Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks

2008 ◽  
Vol 14 (24) ◽  
pp. 7218-7235 ◽  
Author(s):  
Jing Wang ◽  
Zhuo-Jia Lin ◽  
Yong-Cong Ou ◽  
Yong Shen ◽  
Radovan Herchel ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry

Molecules ◽  
2020 ◽  
Vol 25 (24) ◽  
pp. 5950
Author(s):  
Steffen B. Mogensen ◽  
Mercedes K. Taylor ◽  
Ji-Woong Lee
Keyword(s):  
Coordination Chemistry ◽  
Reaction Mechanisms ◽  
Metal Organic Frameworks ◽  
Ring System ◽  
Membered Ring ◽  
Materials Chemistry ◽  
Structural Class ◽  
Basic Nitrogen ◽  
Metal Organic ◽  
Metal Catalyzed

Pyrazole, a member of the structural class of azoles, exhibits molecular properties of interest in pharmaceuticals and materials chemistry, owing to the two adjacent nitrogen atoms in the five-membered ring system. The weakly basic nitrogen atoms of deprotonated pyrazoles have been applied in coordination chemistry, particularly to access coordination polymers and metal-organic frameworks, and homocoupling reactions can in principle provide facile access to bipyrazole ligands. In this context, we summarize recent advances in homocoupling reactions of pyrazoles and other types of azoles (imidazoles, triazoles and tetrazoles) to highlight the utility of homocoupling reactions in synthesizing symmetric bi-heteroaryl systems compared with traditional synthesis. Metal-free reactions and transition-metal catalyzed homocoupling reactions are discussed with reaction mechanisms in detail.

Seaming the interfaces between topologically distinct metal–organic frameworks using random copolymer glues

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2121-2125 ◽  
Author(s):  
Fang Wang ◽  
Hongliang Wang ◽  
Tao Li
Keyword(s):  
Coordination Chemistry ◽  
Metal Organic Frameworks ◽  
Random Copolymer ◽  
Unit Cell ◽  
Random Copolymers ◽  
Unit Cell Parameters ◽  
Cell Parameters ◽  
Metal Organic ◽  
Distinct Unit

A series of random copolymers are used as molecular glues to bridge the interfaces between metal–organic frameworks with distinct unit cell parameters and coordination chemistry.

Magnetic coordination clusters and networks: synthesis and topological description

2010 ◽  
Vol 368 (1915) ◽  
pp. 1509-1536 ◽  
Author(s):  
George E. Kostakis ◽  
Ian J. Hewitt ◽  
Ayuk M. Ako ◽  
Valeriu Mereacre ◽  
Annie K. Powell
Keyword(s):  
Magnetic Properties ◽  
Coordination Chemistry ◽  
Single Molecule ◽  
Metal Organic Frameworks ◽  
New Approach ◽  
Topological Description ◽  
Metal Organic ◽  
Paramagnetic Ions

With the discovery of the phenomenon of single-molecule magnetism, coordination chemists have turned their attention to synthesizing cluster aggregates of paramagnetic ions. This has led to a plethora of coordination clusters with various topologies and diverse magnetic properties. In this paper, we present ways of describing and understanding such compounds as well as outlining a new approach, which we have recently developed, to describing cluster topology. Our approach is based upon and pays tribute to the huge contribution made to coordination chemistry through the development of the Schläfli symbols for describing architectures. To illustrate the developments that are taking place in modern coordination chemistry, we start with some basic definitions of relevance to what follows. Then we describe approaches to discovering new magnetically interesting 3d/4f clusters, assigning their topological descriptions. Finally, we show how the concepts behind the construction of metal–organic frameworks can be extended to using clusters as nodes in the frameworks to give super metal–organic frameworks.

Porosity tuning of carborane-based metal–organic frameworks (MOFs) via coordination chemistry and ligand design

2010 ◽  
Vol 364 (1) ◽  
pp. 266-271 ◽  
Author(s):  
Alexander M. Spokoyny ◽  
Omar K. Farha ◽  
Karen L. Mulfort ◽  
Joseph T. Hupp ◽  
Chad A. Mirkin
Keyword(s):  
Coordination Chemistry ◽  
Metal Organic Frameworks ◽  
Ligand Design ◽  
Metal Organic

scholarly journals Constructing new metal–organic frameworks with complicated ligands from “One-Pot” in situ reactions

2019 ◽  
Vol 10 (14) ◽  
pp. 3949-3955 ◽  
Author(s):  
Xiang-Jing Kong ◽  
Tao He ◽  
Yong-Zheng Zhang ◽  
Xue-Qian Wu ◽  
Si-Nan Wang ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
Metal Organic ◽  
In Situ Reactions

A “One-Pot” strategy has been developed to construct new metal–organic frameworks with complicated ligands from simple precursors by integrating organic and coordination chemistry.

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