How does the Environment Influence a Given Cation? A Systematic Investigation of [Co(CO) 5 ] + in Gas Phase, Solution, and Solid State

2018 ◽  
Vol 24 (72) ◽  
pp. 19348-19360 ◽  
Author(s):  
Stefan C. Meier ◽  
Daniel Himmel ◽  
Ingo Krossing
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Systematic Investigation ◽  
Phase Solution ◽  
Environment Influence

ChemInform Abstract: 1,2-Diphenylcycloalkenes: Electronic and Geometric Structures in the Gas Phase, Solution, and Solid State.

ChemInform ◽  
1988 ◽  
Vol 19 (45) ◽  
Author(s):  
G. HOHLNEICHER ◽  
M. MUELLER ◽  
M. DEMMER ◽  
J. LEX ◽  
J. H. PENN ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Geometric Structures ◽  
Phase Solution ◽  
Electronic And Geometric Structures

scholarly journals Structural diversity in the host–guest complexes of the antifolate pemetrexed with native cyclodextrins: gas phase, solution and solid state studies

2017 ◽  
Vol 13 ◽  
pp. 2252-2263 ◽  
Author(s):  
Magdalena Ceborska ◽  
Magdalena Zimnicka ◽  
Aneta Aniela Kowalska ◽  
Kajetan Dąbrowa ◽  
Barbara Repeć
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Structural Diversity ◽  
2D Nmr ◽  
Association Constants ◽  
Inclusion Type ◽  
Guest Molecules ◽  
Type Complex ◽  
The Stability ◽  
Phase Solution

The complexation of the antifolate pemetrexed (PTX) with native cyclodextrins was studied. This process, along with the findings gathered for the structurally related folic acid was treated as a model for exploiting host–guest interactions of this class of guest molecules in the gas phase, in solution and in the solid state. Mass spectrometry was employed for the investigation of the architecture and relative gas-phase stabilities of these supramolecular complexes. The mode of complexation was further tracked by 1D and 2D NMR proving the formation of the exclusion-type complex with α-CD and pseudorotaxane inclusion-type complexes with β-, and γ-CDs. UV–vis titrations at pH 7.4 gave association constants for the obtained complexes. The stability of the complexes increases in the series: α-CD/PTX < γ-CD/PTX << β-CD/PTX. The association of PTX with a monomer cyclodextrin equivalent – methyl α-D-glucopyranoside – was investigated for a deeper understanding of the type of host–guest interactions. Solid state studies of PTX/CDs were performed using FTIR–ATR and Raman spectroscopy techniques.

Gas Phase, Solution, and Solid State Alkali Ion Binding by the [NbE8]3- (E: As, Sb) Complexes: Synthesis, Structure, and Spectroscopy.

ChemInform ◽  
2004 ◽  
Vol 35 (36) ◽  
Author(s):  
Banu Kesanli ◽  
James Fettinger ◽  
Brian Scott ◽  
Bryan Eichhorn
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Ion Binding ◽  
Phase Solution ◽  
Alkali Ion

1,2-Diphenylcycloalkenes: electronic and geometric structures in the gas phase, solution, and solid state

1988 ◽  
Vol 110 (14) ◽  
pp. 4483-4494 ◽  
Author(s):  
Georg. Hohlneicher ◽  
Martin. Mueller ◽  
Monika. Demmer ◽  
Johann. Lex ◽  
John H. Penn ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Geometric Structures ◽  
Phase Solution ◽  
Electronic And Geometric Structures

Gas Phase, Solution, and Solid State Alkali Ion Binding by the [NbE8]3-(E = As, Sb) Complexes:  Synthesis, Structure, and Spectroscopy

2004 ◽  
Vol 43 (13) ◽  
pp. 3840-3846 ◽  
Author(s):  
Banu Kesanli ◽  
James Fettinger ◽  
Brian Scott ◽  
Bryan Eichhorn
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Ion Binding ◽  
Phase Solution ◽  
Alkali Ion

Ab initiostudy of tautomerism and of basicity center preference in histamine, from gas phase to solution-comparison with experimental data (gas phase, solution, solid state)

2003 ◽  
Vol 16 (10) ◽  
pp. 783-796 ◽  
Author(s):  
Ewa D. Raczyńska ◽  
Małgorzata Darowska ◽  
Michał K. Cyrański ◽  
Mariusz Makowski ◽  
Tomasz Rudka ◽  
...  
Keyword(s):  
Experimental Data ◽  
Solid State ◽  
Gas Phase ◽  
Phase Solution ◽  
Comparison With Experimental Data

Spontaneous Generation of Stable Pnictinyl Radicals from “Jack-in-the-Box” Dipnictines:  A Solid-State, Gas-Phase, and Theoretical Investigation of the Origins of Steric Stabilization1

2001 ◽  
Vol 123 (37) ◽  
pp. 9045-9053 ◽  
Author(s):  
Sarah L. Hinchley ◽  
Carole A. Morrison ◽  
David W. H. Rankin ◽  
Charles L. B. Macdonald ◽  
Robert J. Wiacek ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Theoretical Investigation ◽  
Spontaneous Generation

Intramolecular London Dispersion Interaction Effects on Gas-Phase and Solid-State Structures of Diamondoid Dimers

2017 ◽  
Vol 139 (46) ◽  
pp. 16696-16707 ◽  
Author(s):  
Andrey A. Fokin ◽  
Tatyana S. Zhuk ◽  
Sebastian Blomeyer ◽  
Cristóbal Pérez ◽  
Lesya V. Chernish ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Interaction Effects ◽  
Dispersion Interaction ◽  
London Dispersion ◽  
Solid State Structures

ChemInform Abstract: Are the Compounds InH3 and TlH3 Stable Gas Phase or Solid State Species?

ChemInform ◽  
2010 ◽  
Vol 27 (28) ◽  
pp. no-no
Author(s):  
P. HUNT ◽  
P. SCHWERDTFEGER
Keyword(s):  
Solid State ◽  
Gas Phase
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