Spectroscopic Studies of Water-Soluble Porphyrins with Protein Encapsulated in Bis(2-ethylhexyl)sulfosuccinate (AOT) Reverse Micelles: Aggregation versus Complexation

2006 ◽  
Vol 12 (4) ◽  
pp. 1046-1057 ◽  
Author(s):  
Suzana M. Andrade ◽  
Sílvia M. B. Costa
Keyword(s):  
Reverse Micelles ◽  
Spectroscopic Studies ◽  
Water Soluble ◽  
Aot Reverse Micelles

Structural Effects of the β-Vinyl Linker in Pyridinium Porphyrins: Spectroscopic Studies in Organic Solvents and AOT Reverse Micelles

2013 ◽  
Vol 117 (48) ◽  
pp. 15023-15032 ◽  
Author(s):  
Vanda Vaz Serra ◽  
Suzana M. Andrade ◽  
Eduarda M. P. Silva ◽  
Artur M. S. Silva ◽  
Maria G. P. M. S. Neves ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Reverse Micelles ◽  
Spectroscopic Studies ◽  
Structural Effects ◽  
Aot Reverse Micelles

scholarly journals Formose reaction accelerated in aerosol-OT reverse micelles

2016 ◽  
Vol 12 ◽  
pp. 2663-2667 ◽  
Author(s):  
Makoto Masaoka ◽  
Tomohiro Michitaka ◽  
Akihito Hashidzume
Keyword(s):  
Reverse Micelles ◽  
Water Layer ◽  
Major Product ◽  
Hexadecyltrimethylammonium Bromide ◽  
Interfacial Water ◽  
Formose Reaction ◽  
Aerosol Ot ◽  
Aot Reverse Micelles ◽  
Triton X ◽  
C Nmr

The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in the formose reaction. The 13C NMR spectra for the products of the formose reaction using formaldehyde-13C as starting material are indicative of the formation of ethylene glycol as a major product.

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