π-Stacking Enhanced Dynamic and Redox-Switchable Self-Assembly of Donor-Acceptor Metallo-[2]Catenanes from Diimide Derivatives and Crown Ethers

2008 ◽  
Vol 14 (33) ◽  
pp. 10211-10218 ◽  
Author(s):  
Gayane Koshkakaryan ◽  
Kumar Parimal ◽  
Jiuming He ◽  
Xiyun Zhang ◽  
Zeper Abliz ◽  
...  
Keyword(s):  
Crown Ethers ◽  
Self Assembly ◽  
Π Stacking ◽  
Donor Acceptor

Self-assembly of a C60 derivative bearing an ammonium unit with porphyrin-crown ether conjugates

2005 ◽  
Vol 09 (11) ◽  
pp. 760-768 ◽  
Author(s):  
Jean-François Nierengarten ◽  
Nathalie Solladié
Keyword(s):  
Crown Ether ◽  
Crown Ethers ◽  
Self Assembly ◽  
Association Constant ◽  
Supramolecular Complex ◽  
Supramolecular System ◽  
Ammonium Derivative ◽  
Dramatic Effect ◽  
Recognition Element ◽  
Π Stacking

Our recent progresses in the synthesis and the study of supramolecular porphyrin-fullerene conjugates are reported. In particular, we show that π-stacking of the two chromophores can have a dramatic effect on recognition interactions in non-covalent C 60-porphyrin ensembles. Specifically, a supramolecular complex has been obtained from a porphyrin-crown ether conjugate and a methanofullerene derivative bearing an ammonium function. In addition to the ammonium-crown ether interaction, intramolecular stacking of the fullerene moiety and the porphyrin subunit has been evidenced in the supramolecular system. Due to this additional recognition element, the association constant ( K a ) for the complex is increased by two orders of magnitude when compared to K a values previously found for complexation of the fullerene-ammonium derivative with other crown ethers. Finally, non-covalent systems resulting from the association of the fullerene-ammonium derivative with porphyrins bearing two crown-ether subunits have been investigated. Intramolecular C 60-porphyrin interactions have also been observed within these supramolecular arrays. As a result, the 2:1 complexes are very stable.

High-Fidelity Self-Assembly of Crystalline and Parallel-Oriented Organic Thin Films by π–π Stacking from a Metal Surface

Langmuir ◽  
2014 ◽  
Vol 30 (33) ◽  
pp. 10050-10056 ◽  
Author(s):  
Daniel Skomski ◽  
Junyong Jo ◽  
Christopher D. Tempas ◽  
Seyong Kim ◽  
Dongwhan Lee ◽  
...  
Keyword(s):  
Thin Films ◽  
Metal Surface ◽  
Self Assembly ◽  
Organic Thin Films ◽  
High Fidelity ◽  
Π Stacking

Self-Assembly of a Donor–Acceptor Nanotube. A Strategy To Create Bicontinuous Arrays

2011 ◽  
Vol 133 (47) ◽  
pp. 19125-19130 ◽  
Author(s):  
Siyu Tu ◽  
Se Hye Kim ◽  
Jojo Joseph ◽  
David A. Modarelli ◽  
Jon R. Parquette
Keyword(s):  
Self Assembly ◽  
Donor Acceptor

Light harvesting vesicular donor–acceptor scaffold limits the rate of charge recombination in the presence of an electron donor

2014 ◽  
Vol 7 (5) ◽  
pp. 1661-1669 ◽  
Author(s):  
Rijo T. Cheriya ◽  
Ajith R. Mallia ◽  
Mahesh Hariharan
Keyword(s):  
Charge Transfer ◽  
Survival Time ◽  
Electron Donor ◽  
Self Assembly ◽  
Light Harvesting ◽  
Charge Recombination ◽  
Donor Acceptor

This work highlights the utility of π–π stacked self-assembly for enhanced survival time of charge transfer intermediates upon photoexcitation of donor–acceptor systems.

Donor/Acceptor Segregated π-Stacking Arrays by Use of Shish-Kebab-Type Polymeric Backbones: Highly Conductive Discotic Blends of Phthalocyaninatopolysiloxanes and Perylenediimides

2017 ◽  
Vol 50 (23) ◽  
pp. 9265-9275 ◽  
Author(s):  
Tsuneaki Sakurai ◽  
Satoru Yoneda ◽  
Shugo Sakaguchi ◽  
Kenichi Kato ◽  
Masaki Takata ◽  
...  
Keyword(s):  
Π Stacking ◽  
Donor Acceptor
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