scholarly journals Constructing new metal–organic frameworks with complicated ligands from “One-Pot” in situ reactions

2019 ◽  
Vol 10 (14) ◽  
pp. 3949-3955 ◽  
Author(s):  
Xiang-Jing Kong ◽  
Tao He ◽  
Yong-Zheng Zhang ◽  
Xue-Qian Wu ◽  
Si-Nan Wang ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
Metal Organic ◽  
In Situ Reactions

A “One-Pot” strategy has been developed to construct new metal–organic frameworks with complicated ligands from simple precursors by integrating organic and coordination chemistry.

scholarly journals Upcycling a Plastic Cup: One-Pot Synthesis of Lactate Containing Metal Organic Frameworks from Polylactic Acid

2019 ◽  
Author(s):  
Benjamin Slater ◽  
So-On Wong ◽  
Andrew Duckworth ◽  
Andrew J. P. White ◽  
Matthew R. Hill ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Chiral Separation ◽  
Additional Data ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic ◽  
Feed Source

<p>Waste PLA can be upcycled to metal organic frameworks of potential high value in a one-pot synthesis scheme, where PLA depolymerisation occurs <i>in-situ</i>. Three lactate based frameworks were succesfully synthesised and characterised from PLA as a feed source, including homochiral framework ZnBLD. The chiral separation ability of ZnBLD was maintained.<br></p><p><br></p><p>Additional data including the CIF file, the CheckCIF document, and the raw XRD spectra, are available from the Zenodo repository linked below.<br></p>

An in situ approach to functionalize metal–organic frameworks with tertiary aliphatic amino groups

2020 ◽  
Vol 56 (86) ◽  
pp. 13177-13180
Author(s):  
Fu-Gui Xi ◽  
Wei Sun ◽  
Zhi-yun Dong ◽  
Ning-Ning Yang ◽  
Teng Gong ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Amino Groups ◽  
One Pot ◽  
Metal Catalysis ◽  
Metal Organic

Tertiary aliphatic amino modified UiO-67/66(Zr), IRMOF-n(Zn) and MIL-101(Fe) were synthesized by a facile and efficient one-pot strategy under the corresponding metal catalysis.

scholarly journals Upcycling a Plastic Cup: One-Pot Synthesis of Lactate Containing Metal Organic Frameworks from Polylactic Acid

2019 ◽  
Author(s):  
Benjamin Slater ◽  
So-On Wong ◽  
Andrew Duckworth ◽  
Andrew J. P. White ◽  
Matthew R. Hill ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Chiral Separation ◽  
Additional Data ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic ◽  
Feed Source

<p>Waste PLA can be upcycled to metal organic frameworks of potential high value in a one-pot synthesis scheme, where PLA depolymerisation occurs <i>in-situ</i>. Three lactate based frameworks were succesfully synthesised and characterised from PLA as a feed source, including homochiral framework ZnBLD. The chiral separation ability of ZnBLD was maintained.<br></p><p><br></p><p>Additional data including the CIF file, the CheckCIF document, and the raw XRD spectra, are available from the Zenodo repository linked below.<br></p>

scholarly journals In situ X‐ray Diffraction Investigation of the Crystallisation of Perfluorinated Ce(IV)‐based Metal‐Organic Frameworks with UiO‐66 and MIL‐140 architectures

2021 ◽  
Author(s):  
Stephen J. I. Shearan ◽  
Jannick Jacobsen ◽  
Ferdinando Costantino ◽  
Roberto D’Amato ◽  
Dmitri Novikov ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic

scholarly journals Degradation Mechanism of Porous Metal-Organic Frameworks by In Situ Atomic Force Microscopy

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 722
Author(s):  
Ioanna Christodoulou ◽  
Tom Bourguignon ◽  
Xue Li ◽  
Gilles Patriarche ◽  
Christian Serre ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Degradation Mechanism ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Force Microscopy ◽  
Atomic Force ◽  
Metal Organic ◽  
The Media ◽  
Ph Conditions

In recent years, Metal-Organic Frameworks (MOFs) have attracted a growing interest for biomedical applications. The design of MOFs should take into consideration the subtle balance between stability and biodegradability. However, only few studies have focused on the MOFs’ stability in physiological media and their degradation mechanism. Here, we investigate the degradation of mesoporous iron (III) carboxylate MOFs, which are among the most employed MOFs for drug delivery, by a set of complementary methods. In situ AFM allowed monitoring with nanoscale resolution the morphological, dimensional, and mechanical properties of a series of MOFs in phosphate buffer saline and in real time. Depending on the synthetic route, the external surface presented either well-defined crystalline planes or initial defects, which influenced the degradation mechanism of the particles. Moreover, MOF stability was investigated under different pH conditions, from acidic to neutral. Interestingly, despite pronounced erosion, especially at neutral pH, the dimensions of the crystals were unchanged. It was revealed that the external surfaces of MOF crystals rapidly respond to in situ changes of the composition of the media they are in contact with. These observations are of a crucial importance for the design of nanosized MOFs for drug delivery applications.

scholarly journals A Facile One-Pot Approach to the Synthesis of Gd-Eu Based Metal-Organic Frameworks and Applications to Sensing of Fe3+ and Cr2O72− Ions

Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1679
Author(s):  
Roberta Puglisi ◽  
Anna L. Pellegrino ◽  
Roberto Fiorenza ◽  
Salvatore Scirè ◽  
Graziella Malandrino
Keyword(s):  
Surface Area ◽  
Metal Organic Frameworks ◽  
3D Structure ◽  
Inorganic Ions ◽  
Total Surface Area ◽  
One Pot ◽  
Green Approach ◽  
Metal Organic ◽  
Ft Ir ◽  
Xrd Patterns

Gadolinium metal-organic frameworks (Gd-MOFs) and Eu-doped Gd-MOFs have been synthesized through a one-pot green approach using commercially available reagents. The 1,4-benzenedicarboxylic acid (H2-BDC) and 2,6-naphthalenedicarboxylic acid (H2-NDC) were chosen as ditopic organic linkers to build the 3D structure of the network. The Gd-MOFs were characterized using powder X-ray diffraction (XRD), FT-IR spectroscopy, field emission scanning electron microscopy (FE-SEM) and N2 adsorption–desorption analysis. The Gd-MOF structures were attributed comparing the XRD patterns, supported by the FT-IR spectra, with data reported in the literature for Ln-MOFs of similar lanthanide ionic radius. FE-SEM characterization points to the effect of the duration of the synthesis to a more crystalline and organized structure, with grain dimensions increasing upon increasing reaction time. The total surface area of the MOFs has been determined from the application of the Brunauer–Emmett–Teller method. The study allowed us to correlate the processing conditions and ditopic linker dimension to the network surface area. Both Gd-MOF and Eu-doped Gd-MOF have been tested for sensing of the inorganic ions such as Fe3+ and Cr2O72−.

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