Metal–Organic Framework (MOF)‐Based Materials as Heterogeneous Catalysts for C−H Bond Activation

2018 ◽  
Author(s):  
Mengjia Liu ◽  
Jie Wu ◽  
Hongwei Hou
Keyword(s):  
Heterogeneous Catalysts ◽  
Bond Activation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework

2016 ◽  
Vol 138 (32) ◽  
pp. 10232-10237 ◽  
Author(s):  
Robert J. Comito ◽  
Keith J. Fritzsching ◽  
Benjamin J. Sundell ◽  
Klaus Schmidt-Rohr ◽  
Mircea Dincă
Keyword(s):  
Cation Exchange ◽  
Heterogeneous Catalysts ◽  
Olefin Polymerization ◽  
Metal Organic Framework ◽  
Single Site ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Copper-catalyzed one-pot domino reactions via C–H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal–organic framework catalysis

RSC Advances ◽  
2018 ◽  
Vol 8 (55) ◽  
pp. 31455-31464 ◽  
Author(s):  
Ha V. Dang ◽  
Hoang T. B. Le ◽  
Loan T. B. Tran ◽  
Hiep Q. Ha ◽  
Ha V. Le ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Bond Activation ◽  
Metal Organic Framework ◽  
Domino Reactions ◽  
One Pot ◽  
Metal Organic ◽  
Organic Framework

Cu2(OBA)2(BPY) metal–organic framework was utilized as a productive heterogeneous catalyst for the synthesis of 3-aroylquinolines via one-pot domino reactions of 2-aminobenzylalcohols with propiophenones.

An Efficient and Reusable Multifunctional Composite Magnetic Nanocatalyst for Knoevenagel Condensation

Synlett ◽  
2019 ◽  
Vol 30 (06) ◽  
pp. 699-702 ◽  
Author(s):  
Yu Hu ◽  
Nan Yao ◽  
Jin Tan ◽  
Yang Liu
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Knoevenagel Condensation ◽  
Metal Organic Framework ◽  
Catalytic Performance ◽  
Significant Loss ◽  
Magnetic Nanocatalyst ◽  
Metal Organic ◽  
Nife2o4 Nanoparticles ◽  
Organic Framework

A range of multifunctional magnetic metal–organic framework nanomaterials consisting of various mass ratios of the metal–organic framework MIL-53(Fe) and magnetic SiO2@NiFe2O4 nanoparticles were designed, prepared, characterized, and evaluated as heterogeneous catalysts for the Knoevenagel condensation. The as-fabricated nanomaterials, especially the nanocatalyst MIL-53(Fe)@SiO2@NiFe2O4(1.0), showed good catalytic performance in the Knoevenagel condensation at room temperature as a result of synergistic interaction between the Lewis acid iron sites of MIL-53(Fe) and the active sites of the magnetic SiO2@NiFe2O4 nanoparticles. In addition, the heterogeneous catalyst was readily recovered and a recycling test showed that it could be reused for five times without significant loss of its catalytic activity, making it economical and environmentally friendly.

Sign in / Sign up

Export Citation Format

Share Document