scholarly journals Formose reaction accelerated in aerosol-OT reverse micelles

2016 ◽  
Vol 12 ◽  
pp. 2663-2667 ◽  
Author(s):  
Makoto Masaoka ◽  
Tomohiro Michitaka ◽  
Akihito Hashidzume
Keyword(s):  
Reverse Micelles ◽  
Water Layer ◽  
Major Product ◽  
Hexadecyltrimethylammonium Bromide ◽  
Interfacial Water ◽  
Formose Reaction ◽  
Aerosol Ot ◽  
Aot Reverse Micelles ◽  
Triton X ◽  
C Nmr

The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in the formose reaction. The 13C NMR spectra for the products of the formose reaction using formaldehyde-13C as starting material are indicative of the formation of ethylene glycol as a major product.

Synthesis and Stabilization of Gold Nanoparticles in Reverse Micelles of Aerosol OT and Triton X-100

2005 ◽  
Vol 67 (4) ◽  
pp. 485-490 ◽  
Author(s):  
M. G. Spirin ◽  
S. B. Brichkin ◽  
V. F. Razumov
Keyword(s):  
Gold Nanoparticles ◽  
Reverse Micelles ◽  
Aerosol Ot ◽  
Triton X

Effects of Water Loading on the Fluorescein/Anti-Fluorescein Antibody System in Aerosol-OT Reverse Micelles Formed in n-Heptane

1998 ◽  
Vol 52 (1) ◽  
pp. 96-100
Author(s):  
Jeffrey S. Lundgren ◽  
A. Neal Watkins ◽  
Frank V. Bright
Keyword(s):  
Binding Site ◽  
Reverse Micelle ◽  
Reverse Micelles ◽  
Site Structure ◽  
Water Loading ◽  
Aerosol Ot ◽  
Aot Reverse Micelles ◽  
Charge Disproportionation

We report on the behavior of monoclonal 4-4-20 mouse anti-fluorescein antibodies sequestered within aerosol-OT (AOT) reverse micelles formed in liquid n-heptane as a function of water loading ( R). Our data suggest that the fluorescein binding site structure is unaffected by R. However, we note that there is a region, at intermediate R values, where the fluorescein apparently binds even more strongly to the monoclonal anti-fluorescein antibodies compared to the native antibody in solution. These results are qualitatively explained in terms of the Ruckenstein–Karpe model, which is based on charge disproportionation and redistribution within the reverse micelle. The results demonstrate that R, within an AOT reverse micelle, influences the apparent anti-fluorescein affinity.

Small-Angle X-Ray Scattering and Near-Infrared Vibrational Spectroscopy of Water Confined in Aerosol-OT Reverse Micelles

ChemPhysChem ◽  
2008 ◽  
Vol 9 (18) ◽  
pp. 2794-2801 ◽  
Author(s):  
Sangeetha Balakrishnan ◽  
Nadeem Javid ◽  
Hermann Weingärtner ◽  
Roland Winter
Keyword(s):  
Vibrational Spectroscopy ◽  
Small Angle ◽  
Reverse Micelles ◽  
Near Infrared ◽  
X Ray ◽  
Aerosol Ot ◽  
X Ray Scattering ◽  
Ray Scattering

Self-Catalytic Aminolysis of Aerosol-OT in Reverse Micelles by Diamines

1994 ◽  
Vol 164 (2) ◽  
pp. 444-451 ◽  
Author(s):  
Kazuo Tajima ◽  
Yoko Imai ◽  
Akio Nakamura ◽  
Masakatsu Koshinuma
Keyword(s):  
Reverse Micelles ◽  
Aerosol Ot
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