Peroxycarbenium Ions as the “Gatekeepers” in Reaction Design: Assistance from Inverse Alpha‐Effect in Three‐Component β‐Alkoxy‐β‐peroxylactones Synthesis

2019 ◽  
Vol 25 (63) ◽  
pp. 14460-14468 ◽  
Author(s):  
Vera A. Vil' ◽  
Yana A. Barsegyan ◽  
Denis V. Barsukov ◽  
Alexander A. Korlyukov ◽  
Igor V. Alabugin ◽  
...  
Keyword(s):  
2000 ◽  
Vol 179 ◽  
pp. 387-388
Author(s):  
Gaetano Belvedere ◽  
V. V. Pipin ◽  
G. Rüdiger

Extended AbstractRecent numerical simulations lead to the result that turbulence is much more magnetically driven than believed. In particular the role ofmagnetic buoyancyappears quite important for the generation ofα-effect and angular momentum transport (Brandenburg & Schmitt 1998). We present results obtained for a turbulence field driven by a (given) Lorentz force in a non-stratified but rotating convection zone. The main result confirms the numerical findings of Brandenburg & Schmitt that in the northern hemisphere theα-effect and the kinetic helicityℋkin= 〈u′ · rotu′〉 are positive (and negative in the northern hemisphere), this being just opposite to what occurs for the current helicityℋcurr= 〈j′ ·B′〉, which is negative in the northern hemisphere (and positive in the southern hemisphere). There has been an increasing number of papers presenting observations of current helicity at the solar surface, all showing that it isnegativein the northern hemisphere and positive in the southern hemisphere (see Rüdigeret al. 2000, also for a review).


Data ◽  
2021 ◽  
Vol 6 (1) ◽  
pp. 4
Author(s):  
Evgeny Mikhailov ◽  
Daniela Boneva ◽  
Maria Pashentseva

A wide range of astrophysical objects, such as the Sun, galaxies, stars, planets, accretion discs etc., have large-scale magnetic fields. Their generation is often based on the dynamo mechanism, which is connected with joint action of the alpha-effect and differential rotation. They compete with the turbulent diffusion. If the dynamo is intensive enough, the magnetic field grows, else it decays. The magnetic field evolution is described by Steenbeck—Krause—Raedler equations, which are quite difficult to be solved. So, for different objects, specific two-dimensional models are used. As for thin discs (this shape corresponds to galaxies and accretion discs), usually, no-z approximation is used. Some of the partial derivatives are changed by the algebraic expressions, and the solenoidality condition is taken into account as well. The field generation is restricted by the equipartition value and saturates if the field becomes comparable with it. From the point of view of mathematical physics, they can be characterized as stable points of the equations. The field can come to these values monotonously or have oscillations. It depends on the type of the stability of these points, whether it is a node or focus. Here, we study the stability of such points and give examples for astrophysical applications.


1998 ◽  
Vol 167 ◽  
pp. 406-414
Author(s):  
N. Seehafer

AbstractFilaments are a global phenomenon and their formation, structure and dynamics are determined by magnetic fields. So they are an important signature of the solar magnetism. The central mechanism in traditional mean-field dynamo theory is the alpha effect and it is a major result of this theory that the presence of kinetic or magnetic helicities is at least favourable for the effect. Recent studies of the magnetohydrodynamic equations by means of numerical bifurcation-analysis techniques have confirmed the decisive role of helicity for a dynamo effect. The alpha effect corresponds to the simultaneous generation of magnetic helicities in the mean field and in the fluctuations, the generation rates being equal in magnitude and opposite in sign. In the case of statistically stationary and homogeneous fluctuations, in particular, the alpha effect can increase the energy in the mean magnetic field only under the condition that also magnetic helicity is accumulated there. Generally, the two helicities generated by the alpha effect, that in the mean field and that in the fluctuations, have either to be dissipated in the generation region or to be transported out of this region. The latter may lead to the appearance of helicity in the atmosphere, in particular in filaments, and thus provide valuable information on dynamo processes inaccessible to in situ measurements.


2011 ◽  
Vol 332 (5) ◽  
pp. 496-501 ◽  
Author(s):  
L.L. Kitchatinov ◽  
S.V. Olemskoy

2021 ◽  
Author(s):  
Peter Rutkevich ◽  
Georgy Golitsyn ◽  
Anatoly Tur

<p>Large-scale instability in incompressible fluid driven by the so called Anisotropic Kinetic Alpha (AKA) effect satisfying the incompressible Navier-Stokes equation with Coriolis force is considered. The external force is periodic; this allows applying an unusual for turbulence calculations mathematical method developed by Frisch et al [1]. The method provides the orders for nonlinear equations and obtaining large scale equations from the corresponding secular relations that appear at different orders of expansions. This method allows obtaining not only corrections to the basic solutions of the linear problem but also provides the large-scale solution of the nonlinear equations with the amplitude exceeding that of the basic solution. The fluid velocity is obtained by numerical integration of the large-scale equations. The solution without the Coriolis force leads to constant velocities at the steady-state, which agrees with the full solution of the Navier-Stokes equation reported previously. The time-invariant solution contains three families of solutions, however, only one of these families contains stable solutions. The final values of the steady-state fluid velocity are determined by the initial conditions. After account of the Coriolis force the solutions become periodic in time and the family of solutions collapses to a unique solution. On the other hand, even with the Coriolis force the fluid motion remains two-dimensional in space and depends on a single spatial variable. The latter fact limits the scope of the AKA method to applications with pronounced 2D nature. In application to 3D models the method must be used with caution.</p><p>[1] U. Frisch, Z.S. She and P. L. Sulem, “Large-Scale Flow Driven by the Anisotropic Kinetic Alpha Effect,” Physica D, Vol. 28, No. 3, 1987, pp. 382-392.</p>


2012 ◽  
Vol 57 (6) ◽  
pp. 224-228 ◽  
Author(s):  
M. Yu. Reshetnyak
Keyword(s):  

2005 ◽  
Vol 13 ◽  
pp. 95-96
Author(s):  
Kirill Kuzanyan

AbstractSpatial and temporal distributions of tracers of the alpha-effect in the solar convection zone, such as current helicity and twist factor averaged over solar active regions are available by vector magnetographic observations. We discuss the data obtained at Huairou Solar Observing Station of Chinese Academy of Sciences and confront them with predictions of dynamo theory. At the present time, though the observations are rough, we still have a statistically representative sampling to conclude that the observations do not contradict the theory.


2011 ◽  
Vol 121 (2) ◽  
pp. 234-244 ◽  
Author(s):  
David Taylor Szabo ◽  
Janet J. Diliberto ◽  
Heldur Hakk ◽  
Janice K. Huwe ◽  
Linda S. Birnbaum

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