ChemInform Abstract: Preparation of Dispersed Phase Ceramic Boron Nitride and Aluminum Nitride Composite Coatings by Chemical Vapor Deposition.

ChemInform ◽  
2010 ◽  
Vol 22 (48) ◽  
pp. no-no
Author(s):  
W. Y. LEE ◽  
W. J. LACKEY ◽  
G. B. FREEMAN ◽  
P. K. AGRAWAL ◽  
D. J. TWAIT
1991 ◽  
Vol 74 (10) ◽  
pp. 2649-2658 ◽  
Author(s):  
Woo Y. Lee ◽  
W. J. Lackey ◽  
P. K. Agrawal ◽  
Garth B. Freeman

Author(s):  
G. B. Freeman ◽  
W. Y. Lee ◽  
W. J. Lackey

Dispersed phase ceramic composites have recently received much attention because of their superior mechanical properties including fracture toughness, strength, hardness, resistance to wear and erosion. Chemical vapor deposition (CVD) offers one avenue of preparing ceramic composites by simultaneous deposition of multiple phases, i.e. codeposition. The major advantage of preparing dispersed phase ceramic composites by CVD is that mechanical as well as chemical, electrical, optical, and thermal properties of the composites can be favorably tailored by controlling the composites’ composition and microstructure via variation and optimization of CVD process variables such as temperature, pressure, reagent concentration, substrate type, reactor geometry, etc.In this study, the codeposition of boron nitride (BN) and aluminum nitride (AlN) was explored because the BN+AlN composite system (as a deposited coating) offers the promise of tailoring properties such as friction coefficient, hardness, and resistance to wear and erosion for possible radome, electromagnetic window and tribological applications.


1992 ◽  
Vol 7 (3) ◽  
pp. 754-764 ◽  
Author(s):  
T.S. Moss ◽  
John A. Hanigofsky ◽  
W.J. Lackey

Thermodynamic calculations were performed for chemical vapor deposition in the Al–B–Ti–N–H–Cl–Ar system in order to determine the feasibility of multiphase deposition. Reagent species used were BCl3, AlCl3, TiCl4, NH3, H2, and Ar; B2 was substituted for BCl3 to determine changes in deposition efficiency. Temperature and input molar concentrations were varied over a range of values to establish relationships among solid deposits. Through deposition diagrams, molar efficiency plots, and partial pressure graphs, several two and three phase regions were found to exist. The calculations indicate that the following dispersed phase composites could be prepared: A1N + BN + TiN, BN + TiN, BN + TiB2, BN + TiB2 + TiN, and TiB2 + TiN.


2009 ◽  
Vol 21 (23) ◽  
pp. 5601-5606 ◽  
Author(s):  
Navneet Kumar ◽  
Wontae Noh ◽  
Scott R. Daly ◽  
Gregory S. Girolami ◽  
John R. Abelson

2D Materials ◽  
2017 ◽  
Vol 4 (2) ◽  
pp. 025117 ◽  
Author(s):  
Ariel Ismach ◽  
Harry Chou ◽  
Patrick Mende ◽  
Andrei Dolocan ◽  
Rafik Addou ◽  
...  

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