In Situ Tracking of Dynamic NO Capture through a Crystal-to-Crystal Transformation from a Gate-Open-Type Chain Porous Coordination Polymer to a NO-Adducted Discrete Isomer

2019 ◽  
Vol 25 (12) ◽  
pp. 3020-3031 ◽  
Author(s):  
Jun Zhang ◽  
Wataru Kosaka ◽  
Susumu Kitagawa ◽  
Masaki Takata ◽  
Hitoshi Miyasaka
Keyword(s):  
Coordination Polymer ◽  
Open Type ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

Solvent-triggered single-crystal-to-single-crystal transformation from a monomeric to polymeric copper(II) complex based on an aza macrocyclic ligand

2020 ◽  
Vol 76 (2) ◽  
pp. 225-232 ◽  
Author(s):  
Jong Won Shin ◽  
Ah Rim Jeong ◽  
Younghak Kim ◽  
Dae-Woong Kim ◽  
Sang-Geul Lee ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Self Assembly ◽  
Macrocyclic Ligand ◽  
Adsorption Behaviour ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystal Transformation ◽  
Hydrogen Bonding Interactions

Reversible solvent-triggered single-crystal-to-single-crystal (SCSC) transformations are observed between two copper(II) azamacrocyclic complexes: [Cu(C16H38N6)(H2O)2](C12H6O4) (1) and [Cu(C16H38N6)(C12H6O4)] (2). Complex (1) was prepared via self-assembly of a copper(II) azamacrocyclic complex containing butyl pendant groups, [Cu(C16H38N6)(ClO4)2], with 2,7-naphthalenedicarboxylic acid. When monomeric compound (1) was immersed in CH3OH, coordination polymer (2) was obtained, indicating a solvent-triggered SCSC transformation. Furthermore, when (2) was immersed in water, an reverse SCSC transformation from (2) to (1) occurred. Complex (1) presents a 3D supramolecular structure formed via intermolecular hydrogen-bonding interactions, whereas complex (2) features a 1D zigzag coordination polymer. The reversible SCSC transformation of (1) and (2) was characterized using single-crystal X-ray diffraction and in situ powder X-ray diffraction techniques. Despite its poor porosity, complex (2) displayed interesting CO2 adsorption behaviour under CO2 gas.

In Situ Observation of Gating Phenomena in the Flexible Porous Coordination Polymer Zn2(BPnDC)2(bpy) (SNU-9) in a Combined Diffraction and Gas Adsorption Experiment

2014 ◽  
Vol 53 (3) ◽  
pp. 1513-1520 ◽  
Author(s):  
Volodymyr Bon ◽  
Irena Senkovska ◽  
Dirk Wallacher ◽  
Daniel M. Többens ◽  
Ivo Zizak ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Gas Adsorption ◽  
In Situ Observation ◽  
Adsorption Experiment ◽  
Porous Coordination Polymer

scholarly journals Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer

2014 ◽  
Vol 14 (11) ◽  
pp. 5585-5592 ◽  
Author(s):  
Rashmi A. Agarwal ◽  
Soumya Mukherjee ◽  
E. Carolina Sañudo ◽  
Sujit K. Ghosh ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Gas Adsorption ◽  
Three Dimensional ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

Highly responsive nature of porous coordination polymer surfaces imaged by in situ atomic force microscopy

2018 ◽  
Vol 11 (2) ◽  
pp. 109-116 ◽  
Author(s):  
Nobuhiko Hosono ◽  
Aya Terashima ◽  
Shinpei Kusaka ◽  
Ryotaro Matsuda ◽  
Susumu Kitagawa
Keyword(s):  
Atomic Force Microscopy ◽  
Coordination Polymer ◽  
Polymer Surfaces ◽  
Force Microscopy ◽  
Atomic Force ◽  
Porous Coordination Polymer

Oriented Films of Porous Coordination Polymer Prepared by Repeated in Situ Crystallization

2008 ◽  
Vol 20 (9) ◽  
pp. 2887-2889 ◽  
Author(s):  
Masaru Kubo ◽  
Watcharop Chaikittisilp ◽  
Tatsuya Okubo
Keyword(s):  
Coordination Polymer ◽  
Oriented Films ◽  
In Situ Crystallization ◽  
Porous Coordination Polymer

Double-step CO2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework

2015 ◽  
Vol 44 (22) ◽  
pp. 10141-10145 ◽  
Author(s):  
Wei-Ping Wu ◽  
Zhi-Sen Li ◽  
Bo Liu ◽  
Ping Liu ◽  
Zheng-Ping Xi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Room Temperature ◽  
Double Step ◽  
Co2 Sorption ◽  
Porous Framework ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

A new 2D highly flexible and breathing porous coordination polymer has been synthesized, which exhibits selective and double-step hysteretic adsorption for CO2, and shows a single-crystal-to-single-crystal transformation induced by CH2Cl2 at room temperature.

scholarly journals Pressure-induced Jahn-Teller Switch in the Homoleptic Hybrid Perovskite [(CH3)2NH2]Cu(HCOO)3: Orbital Reordering by Unconventional Degrees of Freedom

2021 ◽  
Author(s):  
Rebecca Scatena ◽  
Michał Andrzejewski ◽  
Roger D Johnson ◽  
Piero Macchi
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Coordination Polymer ◽  
Degrees Of Freedom ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hybrid Perovskite ◽  
Jahn Teller

Through in-situ, high-pressure x-ray diffraction experiments we have shown that the homoleptic perovskite-like coordination polymer [(CH3)2NH2]Cu(HCOO)3 undergoes a pressure-induced orbital reordering phase transition above 5.20 GPa. This transition is distinct...

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