Synthesis of Early-Transition-Metal Carbide and Nitride Nanoparticles through the Urea Route and Their Use as Alkylation Catalysts

2009 ◽  
Vol 15 (44) ◽  
pp. 11999-12004 ◽  
Author(s):  
Weitang Yao ◽  
Philippe Makowski ◽  
Cristina Giordano ◽  
Frédéric Goettmann
Keyword(s):  
Transition Metal ◽  
Transition Metal Carbide ◽  
Metal Carbide ◽  
Early Transition Metal ◽  
Early Transition

CH Bond Activation by Early Transition Metal Carbide Cluster Anion MoC3−

2015 ◽  
Vol 21 (49) ◽  
pp. 17748-17756 ◽  
Author(s):  
Zi-Yu Li ◽  
Lianrui Hu ◽  
Qing-Yu Liu ◽  
Chuan-Gang Ning ◽  
Hui Chen ◽  
...  
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Cluster Anion ◽  
Transition Metal Carbide ◽  
Metal Carbide ◽  
Early Transition Metal ◽  
Carbide Cluster ◽  
Early Transition

scholarly journals An expeditious synthesis of early transition metal carbide nanoparticles on graphitic carbons

2016 ◽  
Vol 52 (61) ◽  
pp. 9546-9549 ◽  
Author(s):  
Debora Ressnig ◽  
Simona Moldovan ◽  
Ovidiu Ersen ◽  
Patricia Beaunier ◽  
David Portehault ◽  
...  
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Metal Chloride ◽  
Transition Metal Carbide ◽  
Metal Carbide ◽  
Early Transition Metal ◽  
Crystalline Metal ◽  
Early Transition

Fast and furious: the reaction of potassium graphites with metal chloride is initiated at room temperature and proceeds expeditiously to yield supported crystalline metal carbide nanoparticles.

scholarly journals Tuning transition metal carbide activity by surface metal alloying: a case study on CO2capture and activation

2018 ◽  
Vol 20 (34) ◽  
pp. 22179-22186 ◽  
Author(s):  
Martí López ◽  
Luke Broderick ◽  
John J. Carey ◽  
Francesc Viñes ◽  
Michael Nolan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Density Functional ◽  
State Of The Art ◽  
Transition Metal Carbide ◽  
Metal Carbide ◽  
Metal Carbides ◽  
Early Transition Metal ◽  
Transition Metal Carbides ◽  
Surface Metal

The CO2capture and activation on early transition metal carbides can be fine-tuned by surface doping of similar metals as evidenced by state-of-the-art density functional simulations of the adsorption and desorption rates on suited models.

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