Mechanistic studies with positive iodine: Kinetics of oxidation of thiocyanate ion by iodine monochloride and aqueous iodine in perchloric acid medium

1989 ◽  
Vol 21 (8) ◽  
pp. 621-633
Author(s):  
B. Thimme Gowda ◽  
J. Ishwara Bhat
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Iodine Monochloride ◽  
Mechanistic Studies ◽  
Kinetics Of Oxidation ◽  
Thiocyanate Ion ◽  
Kinetics Of

Kinetics of oxidation of methanol and mono-deutero-methanol by chromium(VI) in perchloric acid medium

Tetrahedron ◽  
1985 ◽  
Vol 41 (1) ◽  
pp. 205-208 ◽  
Author(s):  
Kalyan Kali Sengupta ◽  
Tapashi Samanta ◽  
Samarendra Nath Basu
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Kinetics Of Oxidation ◽  
Chromium Vi ◽  
Oxidation Of Methanol ◽  
Kinetics Of

scholarly journals Kinetics and Mechanism of Oxidation of Isoleucine byN-Bromophthalimide in Aqueous Perchloric Acid Medium

2011 ◽  
Vol 8 (4) ◽  
pp. 1728-1733 ◽  
Author(s):  
N. M. I. Alhaji ◽  
S. Sofiya Lawrence Mary
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Reaction Rate ◽  
Activation Parameters ◽  
Halide Ions ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Hypobromous Acid ◽  
Different Temperatures ◽  
Kinetics Of

The kinetics of oxidation of isoleucine withN-bromophthalimide has been studied in perchloric acid medium potentiometrically. The reaction is of first order each in [NBP] and [amino acid] and negative fractional order in [H+]. The rate is decreased by the addition of phthalimide. A decrease in the dielectric constant of the medium increases the rate. Addition of halide ions or acrylonitrile has no effect on the kinetics. Similarly, variation of ionic strength of the medium does not affect the reaction rate. The reaction rate has been determined at different temperatures and activation parameters have been calculated. A suitable mechanism involving hypobromous acid as reactive species has been proposed.

scholarly journals Micellar and Polymer Catalysis in the Kinetics of Oxidation of L-lysine by Permanganate Ion in Perchloric Acid Medium

2021 ◽  
Vol 75 ◽  
Author(s):  
Mohammed Hassan ◽  
Mohammad Al-Dhoun ◽  
Yazan Batineh ◽  
Ahmad A. Najjar ◽  
Adnan Dahadha ◽  
...  
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Permanganate Ion

Kinetics of oxidation of ethanol by potassium permanganate in perchloric acid medium

1989 ◽  
Vol 38 (2) ◽  
pp. 313-318 ◽  
Author(s):  
Kalyan Kali Sen Gupta ◽  
Mrityunjoy Adhikari ◽  
Shipra Sen Gupta
Keyword(s):  
Acid Medium ◽  
Potassium Permanganate ◽  
Perchloric Acid ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Oxidation Of Ethanol

Kinetic and mechanistic studies of Rh(III)-catalysed oxidation of D-xylose and L-sorbose by N-bromoacetamide in perchloric acid medium

2011 ◽  
Vol 8 (3) ◽  
pp. 622-635
Author(s):  
A. K. Singh ◽  
S. Yadav ◽  
J. Srivastava ◽  
S. Rahmani ◽  
R. K. Singh ◽  
...  
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Mechanistic Studies ◽  
Catalysed Oxidation

A KINETICS AND MECHANISTIC STUDY OF THE OXIDATION OF L-ARGININE BY QDC IN DMF-WATER MEDIUM

2021 ◽  
pp. 11-12
Author(s):  
Deepika Jain ◽  
Shilpa Rathor
Keyword(s):  
Perchloric Acid ◽  
Reaction Rate ◽  
Main Product ◽  
Activation Parameters ◽  
Reaction Rates ◽  
Mechanistic Study ◽  
Water Medium ◽  
Volume Percentage ◽  
Kinetics Of Oxidation ◽  
Kinetics Of

The present paper describes the kinetics of oxidation of l-Arginine by QDC in the presence of perchloric acid in 30% DMF-H O(v/v) medium at 2 + 40⁰C spectrophotometrically at λ =354nm. The reaction is rst order with respect to [QDC], [H ], and [substrate]. The reaction rate increased with max increasing volume percentage of DMF in reaction mixture. Michaelis- Menten type kinetic was observed with l-Arginine. The reaction rates were studied at different temperature and the activation parameters has been computed. The main product was identied as Cr (III) and 4-Guanidino buteraldehyde.

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