ChemInform Abstract: THE PRECIPITATION OF THE LANTHANIDE ELEMENTS COMPLEXES WITH HEXAAMMINE COBALT(III) CATION. III. PRECIPITATION BEHAVIORS AND THE COMPOSITIONS OF CERIUM(IV) SULFATE AND CARBONATE COMPLEXES

1979 ◽  
Vol 10 (36) ◽  
Author(s):  
A. SAITO ◽  
K. UENO
Keyword(s):  
Lanthanide Elements ◽  
Carbonate Complexes

scholarly journals Meta-studtite stability in aqueous solutions. Impact of HCO3−, H2O2 and ionizing radiation on dissolution and speciation

2021 ◽  
Author(s):  
Junyi Li ◽  
Zoltán Szabó ◽  
Mats Jonsson
Keyword(s):  
Aqueous Solution ◽  
Ionizing Radiation ◽  
Aqueous Solutions ◽  
Carbonate Complexes ◽  
C Nmr

Four different uranyl-(peroxide)-carbonate complexes were identified during studtite and meta-studtite dissolution in aqueous solution containing 10 mM HCO3− by 13C NMR.

Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+

2013 ◽  
Vol 135 (26) ◽  
pp. 9857-9868 ◽  
Author(s):  
Matthew R. MacDonald ◽  
Jefferson E. Bates ◽  
Joseph W. Ziller ◽  
Filipp Furche ◽  
William J. Evans
Keyword(s):  
Molecular Complexes ◽  
Lanthanide Elements

Synthesis and Characterization of Lanthanide Metal-Organic Frameworks with Perfluorinated Linkers

2016 ◽  
Vol 98 ◽  
pp. 70-74
Author(s):  
Andrius Laurikėnas ◽  
Jurgis Barkauskas ◽  
Aivaras Kareiva
Keyword(s):  
Metal Organic Frameworks ◽  
Aqueous Media ◽  
Xrd Analysis ◽  
X Ray Diffraction ◽  
Lanthanide Elements ◽  
Diffusion Controlled ◽  
Benzenedicarboxylic Acid ◽  
Metal Organic ◽  
Lanthanide Metal

In this study, lanthanide elements (Ln3+) and 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylic acid (TFBDC) based metal-organic frameworks (MOFs) were synthesized by precipitation and diffusion-controlled precipitation methods. Powders insoluble in aqueous media and polar solvents were obtained. The microstructure and properties of Ln3+ MOFs were evaluated and discussed. X-ray diffraction (XRD) analysis, infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and fluorescence spectroscopy (FLS) were carried out to characterize Ln3+ MOF's crystallinity, the microstructure, chemical composition and optical properties.

Instrumental neutron activation analysis of lanthanides and coexisting elements in monazite samples and group separation using synthesized inorganic ion exchangers

2020 ◽  
Vol 108 (11) ◽  
pp. 901-912
Author(s):  
Mohamed A. Ghamry ◽  
Fatma H. El-Sweify ◽  
Alaa El-Din A. Abdel-Fattah ◽  
Shorouk M. Aly ◽  
Mohamed F. El-Shahat
Keyword(s):  
Neutron Activation Analysis ◽  
Instrumental Neutron Activation Analysis ◽  
Activation Analysis ◽  
Neutron Activation ◽  
Group Separation ◽  
Ion Exchangers ◽  
Inorganic Ion Exchangers ◽  
Inorganic Ion ◽  
Lanthanide Elements ◽  
Instrumental Neutron Activation

AbstractSamples of Egyptian monazite ore obtained from black sand of Abu-Khashaba, Rashied (Rosetta) area on the Mediterranean Sea coast were analyzed for some lanthanides and coexisting elements using instrumental neutron activation analysis (INAA). The analyses were carried out qualitatively and quantitatively for the elements Ce, Nd, Eu, Gd, Tb, Yb and Sc, La as well as the accompanying elements Co, Cr, Fe, Hf, Nb, Zn, Zr in addition to the actinides Th and U; whereas after relatively longer decay time the following lanthanide elements were analyzed: Ce, Nd, Eu, Gd, Tb, Yb and Sc, beside the accompanying elements Co, Cr, Fe, Hf, Nb, Zn, Zr and Th. Two certified reference materials (CRM) were used in this study. For sorption studies, radioactive isotopes 141Ce, 160Tb, 169Yb, 95Zr, 181Hf, and 95Nb were prepared by neutron irradiation to trace the adsorption behaviors of their corresponding elements under certain conditions. Furthermore, radiochemical separation of the analyzed elements in the irradiated monazite samples in sulfuric acid solutions was carried out. Ion exchange technique was applied under static and dynamic conditions and the employed inorganic ion exchangers were locally synthesized and characterized using FT-IR and scanning electron microscopy (SEM) tools. Good group separation of the analyzed lanthanide elements from the accompanying elements was achieved.

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