scholarly journals Front Cover: Reductive Activation of Small Molecules by Anionic Coinage Metal Atoms and Clusters in the Gas Phase (Chem. Asian J. 21/2019)

2019 ◽  
Vol 14 (21) ◽  
pp. 3748-3748
Author(s):  
Satoru Muramatsu ◽  
Tatsuya Tsukuda
Keyword(s):  
Small Molecules ◽  
Gas Phase ◽  
Reductive Activation ◽  
Coinage Metal ◽  
Front Cover ◽  
Metal Atoms

Theoretical investigations of the interaction between diatomic molecules and coinage metal atoms

2021 ◽  
pp. e1892224
Author(s):  
Y. Qawasmeh ◽  
K. Töpfer ◽  
T. Serwatka ◽  
J. C. Tremblay ◽  
B. Paulus
Keyword(s):  
Diatomic Molecules ◽  
Coinage Metal ◽  
Metal Atoms ◽  
Theoretical Investigations

Computational UV Spectra for Amorphous Solids of Small Molecules

2021 ◽  
Author(s):  
Austin Michael Wallace ◽  
Ryan C. Fortenberry
Keyword(s):  
Carbon Dioxide ◽  
Interstellar Medium ◽  
Small Molecules ◽  
Gas Phase ◽  
Amorphous Solids ◽  
Uv Spectra ◽  
Ammonia Water ◽  
Gas Phase Molecules ◽  
High Level

Ices in the interstellar medium largely exist as amorphous solids composed of small molecules including ammonia, water, and carbon dioxide. Describing gas-phase molecules can be readily accomplished with current high-level...

scholarly journals Front Cover: Laser Spectroscopy and Lifetime Measurements of the S 1 State of Tetracyanoquinodimethane (TCNQ) in a Cold Gas‐Phase Free‐Jet (ChemPhysChem 8/2019)

ChemPhysChem ◽  
2019 ◽  
Vol 20 (8) ◽  
pp. 993-993
Author(s):  
Nobumasa Chaki ◽  
Satoru Muramatsu ◽  
Yuji Iida ◽  
Seiya Kenjo ◽  
Yoshiya Inokuchi ◽  
...  
Keyword(s):  
Gas Phase ◽  
Laser Spectroscopy ◽  
Lifetime Measurements ◽  
Front Cover ◽  
Free Jet ◽  
Cold Gas

scholarly journals Front Cover: The Synthesis and Optoelectronic Applications for Tellurophene‐Based Small Molecules and Polymers (ChemPhysChem 20/2019)

ChemPhysChem ◽  
2019 ◽  
Vol 20 (20) ◽  
pp. 2577-2577
Author(s):  
Xiaoxi Wu ◽  
Lei Lv ◽  
Lifang Hu ◽  
Qinqin Shi ◽  
Aidong Peng ◽  
...  
Keyword(s):  
Small Molecules ◽  
Front Cover ◽  
Optoelectronic Applications

Mechanism of Chromium Deposition from Cr(CO)6 by Uv Laser Light

1989 ◽  
Vol 158 ◽  
Author(s):  
R. Nowak ◽  
P. Hess
Keyword(s):  
Gas Phase ◽  
Metal Film ◽  
Film Growth ◽  
Laser Light ◽  
Film Deposition ◽  
Uv Laser ◽  
Impurity Incorporation ◽  
Metal Atoms ◽  
Chromium Films ◽  
Main Growth

ABSTRACTThe mechanism of metal film deposition from carbonyls as precursors is discussed in detail. It is shown that different species produced by UV laser irradiation in the gas phase contribute to film growth. Highly reactive species such as metal atoms may be important during the nucleation phase, whereas more stable carbonyls are responsible for the main growth process. This indicates that the main decarbonylation effect occurs at the surface. The higher level of impurity incorporation in chromium films in comparison with nickel films is explained by the relative position of the Fermi level in the d-band of Ni and Cr with respect to the 2π* level of CO, which favors CO bond dissociation in the case of chromium.

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