reactions for the synthesis of phenols, with particular attention to our recent work. H2O is proved to be an efficient hydroxide reagent in converting (hetero)aryl halides into the corresponding phenols under synergistic organophotoredox and nickel catalysis. Aryl bromides as well as less reactive aryl chlorides show high reactivity in this catalytic system. This methodology can be applied to the efficient synthesis of diverse phenols and allows the hydroxylation of multifunctional pharmaceutically relevant aryl halides.1 Introduction2 Representative Methods for Transition-Metal-Catalyzed Hydroxylation of (Hetero)Aryl Halides3 Organophotoredox/Ni Dual Catalytic Hydroxylation of Aryl Halides with Water4 Summary and Outlook

Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates

2015 ◽  
Vol 5 (10) ◽  
pp. 4663-4702 ◽  
Author(s):  
Prashant Gautam ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Carbon Monoxide ◽  
Transition Metal ◽  
Organic Synthesis ◽  
Aryl Halides ◽  
Industrial Synthesis ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Important Position

Transition metal catalyzed carbonylation reactions using carbon monoxide as the C-1 source have occupied an all important position in catalysis which is subsequently related to organic synthesis and industrial synthesis of molecules.

Regiocontrolled palladium-catalyzed and copper-mediated C–H bond functionalization of protectedl-histidine

2014 ◽  
Vol 12 (23) ◽  
pp. 3792-3796 ◽  
Author(s):  
Amit Mahindra ◽  
Rahul Jain
Keyword(s):  
Transition Metal ◽  
Aryl Halides ◽  
Bond Functionalization ◽  
Palladium Catalyzed ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Coupling Partner

Regiocontrolled transition-metal-catalyzed C–H bond arylation of protectedl-histidine with aryl halides as the coupling partner is reported.

Arylsilylation of aryl halides using the magnetically recyclable bimetallic Pd–Pt–Fe3O4 catalyst

2018 ◽  
Vol 54 (28) ◽  
pp. 3492-3495 ◽  
Author(s):  
Jisun Jang ◽  
Sangmoon Byun ◽  
B. Moon Kim ◽  
Sunwoo Lee
Keyword(s):  
Transition Metal ◽  
Aryl Halides ◽  
Catalytic Systems ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition metal-catalyzed silylations have typically involved the use of heterogeneous recyclable catalytic systems.

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