ChemInform Abstract: CHEMISTRY OF METAL CARBONYLS AND CYANO COMPLEXES IN LIQUID AMMONIA. XXXIII. PREPARATION OF NEW CARBAMOYL-CARBONYL COMPLEXES FROM WELL-KNOWN AND NEW CATIONIC CARBONYL COMPOUNDS OF MANGANESE AND RHENIUM

1979 ◽  
Vol 10 (6) ◽  
Author(s):  
H. BEHRENS ◽  
R.-J. LAMPE ◽  
P. MERBACH ◽  
M. MOLL
Keyword(s):  
Carbonyl Compounds ◽  
Liquid Ammonia ◽  
Metal Carbonyls ◽  
Carbonyl Complexes ◽  
Cyano Complexes

Fixierung von Metallcarbonylen auf Poly-Isocyaniden [1] / Anchoring of Metal Carbonyls on Poly Isocyanides [1]

1982 ◽  
Vol 37 (2) ◽  
pp. 201-208 ◽  
Author(s):  
Hartmut Menzel ◽  
Wolf Peter Fehlhammer ◽  
Wolfgang Beck
Keyword(s):  
Carbonyl Compounds ◽  
Metal Carbonyl ◽  
Metal Carbonyls ◽  
Cyano Complexes ◽  
Polymeric Supports

Abstract Polyisocyanides with the groups -CH2N ≡ C and -C(O)O(CH2)2N≡C attached to polystyrene have been prepared and reacted with various metal carbonyl compounds resulting in the fixation on the polymeric supports of-M(CO)5, -M(CO)4 (M = Cr, Mo, W), -MO(Cl)(η-C5H5)(CO)2, -Mn2(CO)η -Mn(CO)ηX (N = 3, 4; X = Cl, Br), -Fe(CO)4, -Fe3(CO)11, -FeI2(CO)2, -FeX(η-C5H5)(CO) (X = Cl, Br, I), -Ru(CO)4, -Ru3(CO)9, ,,-Os3H2(CO)10", and -RhCl(CO)2. The cyano complexes [Fe(CN)2(η-C5H5)CO]- and [Mo(CN)2(η-C5H5)(CO)2]- have been immobilized by alkylation with chloromethylated polystyrene

Electrocatalytic reduction of carbon dioxide with Mn(terpyridine) carbonyl complexes

2016 ◽  
Vol 45 (43) ◽  
pp. 17179-17186 ◽  
Author(s):  
Charles W. Machan ◽  
Clifford P. Kubiak
Keyword(s):  
Carbon Dioxide ◽  
Carbonyl Compounds ◽  
Carbonyl Complexes ◽  
Electrocatalytic Reduction ◽  
Coordination Modes ◽  
Reducing Conditions

The behavior of a series of Manganese (Mn) carbonyl compounds with 2,2′:6′,2′′-terpyridine (tpy) in κ2-N,N′ and κ3-N,N′,N′′ coordination modes under electrochemically reducing conditions is reported.

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