Earth‐Abundant Transition‐Metal‐Based Bifunctional Electrocatalysts for Overall Water Splitting in Alkaline Media

2020 ◽  
Vol 26 (29) ◽  
pp. 6423-6436 ◽  
Author(s):  
Jianmin Yu ◽  
Thi Anh Le ◽  
Ngoc Quang Tran ◽  
Hyoyoung Lee
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Alkaline Media ◽  
Overall Water Splitting ◽  
Bifunctional Electrocatalysts ◽  
Earth Abundant

Recent advances in transition-metal-sulfide-based bifunctional electrocatalysts for overall water splitting

2021 ◽  
Author(s):  
Min Wang ◽  
Li Zhang ◽  
Yijia He ◽  
Hongwei Zhu
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Metal Sulfide ◽  
Water Electrolysis ◽  
Practical Application ◽  
Transition Metal Sulfide ◽  
Overall Water Splitting ◽  
Recent Advances ◽  
Bifunctional Electrocatalysts

This review summarizes recent advances relating to transition metal sulfide (TMS)-based bifunctional electrocatalysts, providing guidelines for the design and fabrication of TMS-based catalysts for practical application in water electrolysis.

A general approach to the synthesis of transition metal phosphide nanoarrays on MXene nanosheets for pH-universal hydrogen evolution and alkaline overall water splitting

2020 ◽  
Vol 8 (28) ◽  
pp. 14234-14242 ◽  
Author(s):  
Liang Yan ◽  
Bing Zhang ◽  
Shangyou Wu ◽  
Jianlin Yu
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Water Splitting ◽  
Noble Metal ◽  
Metal Phosphide ◽  
Highly Efficient ◽  
Overall Water Splitting ◽  
Bifunctional Electrocatalysts ◽  
Transition Metal Phosphide

Exploring highly efficient, stable, and non-noble-metal bifunctional electrocatalysts for overall water splitting is greatly desired but still remains an ongoing challenge.

High performance multicomponent bifunctional catalysts for overall water splitting

2020 ◽  
Vol 8 (27) ◽  
pp. 13795-13805 ◽  
Author(s):  
Ranjith Bose ◽  
Vasanth Rajendiran Jothi ◽  
K. Karuppasamy ◽  
Akram Alfantazi ◽  
Sung Chul Yi
Keyword(s):  
Energy Conversion ◽  
Water Splitting ◽  
Precious Metal ◽  
High Performance ◽  
Bifunctional Catalysts ◽  
Overall Water Splitting ◽  
Highly Active ◽  
Bifunctional Electrocatalysts ◽  
Earth Abundant

Designing highly active bifunctional electrocatalysts from Earth-abundant elements has great prospects for substituting precious-metal based catalysts in energy conversion processes, such as water splitting.

scholarly journals Two-Dimensional Layered NiLiP2S6 Crystals as an Efficient Bifunctional Electrocatalyst for Overall Water Splitting

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 786
Author(s):  
Song-Jeng Huang ◽  
Adil Muneeb ◽  
Palani Sabhapathy ◽  
Khasim Saheb Bayikadi ◽  
Tahir Murtaza ◽  
...  
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Alkaline Media ◽  
Intrinsic Activity ◽  
Tafel Slope ◽  
Bifunctional Electrocatalyst ◽  
Long Term Stability ◽  
Highly Efficient ◽  
Overall Water Splitting ◽  
Earth Abundant

The quest of earth-abundant bifunctional electrocatalysts for highly efficient oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is essential for clean and renewable energy systems. Herein, directed by the experimental analysis, we demonstrate layered nickel lithium phosphosulfide (NiLiP2S6) crystal as a highly efficient water-splitting catalyst in alkaline media. With strained lattice due to stacked layers as observed by TEM and electronic structure analysis performed by XPS showed mixed Ni2+,3+ oxidation states induced by addition of Li as a cation, NiLiP2S6 displays excellent OER (current density of 10 mA cm–2 showed an overpotential of 303 mV vs. RHE and a Tafel slope of 114 mV dec–1) and HER activity (current density of −10 mA cm–2 showed an overpotential of 184 mV vs. RHE and a Tafel slope of 94.5 mV dec–1). Finally, an alkaline media was employed to demonstrate the overall water splitting using NiLiP2S6 as both the anode and the cathode, which attained a 50 mA cm−2 current density at 1.68 V. This bimetallic phosphosulfide, together with long-term stability and enhanced intrinsic activity, shows enormous potential in water splitting applications.

Hierarchical superhydrophilic/superaerophobic CoMnP/Ni2P nanosheets-based microplates arrays for enhanced overall water splitting

2021 ◽  
Author(s):  
Mengzhao Liu ◽  
Zhe Sun ◽  
Shiyan Li ◽  
Xiaowa Nie ◽  
Yuefeng Liu ◽  
...  
Keyword(s):  
Water Splitting ◽  
Noble Metal ◽  
Water Electrolysis ◽  
Alkaline Media ◽  
Industrial Water ◽  
Overall Water Splitting ◽  
Bifunctional Electrocatalysts ◽  
Acidic And Alkaline Media

The development of efficient and stable non-noble metal bifunctional electrocatalysts for overall water splitting in acidic and alkaline media is highly desirable for industrial water electrolysis, but remains a profound...

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