ChemInform Abstract: Novel Enantioselective Acylating Agents. The Reactions of Chiral Orthoesters and Silyl Enol Ethers as a Route to Optically Active Monoprotected 1,3-Dicarbonyl Compounds.

T. BASILE; L. LONGOBARDO; E. TAGLIAVINI; C. TROMBINI; A. UMANI-RONCHI

doi:10.1002/chin.199048148

ChemInform Abstract: Novel Enantioselective Acylating Agents. The Reactions of Chiral Orthoesters and Silyl Enol Ethers as a Route to Optically Active Monoprotected 1,3-Dicarbonyl Compounds.

ChemInform ◽

10.1002/chin.199048148 ◽

1990 ◽

Vol 21 (48) ◽

Author(s):

T. BASILE ◽

L. LONGOBARDO ◽

E. TAGLIAVINI ◽

C. TROMBINI ◽

A. UMANI-RONCHI

Keyword(s):

Optically Active ◽

Dicarbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers

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ChemInform Abstract: Synthesis of Optically Active 2-Siloxycyclopropanecarboxylates by Asymmetric Catalysis. Part 4. Influence of Nucleophilicity of Silyl Enol Ethers on Stereoselectivities in Asymmetric Cyclopropanation Reactions.

ChemInform ◽

10.1002/chin.199729035 ◽

2010 ◽

Vol 28 (29) ◽

pp. no-no

Author(s):

R. SCHUMACHER ◽

H.-U. REISSIG

Keyword(s):

Asymmetric Catalysis ◽

Optically Active ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Asymmetric Cyclopropanation

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ChemInform Abstract: Synthesis of Optically Active 2-Siloxycyclopropanecarboxylates by Asymmetric Catalysis. Part 3. Screening of Various Catalysts for the Asymmetric Cyclopropanation of Structurally Typical Silyl Enol Ethers - Scope and Limitations of Ev

ChemInform ◽

10.1002/chin.199729065 ◽

2010 ◽

Vol 28 (29) ◽

pp. no-no

Author(s):

R. SCHUMACHER ◽

F. DAMMAST ◽

H.-U. REISSIG

Keyword(s):

Asymmetric Catalysis ◽

Optically Active ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Asymmetric Cyclopropanation

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ChemInform Abstract: Protected β-Dicarbonyl Compounds: Alkylation of Trimethyl Silyl Enol Ethers with Tris-(phenylseleno) Methane Mediated by Tin Tetrachloride.

Chemischer Informationsdienst ◽

10.1002/chin.198651237 ◽

1986 ◽

Vol 17 (51) ◽

Author(s):

J. V. COMASSETO ◽

C. C. SILVEIRA

Keyword(s):

Dicarbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Tin Tetrachloride

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Catalytic Asymmetric Simmons—Smith Cyclopropanation of Silyl Enol Ethers. Efficient Synthesis of Optically Active Cyclopropanol Derivatives.

ChemInform ◽

10.1002/chin.200643029 ◽

2006 ◽

Vol 37 (43) ◽

Author(s):

Haifeng Du ◽

Jiang Long ◽

Yian Shi

Keyword(s):

Optically Active ◽

Efficient Synthesis ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Catalytic Asymmetric

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Synthesis of 1,4-Dicarbonyl Compounds from Silyl Enol Ethers and Bromocarbonyls, Catalyzed by an Organic Dye under Visible-Light Irradiation with Perfect Selectivity for the Halide Moiety over the Carbonyl Group

Organic Letters ◽

10.1021/acs.orglett.6b02869 ◽

2016 ◽

Vol 18 (21) ◽

pp. 5704-5707 ◽

Cited By ~ 27

Author(s):

Naoto Esumi ◽

Kensuke Suzuki ◽

Yoshihiro Nishimoto ◽

Makoto Yasuda

Keyword(s):

Visible Light ◽

Carbonyl Group ◽

Visible Light Irradiation ◽

Organic Dye ◽

Light Irradiation ◽

Dicarbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers

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ChemInform Abstract: Synthesis of Optically Active α-Hydroxy Ketones by Enantioselective Oxidation of Silyl Enol Ethers with a Fructose-Derived Dioxirane.

ChemInform ◽

10.1002/chin.199828106 ◽

2010 ◽

Vol 29 (28) ◽

pp. no-no

Author(s):

W. ADAM ◽

R. T. FELL ◽

C. R. SAHA-MOELLER ◽

C.-G. ZHAO

Keyword(s):

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Hydroxy Ketones

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Catalytic Asymmetric Simmons−Smith Cyclopropanation of Silyl Enol Ethers. Efficient Synthesis of Optically Active Cyclopropanol Derivatives

Organic Letters ◽

10.1021/ol0609659 ◽

2006 ◽

Vol 8 (13) ◽

pp. 2827-2829 ◽

Cited By ~ 55

Author(s):

Haifeng Du ◽

Jiang Long ◽

Yian Shi

Keyword(s):

Optically Active ◽

Efficient Synthesis ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Catalytic Asymmetric

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Protected β-Dicarbonyl Compounds: Alkylation of Trimethyl Silyl Enol Ethers with Tris-(Phenylseleno) Methane Mediated by Tin Tetrachloride

Synthetic Communications ◽

10.1080/00397918608056362 ◽

1986 ◽

Vol 16 (10) ◽

pp. 1167-1171 ◽

Cited By ~ 6

Author(s):

João V. Comasseto ◽

Claudio C. Silveira

Keyword(s):

Dicarbonyl Compounds ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Tin Tetrachloride

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Formation of quaternary centres via iron allyl cations. Rapid entry into spirocyclic ring systems

Canadian Journal of Chemistry ◽

10.1139/v97-116 ◽

1997 ◽

Vol 75 (7) ◽

pp. 965-974 ◽

Cited By ~ 2

Author(s):

M. Anne Charlton ◽

James R. Green

Keyword(s):

Reductive Cyclization ◽

Cyclization Reactions ◽

Dicarbonyl Compounds ◽

Enol Ethers ◽

Ring Systems ◽

Silyl Enol Ethers ◽

Keto Esters ◽

Condensation Products ◽

Ketene Acetals ◽

Silyl Ketene Acetals

Ester-substituted allyltetracarbonyliron cations react with cycloalkylidene-type silyl enol ethers, silyl ketene acetals, and β-keto-esters to give 1,6-dicarbonyl compounds containing a newly formed quaternary centre. Selected condensation products are converted by enolate chemistry into spirocyclic [4.4], [4.5], and [4.6] systems. Acyloin and other reductive cyclization reactions are employed to convert the condensation products into spirocyclic [4.5], [5.5], and [5.6] systems. Keywords: allyliron complexes, umpolung synthesis, 1,6-dicarbonyls, spirocycle synthesis.

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Synthesis of optically active α-hydroxy ketones by enantioselective oxidation of silyl enol ethers with a fructose-derived dioxirane

Tetrahedron Asymmetry ◽

10.1016/s0957-4166(98)00005-6 ◽

1998 ◽

Vol 9 (3) ◽

pp. 397-401 ◽

Cited By ~ 51

Author(s):

Waldemar Adam ◽

Rainer T. Fell ◽

Chantu R. Saha-Möller ◽

Cong-Gui Zhao

Keyword(s):

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Hydroxy Ketones

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