Chemiluminescence determination of gemifloxacin based on diperiodatoargentate (III)‐sulphuric acid reaction in a micellar medium

Luminescence ◽  
2012 ◽  
Vol 28 (2) ◽  
pp. 108-113 ◽  
Author(s):  
Fang Zhao ◽  
Wen‐hui Zhao ◽  
Wei Xiong
Keyword(s):  
Sulphuric Acid ◽  
Micellar Medium ◽  
Acid Reaction

Vibration-spectral studies of compounds formed by the combination of methylformamide and dimethylformamide with some strong acids

1966 ◽  
Vol 19 (11) ◽  
pp. 2091 ◽  
Author(s):  
E Spinner
Keyword(s):  
Hydrochloric Acid ◽  
Sulphuric Acid ◽  
Infrared Spectra ◽  
Spectral Studies ◽  
Ionic Form ◽  
Reaction Products ◽  
Unknown Structure ◽  
Acid Reaction ◽  
Strong Acids

A determination of the infrared spectra of the solid hydrochlorides of methylformamide and dimethylformamide and of the Raman spectra of their aqueous solutions showed that certain spectral features change with the medium used. The infrared spectra of the two amides in concentrated and in aqueous sulphuric acid, and in concentrated hydrochloric acid (HCl and DCl), are consistent with the existence of two amide/acid reaction products for each amide: one (certainly ionic) form predominates in sulphuric acid solutions; a second form, of unknown structure, is present in the solid hydrochlorides, and in hydrochloric acid the two forms coexist in equilibrium.

scholarly journals Modelling and Multi-Objective Optimization of the Sulphur Dioxide Oxidation Process

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1072
Author(s):  
Mohammad Reza Zaker ◽  
Clémence Fauteux-Lefebvre ◽  
Jules Thibault
Keyword(s):  
Sulphuric Acid ◽  
Sulphur Dioxide ◽  
Variable Number ◽  
Inlet Temperature ◽  
Multi Objective Optimization ◽  
Absorption Column ◽  
Maximum Reaction Rate ◽  
Multi Objective ◽  
Maximum Reaction

Sulphuric acid (H2SO4) is one of the most produced chemicals in the world. The critical step of the sulphuric acid production is the oxidation of sulphur dioxide (SO2) to sulphur trioxide (SO3) which takes place in a multi catalytic bed reactor. In this study, a representative kinetic rate equation was rigorously selected to develop a mathematical model to perform the multi-objective optimization (MOO) of the reactor. The objectives of the MOO were the SO2 conversion, SO3 productivity, and catalyst weight, whereas the decisions variables were the inlet temperature and the length of each catalytic bed. MOO studies were performed for various design scenarios involving a variable number of catalytic beds and different reactor configurations. The MOO process was mainly comprised of two steps: (1) the determination of Pareto domain via the determination a large number of non-dominated solutions, and (2) the ranking of the Pareto-optimal solutions based on preferences of a decision maker. Results show that a reactor comprised of four catalytic beds with an intermediate absorption column provides higher SO2 conversion, marginally superior to four catalytic beds without an intermediate SO3 absorption column. Both scenarios are close to the ideal optimum, where the reactor temperature would be adjusted to always be at the maximum reaction rate. Results clearly highlight the compromise existing between conversion, productivity and catalyst weight.

VI. The glucoside constitution of proteid matter

1894 ◽  
Vol 54 (326-330) ◽  
pp. 53-57 ◽  
Keyword(s):  
Sulphuric Acid ◽  
Cupric Oxide ◽  
The Body ◽  
Long Time

For a long time I have adopted a process for separating the glycogen of the liver consisting in boiling with potash, pouring into alcohol, and collecting the precipitate. For the purpose of estimation, the precipitated glycogen was converted by means of sulphuric acid into glucose, the determination of which gave the information required. I afterwards applied the process to blood, and the various organs and tissues of the body, with the result that a more or less notable amount of cupric oxide reducing product was obtained, which I at the time looked upon as taking origin, as in the case of the liver, from glycogen.

scholarly journals The Development of a New Kinetic Spectrophotometric Method for the Determination of Vanadium(V) Based on its Catalytic Effect on the Oxidation of Malachite Green Oxalate by Bromate in Acidic and Micellar Medium

2010 ◽  
Vol 7 (4) ◽  
pp. 1612-1620 ◽  
Author(s):  
M. Keyvanfard ◽  
N. Abedi
Keyword(s):  
Malachite Green ◽  
Spectrophotometric Method ◽  
Catalytic Effect ◽  
Limit Of Detection ◽  
Fixed Time ◽  
Micellar Medium ◽  
Relative Standard ◽  
Kinetic Spectrophotometric ◽  
Malachite Green Oxalate

A new, simple, sensitive and selective kinetic spectrophotometric method was developed for the determination of ultra trace amounts of vanadium(V). The method is based on the catalytic effect of vanadium(V) on the oxidation of malachite green oxalate (MG) by bromate in acidic and micellar medium. The reaction was monitored spectrophotometrically by measuring the decrease in the absorbance of malachite green oxalate (MG) at 625 nm with a fixed-time method. The decrease in the absorbance of MG is proportional to the concentration of vanadium(V) in the range of 1-100 ng/mL with a fixed time of 0.5-2 min from the initiation of the reaction. The limit of detection is 0.71 ng/mL of vanadium(V). The relative standard deviation for the determination of 5, 30, 50 ng/mL of vanadium(V) was2.5% 2.6%, 2.4% and respectively. The method was applied to the determination of vanadium(V) in water samples.

NEW COLOR REACTIONS OF SEDOHEPTULOSAN AND ITS DETERMINATION IN MIXTURES OF RIBOSE AND FRUCTOSE

1954 ◽  
Vol 32 (1) ◽  
pp. 14-18 ◽  
Author(s):  
L. Ujejski ◽  
E. R. Waygood
Keyword(s):  
Sulphuric Acid ◽  
Colorimetric Determination ◽  
Pure Solution ◽  
Naturally Occurring ◽  
Cysteine Hydrochloride ◽  
Color Reactions

The reagents carbazole – sulphuric acid, cysteine hydrochloride – sulphuric acid, have been applied successfully to the quantitative colorimetric determination of sedoheptulosan in pure solution or in the presence of ribose and/or fructose. Fructose can be determined quantitatively in the presence of sedoheptulosan and/or ribose by using a combination of the two reagents. Results indicate that while sedoheptulose reacts differently to sedoheptulosan with the orcinol reagent, the reactions with carbazole and cysteine are not altered by hydration and these may form a basis for the determination of the naturally occurring seven carbon sugar sedoheptulose.

scholarly journals Determination of Sodium Cromoglycate by a New Kinetic Spectrophotometric Method in Biological Samples

2013 ◽  
Vol 2013 ◽  
pp. 1-5
Author(s):  
Mohsen Keyvanfard ◽  
Khadijeh Alizad ◽  
Razieh Shakeri
Keyword(s):  
Standard Deviation ◽  
Sodium Cromoglycate ◽  
Spectrophotometric Method ◽  
Calibration Curve ◽  
Biological Samples ◽  
Limit Of Detection ◽  
Micellar Medium ◽  
Relative Standard ◽  
Kinetic Spectrophotometric

A new kinetic spectrophotometric method is described for the determination of ultratrace amounts of sodium cromoglycate (SCG). The method based on catalytic action of SCG on the oxidation of amaranth with periodate in acidic and micellar medium. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of the amaranth at 518 nm, for the first 4 min from initiation of the reaction. Calibration curve was linear in the range of 4.0−36.0 ng mL−1SCG. The limit of detection is 2.7 ng mL−1SCG. The relative standard deviation (RSD) for ten replicate analyses of 12, 20, and 28 ng mL−1SCG was 0.40%, 0.32%, and 0.53%, respectively. The proposed method was used for the determination of SCG in biological samples.

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