Palladium-Catalyzed Cyanation of Aryl Halides: Recent Developments and Perspectives

ChemInform ◽  
2003 ◽  
Vol 34 (48) ◽  
Author(s):  
Mark Sundermeier ◽  
Alexander Zapf ◽  
Matthias Beller
Keyword(s):  
Aryl Halides ◽  
Recent Developments ◽  
Palladium Catalyzed

Palladium-Catalyzed Cyanation of Aryl Halides: Recent Developments and Perspectives

2003 ◽  
Vol 2003 (19) ◽  
pp. 3513-3526 ◽  
Author(s):  
Mark Sundermeier ◽  
Alexander Zapf ◽  
Matthias Beller
Keyword(s):  
Aryl Halides ◽  
Recent Developments ◽  
Palladium Catalyzed

Recent developments and perspectives in palladium-catalyzed cyanation of aryl halides: synthesis of benzonitriles

2011 ◽  
Vol 40 (10) ◽  
pp. 5049 ◽  
Author(s):  
Pazhamalai Anbarasan ◽  
Thomas Schareina ◽  
Matthias Beller
Keyword(s):  
Aryl Halides ◽  
Recent Developments ◽  
Palladium Catalyzed

scholarly journals Recent advances and prospects in the palladium-catalyzed cyanation of aryl halides

RSC Advances ◽  
2020 ◽  
Vol 10 (56) ◽  
pp. 33683-33699
Author(s):  
Mohan Neetha ◽  
C. M. A. Afsina ◽  
Thaipparambil Aneeja ◽  
Gopinathan Anilkumar
Keyword(s):  
Organic Chemistry ◽  
Aryl Halides ◽  
Synthetic Organic Chemistry ◽  
Recent Advances ◽  
Aryl Nitriles ◽  
Recent Developments ◽  
Palladium Catalyzed

Aryl nitriles are an inevitable part of synthetic organic chemistry. This review summarizes the recent developments in palladium-catalyzed cyanation of aryl halides from 2012–2020.

Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles

Synthesis ◽  
2020 ◽  
Author(s):  
Lili Shi ◽  
Junkai Fu ◽  
Shuangqiu Gao ◽  
Le Chang ◽  
Binglin Wang
Keyword(s):  
Heck Reaction ◽  
Alkyl Radicals ◽  
Type Reaction ◽  
The Past ◽  
Alkyl Electrophiles ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Initial Work ◽  
Activated Olefins ◽  
Pseudo Halides

AbstractThe Mizoroki–Heck reaction is considered as one of the most ingenious and widely used methods for constructing C–C bonds. This reaction mainly focuses on activated olefins (styrenes, acrylates, or vinyl ethers) and aryl/vinyl (pseudo) halides. In comparison, the studies on unactivated alkenes and alkyl electrophiles are far less due to the low reactivity, poor selectivity, as well as competitive β-H elimination. In the past years, a growing interest has thus been devoted and significant breakthroughs have been achieved in the employment of unactivated alkenes and alkyl electrophiles as the reaction components, and this type of coupling is called as Heck-type or Heck-like reaction, which distinguishes from the traditional Heck reaction. Herein, we give a brief summary on Heck-type reaction between unactivated alkenes and alkyl electrophlies, covering its initial work, recent advancements, and mechanistic discussions.1 Introduction2 Intramolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles2.1 Cobalt-Catalyzed Intramolecular Heck-Type Reaction2.2 Palladium-Catalyzed Intramolecular Heck-Type Reaction2.3 Nickel-Catalyzed Intramolecular Heck-Type Reaction2.4 Photocatalysis and Multimetallic Protocol for Intramolecular Heck-Type Reaction3 Intermolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles3.1 Electrophilic Trifluoromethylating Reagent as Reaction Partners3.2 Alkyl Electrophiles as Reaction Partners4 Oxidative Heck-Type Reaction of Unactivated Alkenes and Alkyl Radicals5 Conclusions and Outlook

Palladium Catalyzed Cascade Azidation/Carbonylation of Aryl Halides with Sodium Azide for the Synthesis of Amides

2021 ◽  
Author(s):  
Zhuang Qi ◽  
Shan‐Shan Li ◽  
Lin Li ◽  
Qi Qin ◽  
Li‐Miao Yang ◽  
...  
Keyword(s):  
Sodium Azide ◽  
Aryl Halides ◽  
Palladium Catalyzed

Palladium-Catalyzed Olefinations of Aryl Halides (Heck Reaction) and Related Transformations

ChemInform ◽  
2005 ◽  
Vol 36 (44) ◽  
Author(s):  
Matthias Beller ◽  
Alexander Zapf ◽  
Thomas H. Riermeier
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed
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