ChemInform Abstract: WEAK COMPLEXES OF SULFUR AND SELENIUM. PART 5. HALIDE-ION REPLACEMENT IN 1-1 COMPLEXES OF SULFUR DIOXIDE, THIONYL CHLORIDE, AND SULFONYL CHORIDE WITH HALIDE IONS IN ACETONITRILE AND DIMETHYL SULFOXIDE

1978 ◽  
Vol 9 (49) ◽  
Author(s):  
M. A. KHAN ◽  
S. WASIF ◽  
S. B. SALAMA
Keyword(s):  
Sulfur Dioxide ◽  
Dimethyl Sulfoxide ◽  
Thionyl Chloride ◽  
Halide Ions ◽  
Weak Complexes

Reactions in mixed non-aqueous systems containing sulfur dioxide. V. The formation of metal sulfur oxyanion compounds by the electrolytic solution of metals

1983 ◽  
Vol 36 (10) ◽  
pp. 1991 ◽  
Author(s):  
NK Graham ◽  
JB Gill ◽  
DC Goodall
Keyword(s):  
Sulfur Dioxide ◽  
Dimethyl Sulfoxide ◽  
Binary Systems ◽  
Solvent System ◽  
Binary Solvent ◽  
Aqueous Systems ◽  
Electrolytic Solution ◽  
Solvent Parameters

The metals Ti, Zr, V, Cr, Mo, Fe, Ni and Sn dissolve electrolytically in the binary solvent system dimethyl sulfoxide-sulfur dioxide, forming metal disulfates; W forms sulfate. The metals dissolve electrolytically in other binary systems containing sulfur dioxide, forming mixtures of sulfur oxyanions. The importance of solvent parameters in metal reactivity is discussed, together with the mechanism of the reactions.

Sign in / Sign up

Export Citation Format

Share Document