ChemInform Abstract: Kinetics of the Oxidation of Heterocyclic Secondary Alcohols by N- Chloro-r-2,c-6-diphenyl-t-3-methylpiperidin-4-one (NCP) in Perchloric Acid Medium

ChemInform ◽  
2010 ◽  
Vol 25 (49) ◽  
pp. no-no
Author(s):  
K. SELVARAJ ◽  
V. VENKATESWARAN ◽  
K. RAMARAJAN
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Secondary Alcohols ◽  
Kinetics Of

Kinetics of oxidation of methanol and mono-deutero-methanol by chromium(VI) in perchloric acid medium

Tetrahedron ◽  
1985 ◽  
Vol 41 (1) ◽  
pp. 205-208 ◽  
Author(s):  
Kalyan Kali Sengupta ◽  
Tapashi Samanta ◽  
Samarendra Nath Basu
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Kinetics Of Oxidation ◽  
Chromium Vi ◽  
Oxidation Of Methanol ◽  
Kinetics Of

scholarly journals Kinetics and Mechanism of Oxidation of Isoleucine byN-Bromophthalimide in Aqueous Perchloric Acid Medium

2011 ◽  
Vol 8 (4) ◽  
pp. 1728-1733 ◽  
Author(s):  
N. M. I. Alhaji ◽  
S. Sofiya Lawrence Mary
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Reaction Rate ◽  
Activation Parameters ◽  
Halide Ions ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Hypobromous Acid ◽  
Different Temperatures ◽  
Kinetics Of

The kinetics of oxidation of isoleucine withN-bromophthalimide has been studied in perchloric acid medium potentiometrically. The reaction is of first order each in [NBP] and [amino acid] and negative fractional order in [H+]. The rate is decreased by the addition of phthalimide. A decrease in the dielectric constant of the medium increases the rate. Addition of halide ions or acrylonitrile has no effect on the kinetics. Similarly, variation of ionic strength of the medium does not affect the reaction rate. The reaction rate has been determined at different temperatures and activation parameters have been calculated. A suitable mechanism involving hypobromous acid as reactive species has been proposed.

scholarly journals Micellar and Polymer Catalysis in the Kinetics of Oxidation of L-lysine by Permanganate Ion in Perchloric Acid Medium

2021 ◽  
Vol 75 ◽  
Author(s):  
Mohammed Hassan ◽  
Mohammad Al-Dhoun ◽  
Yazan Batineh ◽  
Ahmad A. Najjar ◽  
Adnan Dahadha ◽  
...  
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Permanganate Ion

Kinetics of oxidation of ethanol by potassium permanganate in perchloric acid medium

1989 ◽  
Vol 38 (2) ◽  
pp. 313-318 ◽  
Author(s):  
Kalyan Kali Sen Gupta ◽  
Mrityunjoy Adhikari ◽  
Shipra Sen Gupta
Keyword(s):  
Acid Medium ◽  
Potassium Permanganate ◽  
Perchloric Acid ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Oxidation Of Ethanol
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