Realizing the Commercial Potential of Hierarchical Zeolites: New Opportunities in Catalytic Cracking

ChemCatChem ◽  
2013 ◽  
Vol 6 (1) ◽  
pp. 46-66 ◽  
Author(s):  
Kunhao Li ◽  
Julia Valla ◽  
Javier Garcia-Martinez
Keyword(s):  
Catalytic Cracking ◽  
Hierarchical Zeolites ◽  
Commercial Potential

Hierarchical zeolites obtained by alkaline treatment for enhanced n-pentane catalytic cracking

Fuel ◽  
2021 ◽  
pp. 122669
Author(s):  
Zijian Wang ◽  
Rongxin Zhang ◽  
Jieguang Wang ◽  
Zhongwei Yu ◽  
Yanjuan Xiang ◽  
...  
Keyword(s):  
Catalytic Cracking ◽  
Alkaline Treatment ◽  
Hierarchical Zeolites

Exploring the impact of synthetic strategies on catalytic cracking in hierarchical beta zeolites via hydrothermal desilication and organosilane-templated synthesis

2020 ◽  
Vol 10 (14) ◽  
pp. 4602-4611 ◽  
Author(s):  
Ke Zhang ◽  
Sergio Fernandez ◽  
Elisha S. Converse ◽  
Sarah Kobaslija
Keyword(s):  
Catalytic Cracking ◽  
Catalytic Properties ◽  
Hierarchical Zeolites ◽  
Templated Synthesis ◽  
Beta Zeolites ◽  
The Creation ◽  
The Impact ◽  
Hierarchical Beta

Hierarchical zeolites can be synthesized by different strategies, resulting in the creation of mesoporosity with different configurations (inter-crystalline or intra-crystalline) in addition to unique porous and catalytic properties.

Catalytic cracking of large molecules over hierarchical zeolites

2006 ◽  
pp. 1769 ◽  
Author(s):  
Qian Lei ◽  
Tianbo Zhao ◽  
Fengyan Li ◽  
Lingling Zhang ◽  
Yue Wang
Keyword(s):  
Catalytic Cracking ◽  
Hierarchical Zeolites ◽  
Large Molecules

Fluidized Catalytic Cracking Catalyst Microstructure as Determined by A Scanning Ion Microprobe

1990 ◽  
Vol 48 (2) ◽  
pp. 302-303
Author(s):  
J.K. Lampert ◽  
G.S. Koermer ◽  
J.M. Macaoy ◽  
J.M. Chabala ◽  
R. Levi-Setti
Keyword(s):  
Catalytic Cracking ◽  
Secondary Ion Mass Spectrometry ◽  
Fuel Oil ◽  
Ion Microprobe ◽  
Fluidized Catalytic Cracking ◽  
Ion Probe ◽  
Silica Alumina ◽  
Resolution Imaging ◽  
The University ◽  
High Spatial Resolution Imaging

We have used high spatial resolution imaging secondary ion mass spectrometry (SIMS) to differentiate mineralogical phases and to investigate chemical segregations in fluidized catalytic cracking (FCC) catalyst particles. The oil industry relies on heterogeneous catalysis using these catalysts to convert heavy hydrocarbon fractions into high quality gasoline and fuel oil components. Catalyst performance is strongly influenced by catalyst microstructure and composition, with different chemical reactions occurring at specific types of sites within the particle. The zeolitic portions of the particle, where the majority of the oil conversion occurs, can be clearly distinguished from the surrounding silica-alumina matrix in analytical SIMS images.The University of Chicago scanning ion microprobe (SIM) employed in this study has been described previously. For these analyses, the instrument was operated with a 40 keV, 10 pA Ga+ primary ion probe focused to a 30 nm FWHM spot. Elemental SIMS maps were obtained from 10×10 μm2 areas in times not exceeding 524s.

An analytical microscopic study of metals in fluidized catalytic cracking catalyst

1986 ◽  
Vol 44 ◽  
pp. 854-855
Author(s):  
Clifford S. Rainey
Keyword(s):  
Electron Microscopy ◽  
Spatial Distribution ◽  
Catalytic Cracking ◽  
Catalyst Deactivation ◽  
Coke Formation ◽  
Acid Sites ◽  
Y Zeolite ◽  
Fcc Catalyst ◽  
Fluidized Catalytic Cracking ◽  
High Regeneration

The spatial distribution of V and Ni deposited within fluidized catalytic cracking (FCC) catalyst is studied because these metals contribute to catalyst deactivation. Y zeolite in FCC microspheres are high SiO2 aluminosilicates with molecular-sized channels that contain a mixture of lanthanoids. They must withstand high regeneration temperatures and retain acid sites needed for cracking of hydrocarbons, a process essential for efficient gasoline production. Zeolite in combination with V to form vanadates, or less diffusion in the channels due to coke formation, may deactivate catalyst. Other factors such as metal "skins", microsphere sintering, and attrition may also be involved. SEM of FCC fracture surfaces, AEM of Y zeolite, and electron microscopy of this work are developed to better understand and minimize catalyst deactivation.

CATALYTIC CRACKING OF PALM OIL: KINETIC STUDY

Clean Air ◽  
2007 ◽  
Vol 8 (1) ◽  
pp. 65-79 ◽  
Author(s):  
Farouq Twaiq ◽  
Abdul Rahman Mohamed ◽  
Subhash Bhatia
Keyword(s):  
Kinetic Study ◽  
Palm Oil ◽  
Catalytic Cracking
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