Chemical Fixation of CO2 Under Solvent and Co-Catalyst-free Conditions Using a Highly Porous Two-fold Interpenetrated Cu(II)-Metal–Organic Framework

2021 ◽  
Author(s):  
Sandeep Singh Dhankhar ◽  
Rajesh Das ◽  
Bharat Ugale ◽  
Renjith S. Pillai ◽  
C. M. Nagaraja
Keyword(s):  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Co Catalyst ◽  
Catalyst Free ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

2018 ◽  
Vol 54 (4) ◽  
pp. 342-345 ◽  
Author(s):  
Jun Liang ◽  
Ya-Qiang Xie ◽  
Xu-Sheng Wang ◽  
Qiang Wang ◽  
Tao-Tao Liu ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Cyclic Carbonate ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A mesoporous cationic Cr-based metal–organic framework (MOF), FJI-C10, has been obtained and exhibited excellent performances in chemical fixation of CO2 into cyclic carbonates under co-catalyst free and mild conditions.

A tri-functional metal–organic framework heterogeneous catalyst for efficient conversion of CO2 under mild and co-catalyst free conditions

2019 ◽  
Vol 55 (95) ◽  
pp. 14347-14350 ◽  
Author(s):  
Dingxuan Ma ◽  
Yaowen Zhang ◽  
Shaoshao Jiao ◽  
Jixin Li ◽  
Kang Liu ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Heterogeneous Catalyst ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
Catalytic Performance ◽  
Co Catalyst ◽  
Efficient Conversion ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A novel tri-functional MOF catalyst was achieved by PSM method. Because of the synergistic effect of Lewis acid, Brønsted acid and Br− anion, MIL-IMAc-Br− displayed an efficient catalytic performance for CO2 conversion.

scholarly journals Co-catalyst free ethene dimerization over Zr-based metal-organic framework (UiO-67) functionalized with Ni and bipyridine

2020 ◽  
Author(s):  
Mustafa Kømurcu ◽  
Andrea Lazzarini ◽  
Gurpreet Kaur ◽  
Elisa Borfecchia ◽  
Sigurd Øien-Ødegaard ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Co Catalyst ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

Design and synthesis of a new magnetic metal organic framework as a versatile platform for immobilization of acidic catalysts and CO2 fixation reaction

2021 ◽  
Author(s):  
Faezeh Taghavi ◽  
Amir Khojastehnezhad ◽  
Reza Khalifeh ◽  
Maryam Rajabzadeh ◽  
Fahimeh Rezaei ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
Chemical Fixation ◽  
Design And Synthesis ◽  
Acidic Catalysts ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Fixation Reaction ◽  
Organic Framework

The first report of the use of an acidic magnetic metal organic framework for the chemical fixation of CO2 as an environmentally friendly reaction.

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

A New Multi-Functional Cu(II)-Organic Framework as a Platform for Selective Carbon Dioxide Chemical Fixation and Separation of Organic Dyes

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yang-Tian Yan ◽  
Chen-Yang Wang ◽  
Li-Na Zheng ◽  
Yun-Long Wu ◽  
Jiao Liu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Benzoic Acid ◽  
Organic Dyes ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Acid Ligand ◽  
Metal Organic ◽  
Organic Framework

A new multi-functional metal-organic framework, {[Cu2(HL)(H2O)2]·NMP·2H2O}n (1), was assembled employing a asymmetrical V-shaped rigid multicarboxylic acid ligand H5L (H5L= 2,4-di(2′,5′-dicarboxylphenyl)benzoic acid) with Cu(II) ions. 1 possesses a 3D pore formed...

Quantum Rotations and Chiral Polarization of Qubit Prototype Molecules in a Highly Porous Metal–Organic Framework: 1H NMR T1 Study

2011 ◽  
Vol 115 (42) ◽  
pp. 20460-20465 ◽  
Author(s):  
Svyatoslav P. Gabuda ◽  
Svetlana G. Kozlova ◽  
Denis G. Samsonenko ◽  
Danil N. Dybtsev ◽  
Vladimir P. Fedin
Keyword(s):  
1H Nmr ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
1H Nmr T1 ◽  
Highly Porous ◽  
Organic Framework

A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9348 ◽  
Author(s):  
Zhiyong Lu ◽  
Liting Du ◽  
Baishu Zheng ◽  
Junfeng Bai ◽  
Mingxing Zhang ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Metal Organic Framework ◽  
H2 Adsorption ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

Highly porous metal–organic framework sustained with 12-connected nanoscopic octahedra

2013 ◽  
Vol 42 (5) ◽  
pp. 1708-1714 ◽  
Author(s):  
Weigang Lu ◽  
Daqiang Yuan ◽  
Trevor A. Makal ◽  
Zhangwen Wei ◽  
Jian-Rong Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework
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