ChemInform Abstract: Homogeneous and Heterogeneous Catalytic Asymmetric Reactions. Part 2. Asymmetric Hydrogenation of Steroid Ketones.

ChemInform ◽  
1990 ◽  
Vol 21 (35) ◽  
Author(s):  
G. GOENDOES ◽  
L. GERA ◽  
M. BARTOK ◽  
J. C. ORR
Keyword(s):  
Asymmetric Hydrogenation ◽  
Asymmetric Reactions ◽  
Heterogeneous Catalytic ◽  
Catalytic Asymmetric ◽  
Catalytic Asymmetric Reactions

Homogeneous and heterogeneous catalytic asymmetric reactions

1989 ◽  
Vol 373 (3) ◽  
pp. 365-375 ◽  
Author(s):  
György Göndös ◽  
Lajos Gera ◽  
Mihály Bartók ◽  
James C. Orr
Keyword(s):  
Asymmetric Reactions ◽  
Heterogeneous Catalytic ◽  
Catalytic Asymmetric ◽  
Catalytic Asymmetric Reactions

Homogeneous and heterogeneous catalytic asymmetric reactions

1990 ◽  
Vol 60 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Gyula Wittmann ◽  
Gizella B. Bartók ◽  
Mihály Bartók ◽  
Gerard V. Smith
Keyword(s):  
Asymmetric Reactions ◽  
Heterogeneous Catalytic ◽  
Catalytic Asymmetric ◽  
Catalytic Asymmetric Reactions

scholarly journals Pyrazoleamides in Catalytic Asymmetric Reactions: Recent Advances

2021 ◽  
Author(s):  
Sara Meninno ◽  
Francesca Franco ◽  
Maurizio Benaglia ◽  
Alessandra Lattanzi
Keyword(s):  
Asymmetric Reactions ◽  
Recent Advances ◽  
Catalytic Asymmetric ◽  
Catalytic Asymmetric Reactions

A Facile Synthesis of the Enantiopure, Nitrogen-Substituted 2,2'-Diamino-1,1'-binaphthyls as Potential Ligands for Catalytic Asymmetric Reactions

1998 ◽  
Vol 63 (4) ◽  
pp. 515-519 ◽  
Author(s):  
Štěpán Vyskočil ◽  
Martin Smrčina ◽  
Pavel Kočovský
Keyword(s):  
Room Temperature ◽  
Asymmetric Reactions ◽  
Reductive Alkylation ◽  
Facile Synthesis ◽  
Catalytic Asymmetric ◽  
Catalytic Asymmetric Reactions

Reductive alkylation of (R)-(+)-2,2'-diamino-1,1'-binaphthyl (1) with various ketones has been accomplished by means of NaBH4/H2SO4 in THF at room temperature. Bisalkylation predominated with the sterically less demanding acetone (1→3a; 82%), whereas the bulky 2-adamantanone afforded mainly the monoalkylated product 4c (71%). Both mono- and bisalkylated diamines (R)-3 and (R)-4 were reductively permethylated on reaction with CH2O, NaBH4, and H2SO4. The Pd(0)-catalyzed phenylation of (R)-(+)-1 with PhBr afforded the N,N'-diphenyl derivative (R)-7 (70%).

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