Alkenylborane-Derived Frustrated Lewis Pairs: Metal-Free Catalytic Hydrogenation Reactions of Electron-Deficient Alkenes

2012 ◽  
Vol 31 (15) ◽  
pp. 5638-5649 ◽  
Author(s):  
J. Sreedhar Reddy ◽  
Bao-Hua Xu ◽  
Tayseer Mahdi ◽  
Roland Fröhlich ◽  
Gerald Kehr ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Hydrogenation Reactions ◽  
Lewis Pairs

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

2011 ◽  
Vol 50 (24) ◽  
pp. 12338-12348 ◽  
Author(s):  
Douglas W. Stephan ◽  
Sharonna Greenberg ◽  
Todd W. Graham ◽  
Preston Chase ◽  
Jeff J. Hastie ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Lewis Pairs

Development of [3]ferrocenophane-derived N/B frustrated Lewis pairs for the metal-free catalytic hydrogenation of imines

2019 ◽  
Vol 49 (4) ◽  
pp. 522-528
Author(s):  
Zhentao Pan ◽  
Hui Wang ◽  
Fei Ling ◽  
Lian Xiao ◽  
Dingguo Song ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Lewis Pairs

Development of silica-supported frustrated Lewis pairs: highly active transition metal-free catalysts for the Z-selective reduction of alkynes

2016 ◽  
Vol 6 (3) ◽  
pp. 882-889 ◽  
Author(s):  
Kai C. Szeto ◽  
Wissam Sahyoun ◽  
Nicolas Merle ◽  
Jessica Llop Castelbou ◽  
Nicolas Popoff ◽  
...  
Keyword(s):  
Transition Metal ◽  
Lewis Acid ◽  
Selective Reduction ◽  
Frustrated Lewis Pairs ◽  
Acid Base ◽  
Metal Free ◽  
Highly Active ◽  
Active Transition ◽  
Lewis Pairs

Supported Lewis acid/base systems based have been prepared and characterized.

Reversible, metal-free hydrogenactivation by frustrated Lewis pairs

2011 ◽  
Vol 40 (5) ◽  
pp. 1091-1097 ◽  
Author(s):  
Chunfang Jiang ◽  
Olivier Blacque ◽  
Thomas Fox ◽  
Heinz Berke
Keyword(s):  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Lewis Pairs

Understanding the Reactivity of Geminal P/B and P/Al Frustrated Lewis Pairs in CO2 Addition and H2 Activation

2021 ◽  
Author(s):  
Muhammad Dzulfahmi Ramadhan ◽  
Panida Surawatanawong
Keyword(s):  
Transition Metal ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Co2 Addition ◽  
Lewis Pairs

Understanding CO2 addition and H2 activation by geminal P/Z (Z = B, Al) frustrated Lewis pairs (FLPs) is crucial for the development of transition metal-free catalysts for hydrogenation of unsaturated...

Metal-Free Iodoperfluoroalkylation: Photocatalysis versus Frustrated Lewis Pair Catalysis

Synthesis ◽  
2020 ◽  
Vol 53 (01) ◽  
pp. 123-134
Author(s):  
Constantin Czekelius ◽  
Lucas Helmecke ◽  
Michael Spittler ◽  
Bernd M. Schmidt
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Reaction Pathways ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Comprehensive Account ◽  
Frustrated Lewis Pair ◽  
Catalytic Metal ◽  
Lewis Pairs

A comparison of two catalytic, metal-free iodoperfluoro­alkylation protocols is presented. Frustrated Lewis pairs [ t Bu3P/B(C6F5)3] or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes as well as insights into the mechanistic details of both reaction pathways are provided.

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