scholarly journals Highly Loaded Mildly Edge‐Oxidized Graphene Nanosheet Dispersions for Large‐Scale Inkjet Printing of Electrochemical Sensors

2020 ◽  
Vol 7 (2) ◽  
pp. 460-468
Author(s):  
Bhawna Nagar ◽  
Milica Jović ◽  
Victor Costa Bassetto ◽  
Yingdi Zhu ◽  
Horst Pick ◽  
...  
Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1753 ◽  
Author(s):  
Nikita Nekrasov ◽  
Dmitry Kireev ◽  
Nejra Omerović ◽  
Aleksei Emelianov ◽  
Ivan Bobrinetskiy

In this work, we report a novel method of maskless doping of a graphene channel in a field-effect transistor configuration by local inkjet printing of organic semiconducting molecules. The graphene-based transistor was fabricated via large-scale technology, allowing for upscaling electronic device fabrication and lowering the device’s cost. The altering of the functionalization of graphene was performed through local inkjet printing of N,N′-Dihexyl-3,4,9,10-perylenedicarboximide (PDI-C6) semiconducting molecules’ ink. We demonstrated the high resolution (about 50 µm) and accurate printing of organic ink on bare chemical vapor deposited (CVD) graphene. PDI-C6 forms nanocrystals onto the graphene’s surface and transfers charges via π–π stacking to graphene. While the doping from organic molecules was compensated by oxygen molecules under normal conditions, we demonstrated the photoinduced current generation at the PDI-C6/graphene junction with ambient light, a 470 nm diode, and 532 nm laser sources. The local (in the scale of 1 µm) photoresponse of 0.5 A/W was demonstrated at a low laser power density. The methods we developed open the way for local functionalization of an on-chip array of graphene by inkjet printing of different semiconducting organic molecules for photonics and electronics.


Author(s):  
Stuart I. Benton ◽  
Chiara Bernardini ◽  
Jeffrey P. Bons ◽  
Rolf Sondergaard

Efforts to reduce blade count and avoid boundary layer separation have led to low-pressure turbine airfoils with significant increases in loading as well as front-loaded pressure distributions. These features have been independently shown to increase losses within the secondary flow field at the endwall. Compound angle blowing from discrete jets on the blade suction surface near the endwall has been shown to be effective in reducing these increased losses and enabling the efficient use of highly loaded blade designs. In this study, experiments are performed on the front loaded L2F low-pressure turbine airfoil in a linear cascade. The required mass flow is reduced by decreasing hole count from previous configurations and from the introduction of unsteady blowing. The effects of pulsing frequency and duty cycle are investigated using phase-locked stereo particle image velocimetry to demonstrate the large scale movement and hysteresis behavior of the passage vortex interacting with the pulsed jets. Total pressure loss contours at the cascade outlet demonstrate that the efficiency benefit is maintained with the use of unsteady forcing.


MRS Advances ◽  
2017 ◽  
Vol 2 (60) ◽  
pp. 3691-3696 ◽  
Author(s):  
Jay A. Desai ◽  
Nirmal Adhikari ◽  
Anupama B. Kaul

ABSTRACTIn this work, we demonstrate optical and electrical transport properties of chemically exfoliated WS2 in cyclohexanone/ terpineol solvent using different sonication times. High electrical conductivity of WS2 nanodispersions was observed when appropriate amount of voltage was applied indicating their semi-conductive behavior. Surface morphology of WS2 nanodispersions sonicated at different times were studied using optical microscopy. Optical bandgap of WS2 nanodispersions were determined from optical absorbance spectrum. Inkjet printing was used to demonstrate uniform distribution of WS2 nanosheets and their precise and large scale printability. These dispersions indicate the potential of WS2 in various optoelectronic and semiconducting device applications.


Author(s):  
Benjamin Winhart ◽  
Martin Sinkwitz ◽  
Andreas Schramm ◽  
Pascal Post ◽  
Francesca di Mare

Abstract In the proposed paper the transient interaction between periodic incoming wakes and the laminar separation bubble located on the rear suction surface of a typical, highly loaded LPT blade is investigated by means of highly resolved large-eddy simulations. An annular, large scale, 1.5-stage LPT test-rig, equipped with a modified T106 turbine blading and an upstream rotating vortex generator is considered and the numerical predictions are compared against hot film array measurements. In order to accurately assess both baseline transition and wake impact, simulations were conducted with unperturbed and periodically perturbed inflow conditions. Main mechanisms of transition and wake-boundary layer interaction are investigated utilizing a frequency-time domain analysis. Finally visualizations of the main flow structures and shear layer instabilities are provided utilizing the q-criterion as well as the finite-time Lyapunov exponent.


Author(s):  
Zahra Saki ◽  
Mahdi Malekshahi Byranvand ◽  
Nima Taghavinia ◽  
Mayank Kedia ◽  
Michael Saliba

This review explores perovskite crystallization in scalable deposition techniques, including blade, slot-die, spray coating, and inkjet printing.


2008 ◽  
Vol 57 (7) ◽  
pp. 1001-1007 ◽  
Author(s):  
D. Braun ◽  
W. Gujer

The hydraulic characteristics of aeration tanks in WWTPs have a major impact on the degradation of pollutants, as well as on the control of the aeration. In particular in long reactors, which are not separated by baffles, hydraulic shortcuts or large scale recirculation can lead to a loss of performance. This work demonstrates that reactive tracers such as ammonium and oxygen can be used to investigate the hydraulics of aeration tanks in detail. With the use of electrochemical sensors it is possible to investigate effects in a broad range of time scales. In the present case study a slow oscillation of the aeration control loop was investigated. Large scale recirculation in the aeration tank and fast fluctuations of the ammonium concentrations close to the oxygen sensor were identified as the cause of these oscillations. Both, the recirculation as well as the fluctuation of the ammonium have a substantial influence on the performance of the aeration tank and the aeration control loop.


Chemosensors ◽  
2019 ◽  
Vol 7 (1) ◽  
pp. 8 ◽  
Author(s):  
Giulio Rosati ◽  
Arianna Cunego ◽  
Fabio Fracchetti ◽  
Antonio Del Casale ◽  
Matteo Scaramuzza ◽  
...  

Bacteriophages are responsible for significant material and time losses in the dairy industry. This because these viruses infect the selected lactic starter cultures used for milk fermentation, i.e., the first stage toward cheese production. Standard detection techniques are time- and labor-consuming, causing huge costs related to production plant sanitation and product wasting. A new type of biosensor for early detection of bacteriophage contamination is highly demanded by the milk processing market, and inkjet-printed electrochemical sensors could be the answer. Inkjet printing is a well-known technology that has been revisited in recent years, using silver nanoparticle (AgNP) based inks for low-cost and easy fabrication of sensing and biosensing systems on flexible and eco-compatible substrates. In this research, we studied inkjet printing for the manufacturing of both interdigitated electrodes arrays (IDEAs), and a versatile system to monitor bacterial cultures by electrochemical impedance spectroscopy (EIS). In particular, we studied this biosensing system for the detection of bacteriophages by comparing its performance with standard microbiological methods. We performed electrical and morphological characterizations of the devices produced with a consumer-use inkjet printer with commercial AgNPs ink on flexible substrates, such as office paper, polyethylene (PET), and photo paper. We used light microscopy optical analysis, profilometry, atomic force microscopy (AFM), and scanning electron microscopy (SEM) imaging to define the objects resolution, their real dimensions, and thickness. We also investigated the devices’ conductivity and layout, by EIS measurements with a standard buffer solution, i.e., phosphate buffered saline (PBS). Finally, we tested our system by monitoring Lactococcus lactis cultures and bacteriophage infection. We compared the results to those obtained by two standard microbiological methods in terms of response time, proving that our technique requires less than half the time of other methods and no specialized personnel.


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