Ruthenium Complexation in an Aluminium Metal-Organic Framework and Its Application in Alcohol Oxidation Catalysis

2012 ◽  
Vol 18 (48) ◽  
pp. 15337-15344 ◽  
Author(s):  
Fabian Carson ◽  
Santosh Agrawal ◽  
Mikaela Gustafsson ◽  
Agnieszka Bartoszewicz ◽  
Francisca Moraga ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Alcohol Oxidation ◽  
Oxidation Catalysis ◽  
Metal Organic ◽  
Aluminium Metal ◽  
Organic Framework

scholarly journals Post Synthetic Defect Engineering of UiO-66 Metal–Organic Framework with An Iridium(III)-HEDTA Complex and Application in Water Oxidation Catalysis

Inorganics ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 123 ◽  
Author(s):  
Giordano Gatto ◽  
Alceo Macchioni ◽  
Roberto Bondi ◽  
Fabio Marmottini ◽  
Ferdinando Costantino
Keyword(s):  
Water Oxidation ◽  
Metal Organic Framework ◽  
Oxidation Catalysis ◽  
Partial Substitution ◽  
Iridium Complexes ◽  
Cerium Ammonium Nitrate ◽  
Highly Active ◽  
Water Oxidation Catalysis ◽  
Metal Organic ◽  
Organic Framework

Clean production of renewable fuels is a great challenge of our scientific community. Iridium complexes have demonstrated a superior catalytic activity in the water oxidation (WO) reaction, which is a crucial step in water splitting process. Herein, we have used a defective zirconium metal–organic framework (MOF) with UiO-66 structure as support of a highly active Ir complex based on EDTA with the formula [Ir(HEDTA)Cl]Na. The defects are induced by the partial substitution of terephthalic acid with smaller formate groups. Anchoring of the complex occurs through a post-synthetic exchange of formate anions, coordinated at the zirconium clusters of the MOF, with the free carboxylate group of the [Ir(HEDTA)Cl]− complex. The modified material was tested as a heterogeneous catalyst for the WO reaction by using cerium ammonium nitrate (CAN) as the sacrificial agent. Although turnover frequency (TOF) and turnover number (TON) values are comparable to those of other iridium heterogenized catalysts, the MOF exhibits iridium leaching not limited at the first catalytic run, as usually observed, suggesting a lack of stability of the hybrid system under strong oxidative conditions.

scholarly journals An exceptionally stable octacobalt-cluster-based metal–organic framework for enhanced water oxidation catalysis

2019 ◽  
Vol 10 (42) ◽  
pp. 9859-9864 ◽  
Author(s):  
Ning-Yu Huang ◽  
Jian-Qiang Shen ◽  
Zi-Ming Ye ◽  
Wei-Xiong Zhang ◽  
Pei-Qin Liao ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Adsorption Energy ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
Oxidation Catalysis ◽  
Cobalt Ions ◽  
Water Oxidation Catalysis ◽  
Metal Organic ◽  
Kinetics Of ◽  
Organic Framework

The site, capping four coplanar cobalt ions, has a near-optimal OH− adsorption energy, which is beneficial to accelerate the reaction kinetics of water oxidation catalysis.

scholarly journals Back Cover: Multi-frequency (S, X, Q and W-band) EPR and ENDOR Study of Vanadium(IV) Incorporation in the Aluminium Metal-Organic Framework MIL-53 (ChemPhysChem 14/2015)

ChemPhysChem ◽  
2015 ◽  
Vol 16 (14) ◽  
pp. 3118-3118 ◽  
Author(s):  
Irena Nevjestić ◽  
Hannes Depauw ◽  
Karen Leus ◽  
Vidmantas Kalendra ◽  
Ignacio Caretti ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Back Cover ◽  
W Band ◽  
Metal Organic ◽  
Aluminium Metal ◽  
Organic Framework

scholarly journals Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework

2014 ◽  
Vol 136 (13) ◽  
pp. 4965-4973 ◽  
Author(s):  
Honghan Fei ◽  
JaeWook Shin ◽  
Ying Shirley Meng ◽  
Mario Adelhardt ◽  
Jörg Sutter ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Oxidation Catalysis ◽  
Metal Organic ◽  
Organic Framework

A mesoporous aluminium metal–organic framework with 3 nm open pores

2013 ◽  
Vol 1 (2) ◽  
pp. 324-329 ◽  
Author(s):  
Sheng-Han Lo ◽  
Ching-Hsuan Chien ◽  
Yu-Lun Lai ◽  
Chun-Chuen Yang ◽  
Jey Jau Lee ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Aluminium Metal ◽  
Organic Framework

Incorporation of a Ru complex into an amine-functionalized metal–organic framework for enhanced activity in photocatalytic aerobic benzyl alcohol oxidation

2019 ◽  
Vol 9 (6) ◽  
pp. 1511-1517 ◽  
Author(s):  
Yusuke Isaka ◽  
Yoshifumi Kondo ◽  
Yasutaka Kuwahara ◽  
Kohsuke Mori ◽  
Hiromi Yamashita
Keyword(s):  
Benzyl Alcohol ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Alcohol Oxidation ◽  
Benzyl Alcohol Oxidation ◽  
Ru Complex ◽  
Amine Functionalized ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic ◽  
Organic Framework

Encapsulation of [Ru(bpy)3]2+ in the cavity of a metal–organic framework was found to enhance its activity in the photocatalytic aerobic oxidation of benzyl alcohol.

scholarly journals ChemInform Abstract: Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal-Organic Framework.

ChemInform ◽  
2014 ◽  
Vol 45 (41) ◽  
pp. no-no
Author(s):  
Honghan Fei ◽  
JaeWook Shin ◽  
Ying Shirley Meng ◽  
Mario Adelhardt ◽  
Joerg Sutter ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Oxidation Catalysis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Highly efficient metal organic framework (MOF)-based copper catalysts for the base-free aerobic oxidation of various alcohols

RSC Advances ◽  
2017 ◽  
Vol 7 (29) ◽  
pp. 17806-17812 ◽  
Author(s):  
Abu Taher ◽  
Dong Wook Kim ◽  
Ik-Mo Lee
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Alcohol Oxidation ◽  
Copper Catalysts ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

Copper containing metal organic frameworks (MOFs) are found to be highly efficient heterogeneous catalysts for alcohol oxidation.

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