Palladium-Catalyzed Olefinations of Aryl Halides (Heck Reaction) and Related Transformations

ChemInform ◽  
2005 ◽  
Vol 36 (44) ◽  
Author(s):  
Matthias Beller ◽  
Alexander Zapf ◽  
Thomas H. Riermeier
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides.

ChemInform ◽  
2015 ◽  
Vol 46 (38) ◽  
pp. no-no
Author(s):  
Guizhou Yue ◽  
Kaining Lei ◽  
Hajime Hirao ◽  
Jianrong Steve Zhou
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

Development of a General Palladium-Catalyzed Carbonylative Heck Reaction of Aryl Halides

2010 ◽  
Vol 132 (41) ◽  
pp. 14596-14602 ◽  
Author(s):  
Xiao-Feng Wu ◽  
Helfried Neumann ◽  
Anke Spannenberg ◽  
Thomas Schulz ◽  
Haijun Jiao ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

Activation of CX (=Cl, Br) bond in aryl halides toward the palladium-catalyzed Heck reaction using 2,6-bis(diphenylphosphino)pyridine

2013 ◽  
Vol 366 ◽  
pp. 30-35 ◽  
Author(s):  
Ali Ataei ◽  
Shirin Nadri ◽  
Ezzat Rafiee ◽  
Sirous Jamali ◽  
Mohammad Joshaghani
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

Palladium-Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides

2015 ◽  
Vol 127 (22) ◽  
pp. 6631-6635 ◽  
Author(s):  
Guizhou Yue ◽  
Kaining Lei ◽  
Hajime Hirao ◽  
Jianrong Steve Zhou
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

ChemInform Abstract: Development of a General Palladium-Catalyzed Carbonylative Heck Reaction of Aryl Halides.

ChemInform ◽  
2011 ◽  
Vol 42 (10) ◽  
pp. no-no
Author(s):  
Xiao-Feng Wu ◽  
Helfried Neumann ◽  
Anke Spannenberg ◽  
Thomas Schulz ◽  
Haijun Jiao ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

Palladium-Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides

2015 ◽  
Vol 54 (22) ◽  
pp. 6531-6535 ◽  
Author(s):  
Guizhou Yue ◽  
Kaining Lei ◽  
Hajime Hirao ◽  
Jianrong Steve Zhou
Keyword(s):  
Heck Reaction ◽  
Aryl Halides ◽  
Palladium Catalyzed

Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles

Synthesis ◽  
2020 ◽  
Author(s):  
Lili Shi ◽  
Junkai Fu ◽  
Shuangqiu Gao ◽  
Le Chang ◽  
Binglin Wang
Keyword(s):  
Heck Reaction ◽  
Alkyl Radicals ◽  
Type Reaction ◽  
The Past ◽  
Alkyl Electrophiles ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Initial Work ◽  
Activated Olefins ◽  
Pseudo Halides

AbstractThe Mizoroki–Heck reaction is considered as one of the most ingenious and widely used methods for constructing C–C bonds. This reaction mainly focuses on activated olefins (styrenes, acrylates, or vinyl ethers) and aryl/vinyl (pseudo) halides. In comparison, the studies on unactivated alkenes and alkyl electrophiles are far less due to the low reactivity, poor selectivity, as well as competitive β-H elimination. In the past years, a growing interest has thus been devoted and significant breakthroughs have been achieved in the employment of unactivated alkenes and alkyl electrophiles as the reaction components, and this type of coupling is called as Heck-type or Heck-like reaction, which distinguishes from the traditional Heck reaction. Herein, we give a brief summary on Heck-type reaction between unactivated alkenes and alkyl electrophlies, covering its initial work, recent advancements, and mechanistic discussions.1 Introduction2 Intramolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles2.1 Cobalt-Catalyzed Intramolecular Heck-Type Reaction2.2 Palladium-Catalyzed Intramolecular Heck-Type Reaction2.3 Nickel-Catalyzed Intramolecular Heck-Type Reaction2.4 Photocatalysis and Multimetallic Protocol for Intramolecular Heck-Type Reaction3 Intermolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles3.1 Electrophilic Trifluoromethylating Reagent as Reaction Partners3.2 Alkyl Electrophiles as Reaction Partners4 Oxidative Heck-Type Reaction of Unactivated Alkenes and Alkyl Radicals5 Conclusions and Outlook

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