Oxidative Solid-State Crosslinking of Polymer Precursors to Pattern Intrinsically Conducting Polymers

ChemInform ◽  
2005 ◽  
Vol 36 (1) ◽  
Author(s):  
Sung-Yeon Jang ◽  
Manuel Marquez ◽  
Gregory A. Sotzing
1985 ◽  
Vol 46 (9) ◽  
pp. 1595-1601 ◽  
Author(s):  
F. Devreux ◽  
G. Bidan ◽  
A.A. Syed ◽  
C. Tsintavis

1983 ◽  
Vol 44 (C3) ◽  
pp. C3-567-C3-572 ◽  
Author(s):  
F. Bénière ◽  
D. Boils ◽  
H. Cánepa ◽  
J. Franco ◽  
A. Le Corre ◽  
...  

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 841
Author(s):  
Sung Jin Park ◽  
Myong Euy Lee ◽  
Hyeon Mo Cho ◽  
Sangdeok Shim

The sol–gel polymerization of alkoxysilanes is a convenient and widely used method for the synthesis of silicon polymers and silicon–organic composites. The development of new sol–gel precursors is very important for obtaining new types of sol–gel products. New condensation polymer precursors containing consecutive silicon atoms—decaisopropoxycyclopentasilane (CPS) and dodecaethoxyneopentasilane (NPS)—were synthesized for the preparation of polysilane–polysiloxane material. The CPS and NPS xerogels were prepared by the sol–gel polymerization of CPS and NPS under three reaction conditions (acidic, basic and neutral). The CPS and NPS xerogels were characterized using N2 physisorption measurements (Brunauer–Emmett–Teller; BET and Brunauer-Joyner-Halenda; BJH), solid-state CP/MAS (cross-polarization/magic angle spinning) NMRs (nuclear magnetic resonances), TEM, and SEM. Their porosity and morphology were strongly affected by the structure of the precursors, and partial oxidative cleavage of Si-Si bonds occurred during the sol–gel process. The new condensation polymer precursors are expected to expand the choice of approaches for new polysilane–polysiloxane.


2008 ◽  
Vol 20 (6) ◽  
pp. 1175-1178 ◽  
Author(s):  
Jayesh G. Bokria ◽  
Arvind Kumar ◽  
Venkataramanan Seshadri ◽  
Arlene Tran ◽  
Gregory A. Sotzing

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