ChemInform Abstract: THEORY AND USE OF PHOTOELECTRON SPECTROSCOPY. 106. CYCLOALKYLIDENESELENOKETENES, PRODUCTS OF THE PYROLYSIS OF 1,2,3-SELENADIAZOLES - STUDIES WITH TEMPERATURE-DEPENDENT PE (PHOTOELECTRON) SPECTROSCOPY AND MATRIX IR SPECTROSCOPY

1985 ◽  
Vol 16 (12) ◽  
Author(s):  
R. SCHULZ ◽  
A. SCHWEIG
1984 ◽  
Vol 39 (11) ◽  
pp. 1536-1540 ◽  
Author(s):  
Reinhard Schulz ◽  
Armin Schweig

Abstract The gas-phase pyrolysis of cyclohexeno-1,2,3-selenadiazole and cycloocteno-1,2,3-selenadiazole has been investigated by variable temperature photoelectron spectroscopy and matrix IR spectroscopy. The ring contracted, highly reactive products cyclopentylidenselenoketene (cyclopentylidenmethanselone) and cycloheptylidenselenoketene (cycloheptylidenmethanselone) - which had not been found in liquid phase thermolysis experiments - have been detected. Additionally HeI photoelectron and IR spectra of analogous ketenes and thioketenes are presented for comparative reasons.


ChemInform ◽  
2010 ◽  
Vol 22 (18) ◽  
pp. no-no
Author(s):  
V. N. KHABASHESKU ◽  
S. E. BOGANOV ◽  
P. S. ZUEV ◽  
O. M. NEFEDOV ◽  
J. TAMAS ◽  
...  

2009 ◽  
Vol 113 (19) ◽  
pp. 5567-5576 ◽  
Author(s):  
Xue-Bin Wang ◽  
Alina P. Sergeeva ◽  
Jie Yang ◽  
Xiao-Peng Xing ◽  
Alexander I. Boldyrev ◽  
...  

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