ChemInform Abstract: Crystal Structure of a Lithium Chloride Cubane Cluster Solvated by Diethyl Ether.

ChemInform ◽  
2010 ◽  
Vol 32 (36) ◽  
pp. no-no
Author(s):  
Norbert W. Mitzel ◽  
Christian Lustig
Keyword(s):  
Crystal Structure ◽  
Diethyl Ether ◽  
Lithium Chloride ◽  
Cubane Cluster

Notizen: Crystal Structure of a Lithium Chloride Cubane Cluster Solvated by Diethyl Ether

2001 ◽  
Vol 56 (4-5) ◽  
pp. 443-445 ◽  
Author(s):  
Norbert W. Mitzel ◽  
Christian Lustig
Keyword(s):  
Crystal Structure ◽  
Diethyl Ether ◽  
Lithium Chloride ◽  
Cubane Cluster

The thermally highly unstable diethyl ether solvate of lithium chloride was crystallised and its crystal structure determined. It consists of a cubic cluster of the composition Li4Cl4 with each of the four Li atoms coordinated to a molecule of diethyl ether.

A 35-year-old mystery solved: a facile synthetic route and structural confirmation of tetrachlorobis(diethyl ether)tungsten(IV)

2021 ◽  
Vol 77 (4) ◽  
Author(s):  
Thomas E. Shaw ◽  
Alfred P. Sattelberger ◽  
Titel Jurca
Keyword(s):  
Crystal Structure ◽  
Diethyl Ether ◽  
Thermal Instability ◽  
Room Temperature ◽  
Surface Characteristics ◽  
Hirshfeld Surface ◽  
Asymmetric Unit ◽  
Synthetic Route ◽  
X Ray ◽  
Elemental Analyses

The true identity of the diethyl ether adduct of tungsten(IV) chloride, WCl4(Et2O) x , has been in doubt since 1985. Initially postulated as the bis-adduct, WCl4(Et2O)2, questions arose when elemental analyses were more in line with a mono-ether adduct, viz. WCl4(Et2O). It was proposed that this was due to the thermal instability of the bis-adduct. Here, we report the room-temperature X-ray crystal structure and Hirshfeld surface characteristics of trans-tetrachloridobis(diethyl ether)tungsten(IV), trans-WCl4(Et2O)2 or trans-[WCl4(C4H10O)2]. The compound crystallizes, with half of the molecule in the asymmetric unit, in the centrosymmetric space group P21/n. The W—O distance is 2.070 (2) Å, while the W—Cl distances are 2.3586 (10) and 2.3554 (10) Å.

Rare example of a monomeric aryllithium complex. X-ray crystal structure of (2,4,6-triphenylphenyl)lithium-bis(diethyl ether)

1992 ◽  
Vol 11 (11) ◽  
pp. 3907-3910 ◽  
Author(s):  
Gregory S. Girolami ◽  
Matthew E. Riehl ◽  
Kenneth S. Suslick ◽  
Scott R. Wilson
Keyword(s):  
Crystal Structure ◽  
Diethyl Ether ◽  
X Ray

ChemInform Abstract: Crystal Structure of the η3-Allyllithium Compound [1,3-Diphenylallyllithium-Diethyl Ether]

1986 ◽  
Vol 17 (18) ◽  
Author(s):  
G. BOCHE ◽  
H. ETZRODT ◽  
M. MARSCH ◽  
W. MASSA ◽  
G. BAUM ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Diethyl Ether

Crystal Structure of the Monohydrates of Lithium Chloride and Lithium Bromide.

ChemInform ◽  
2003 ◽  
Vol 34 (19) ◽  
Author(s):  
Andreas Hoennerscheid ◽  
Juergen Nuss ◽  
Claus Muehle ◽  
Martin Jansen
Keyword(s):  
Crystal Structure ◽  
Lithium Chloride ◽  
Lithium Bromide

Synthesis and crystal structure of a supramolecular adduct of the cubane cluster [CIPdMo3Se4(H2O)7Cl2]+ with macrocyclic cavitand cucurbituril

2000 ◽  
Vol 49 (11) ◽  
pp. 1877-1881 ◽  
Author(s):  
M. N. Sokolov ◽  
D. N. Dybtsev ◽  
A. V. Virovets ◽  
K. Hegetschweiler ◽  
V. P. Fedin
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Supramolecular Adduct ◽  
Cubane Cluster
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