Introducing the Chiral Transient Directing Group Strategy to Rhodium(III)‐Catalyzed Asymmetric C−H Activation

2019 ◽  
Vol 25 (18) ◽  
pp. 4688-4694 ◽  
Author(s):  
Guozhu Li ◽  
Jijun Jiang ◽  
Hui Xie ◽  
Jun Wang
Keyword(s):  
Group Strategy ◽  
Directing Group

scholarly journals Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy

2021 ◽  
Author(s):  
Sara Kopf ◽  
Helfried Neumann ◽  
Matthias Beller
Keyword(s):  
Group Strategy ◽  
One Step ◽  
Directing Group

A shortcut to ortho-deuterated aldehydes: a catalytic directing group enables the manganese-catalyzed C–H activation and deuteration of benzaldehydes in one step.

A Transient Directing Group Strategy Enables Enantioselective Multicomponent Organofluorine Synthesis

2021 ◽  
Author(s):  
Zhonglin Liu ◽  
Lucas J. Oxtoby ◽  
Mingyu Liu ◽  
Zi-Qi Li ◽  
Van T. Tran ◽  
...  
Keyword(s):  
Group Strategy ◽  
Directing Group

Synthesis of Functionalized Triphenylenes via a Traceless Directing Group Strategy

2018 ◽  
Vol 20 (6) ◽  
pp. 1491-1495 ◽  
Author(s):  
Shuai Yang ◽  
Feng Wang ◽  
Yanqi Wu ◽  
Wenkai Hua ◽  
Fengzhi Zhang
Keyword(s):  
Group Strategy ◽  
Directing Group

Ir-catalyzed selective dehydrogenative cross-coupling of aryls with o-carboranes via a mixed directing-group strategy

2020 ◽  
Vol 56 (51) ◽  
pp. 7001-7004 ◽  
Author(s):  
Yu Chen ◽  
Yangjian Quan ◽  
Zuowei Xie
Keyword(s):  
Cross Coupling ◽  
Group Strategy ◽  
Dehydrogenative Coupling ◽  
Directing Group

Ir-catalyzed highly selective B–H/C–H cross dehydrogenative coupling between o-carboranes and (hetero)aryls has been achieved using a mixed directing-group strategy.

scholarly journals A Transient‐Directing‐Group Strategy Enables Enantioselective Reductive Heck Hydroarylation of Alkenes

2020 ◽  
Vol 59 (23) ◽  
pp. 8885-8890 ◽  
Author(s):  
Lucas J. Oxtoby ◽  
Zi‐Qi Li ◽  
Van T. Tran ◽  
Tuğçe G. Erbay ◽  
Ruohan Deng ◽  
...  
Keyword(s):  
Group Strategy ◽  
Directing Group

Rhodium(iii)-catalyzed indole synthesis at room temperature using the transient oxidizing directing group strategy

2019 ◽  
Vol 55 (64) ◽  
pp. 9547-9550 ◽  
Author(s):  
Yaping Shang ◽  
Krishna Jonnada ◽  
Subhash Laxman Yedage ◽  
Hua Tu ◽  
Xiaofeng Zhang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Nitroso Group ◽  
Group Strategy ◽  
Internal Alkynes ◽  
Directing Group ◽  
Catalyzed Reactions ◽  
Indole Synthesis

Rh-Catalyzed reactions of N-alkyl anilines with internal alkynes at room temperature have been developed using an in situ generated N-nitroso group as a transient oxidizing directing group.

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