ChemInform Abstract: Reductive Cleavage of C-S Bond by Samarium Diiodide: A Novel Method for the Synthesis of Disulfides and Thiolesters.

ChemInform ◽  
1995 ◽  
Vol 26 (16) ◽  
pp. no-no
Author(s):  
X. JIA ◽  
Y. ZHANG ◽  
X. ZHOU
Keyword(s):  
Reductive Cleavage ◽  
Samarium Diiodide ◽  
Novel Method

Samarium Diiodide Induced Reductive Cleavage of the Se–Se Bond in Diselenides: A Novel Synthesis of 3-Substituted-Imidazolidine-2-One-1-Carbonyl Selenoesters

2002 ◽  
Vol 2002 (4) ◽  
pp. 168-169 ◽  
Author(s):  
Weike Su ◽  
Ning Gao ◽  
Yongmin Zhang
Keyword(s):  
Reductive Cleavage ◽  
Samarium Diiodide ◽  
Novel Synthesis ◽  
Neutral Conditions ◽  
Substituted 1

The reduction of diselenides by samarium diiodide led to samarium selenolates (RSeSmI2). These species reacted with 3-substituted-1-chlorocarbonyl-imidazolidin-2-ones to give the corresponding selenoesters in good yields under mild and neutral conditions.

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