ChemInform Abstract: Rhodium-Catalyzed Coupling Reaction of 2-Vinylquinolines with Terminal Alkenes via C-H Bond Activation.

ChemInform ◽  
2010 ◽  
Vol 29 (10) ◽  
pp. no-no
Author(s):  
Y.-G. LIM ◽  
J.-B. KANG
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Terminal Alkenes

Nickel-Catalyzed Hydrosilylation of Terminal Alkenes with Primary Silanes via Electrophilic Silicon–Hydrogen Bond Activation

2021 ◽  
Vol 23 (4) ◽  
pp. 1434-1439
Author(s):  
Xiaoyu Wu ◽  
Guangni Ding ◽  
Wenkui Lu ◽  
Liqun Yang ◽  
Jingyang Wang ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Bond Activation ◽  
Terminal Alkenes

ChemInform Abstract: Direct Dehydroxylative Coupling Reaction of Alcohols with Organosilanes Through Si-X Bond Activation by Halogen Bonding.

ChemInform ◽  
2015 ◽  
Vol 46 (44) ◽  
pp. no-no
Author(s):  
Masato Saito ◽  
Nobuya Tsuji ◽  
Yusuke Kobayashi ◽  
Yoshiji Takemoto
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Halogen Bonding

Palladium(0)-catalyzed cyclopropanation of benzyl bromides via C(sp3)–H bond activation

2014 ◽  
Vol 50 (28) ◽  
pp. 3692-3694 ◽  
Author(s):  
Jiangang Mao ◽  
Shuo-Qing Zhang ◽  
Bing-Feng Shi ◽  
Weiliang Bao
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Type Coupling

A novel Pd(0)-catalyzed domino cyclopropanation reaction was established. The process involves a Heck-type coupling reaction and a C(sp3)–H activation.

The oxidative coupling between benzaldehyde derivatives and phenylacetylene catalyzed by rhodium complexes via C-H bond activation

2020 ◽  
Vol 26 (1) ◽  
pp. 20-25
Author(s):  
Xinyi Zhao ◽  
Hongge Jia ◽  
Qingji Wang ◽  
Heming Song ◽  
Yanan Tang ◽  
...  
Keyword(s):  
Amino Acid ◽  
Oxidative Coupling ◽  
Bond Activation ◽  
Coupling Reaction ◽  
Reaction Yield ◽  
Rhodium Complexes ◽  
Electronic Effects ◽  
Oxidative Coupling Reaction ◽  
Excellent Activity ◽  
Benzaldehyde Derivatives

AbstractThis paper reports the use of rhodium (Rh) catalysts for the oxidative coupling reaction between phenylacetylene and benzaldehyde derivatives via C-H bond activation. These reactions were catalyzed by Rh(l-amino acid)(cod) (the l-amino acid is l-phenylalanine, l-valine or l-proline; cod is 1,5-cyclooctadiene) to obtain chromones in 12.7–88.3% yield. These new Rh catalysts have excellent activity for the coupling reaction between phenylacetylene and different benzaldehyde derivatives. It was found that the electronic effects of the benzaldehyde derivative substituent affected the reaction yield, which is in accordance with the proposed mechanism.

CH Bond Activation of Unsaturated Hydrocarbons by a Niobium Methyl Cyclopropyl Precursor. Cyclopropyl Ring Opening and Alkyne Coupling Reaction

2016 ◽  
Vol 36 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Pascal Oulié ◽  
Chiara Dinoi ◽  
Chen Li ◽  
Alix Sournia-Saquet ◽  
Kane Jacob ◽  
...  
Keyword(s):  
Ring Opening ◽  
Bond Activation ◽  
Coupling Reaction ◽  
Unsaturated Hydrocarbons ◽  
Ch Bond Activation ◽  
Alkyne Coupling

Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones

2016 ◽  
Vol 3 (2) ◽  
pp. 259-267 ◽  
Author(s):  
Jiawen Li ◽  
Guiping Qin ◽  
Yang Liu ◽  
Hanmin Huang
Keyword(s):  
Bond Activation ◽  
Coupling Reaction ◽  
Cross Coupling

Palladium-catalysed cross-coupling of aminals with N-sulfonyl hydrazones has been established via C–N bond activation under base-free conditions.

Sign in / Sign up

Export Citation Format

Share Document