Efficient and recyclable novel Ni‐based metal–organic framework nanostructure as catalyst for the cascade reaction of alcohol oxidation–Knoevenagel condensation

2017 ◽  
Vol 32 (2) ◽  
Author(s):  
Sima Aryanejad ◽  
Ghodsieh Bagherzade ◽  
Alireza Farrokhi
Keyword(s):  
Knoevenagel Condensation ◽  
Metal Organic Framework ◽  
Alcohol Oxidation ◽  
Cascade Reaction ◽  
Metal Organic ◽  
Organic Framework

Synthesis and click modification of an azido-functionalized Zr(iv) metal–organic framework and a catalytic study

RSC Advances ◽  
2015 ◽  
Vol 5 (2) ◽  
pp. 893-900 ◽  
Author(s):  
Xiu-Chun Yi ◽  
Fu-Gui Xi ◽  
Yan Qi ◽  
En-Qing Gao
Keyword(s):  
Knoevenagel Condensation ◽  
Metal Organic Framework ◽  
Base Catalyst ◽  
Click Reactions ◽  
Metal Organic ◽  
Organic Framework

A new azido-functionalized Zr(iv) MOF was synthesized and further functionalized via post-synthetic click reactions, and the amino-tagged MOF is a base catalyst for Knoevenagel condensation.

An Efficient and Reusable Multifunctional Composite Magnetic Nanocatalyst for Knoevenagel Condensation

Synlett ◽  
2019 ◽  
Vol 30 (06) ◽  
pp. 699-702 ◽  
Author(s):  
Yu Hu ◽  
Nan Yao ◽  
Jin Tan ◽  
Yang Liu
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Knoevenagel Condensation ◽  
Metal Organic Framework ◽  
Catalytic Performance ◽  
Significant Loss ◽  
Magnetic Nanocatalyst ◽  
Metal Organic ◽  
Nife2o4 Nanoparticles ◽  
Organic Framework

A range of multifunctional magnetic metal–organic framework nanomaterials consisting of various mass ratios of the metal–organic framework MIL-53(Fe) and magnetic SiO2@NiFe2O4 nanoparticles were designed, prepared, characterized, and evaluated as heterogeneous catalysts for the Knoevenagel condensation. The as-fabricated nanomaterials, especially the nanocatalyst MIL-53(Fe)@SiO2@NiFe2O4(1.0), showed good catalytic performance in the Knoevenagel condensation at room temperature as a result of synergistic interaction between the Lewis acid iron sites of MIL-53(Fe) and the active sites of the magnetic SiO2@NiFe2O4 nanoparticles. In addition, the heterogeneous catalyst was readily recovered and a recycling test showed that it could be reused for five times without significant loss of its catalytic activity, making it economical and environmentally friendly.

Incorporation of a Ru complex into an amine-functionalized metal–organic framework for enhanced activity in photocatalytic aerobic benzyl alcohol oxidation

2019 ◽  
Vol 9 (6) ◽  
pp. 1511-1517 ◽  
Author(s):  
Yusuke Isaka ◽  
Yoshifumi Kondo ◽  
Yasutaka Kuwahara ◽  
Kohsuke Mori ◽  
Hiromi Yamashita
Keyword(s):  
Benzyl Alcohol ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Alcohol Oxidation ◽  
Benzyl Alcohol Oxidation ◽  
Ru Complex ◽  
Amine Functionalized ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic ◽  
Organic Framework

Encapsulation of [Ru(bpy)3]2+ in the cavity of a metal–organic framework was found to enhance its activity in the photocatalytic aerobic oxidation of benzyl alcohol.

Nanozyme-mediated cascade reaction based on metal-organic framework for synergetic chemo-photodynamic tumor therapy

2020 ◽  
Vol 328 ◽  
pp. 631-639
Author(s):  
Shu Sheng ◽  
Feng Liu ◽  
Lin Lin ◽  
Nan Yan ◽  
Yanbing Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Tumor Therapy ◽  
Cascade Reaction ◽  
Metal Organic ◽  
Organic Framework

Ruthenium Complexation in an Aluminium Metal-Organic Framework and Its Application in Alcohol Oxidation Catalysis

2012 ◽  
Vol 18 (48) ◽  
pp. 15337-15344 ◽  
Author(s):  
Fabian Carson ◽  
Santosh Agrawal ◽  
Mikaela Gustafsson ◽  
Agnieszka Bartoszewicz ◽  
Francisca Moraga ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Alcohol Oxidation ◽  
Oxidation Catalysis ◽  
Metal Organic ◽  
Aluminium Metal ◽  
Organic Framework
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