Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes

2016 ◽  
Vol 11 (22) ◽  
pp. 3148-3158 ◽  
Author(s):  
Giorgio Olivo ◽  
Olaf Cussó ◽  
Miquel Costas
Keyword(s):  
Hydrogen Peroxide ◽  
Coordination Complexes ◽  
Biologically Inspired ◽  
Iron Coordination

scholarly journals A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides

2017 ◽  
Vol 8 (5) ◽  
pp. 3660-3667 ◽  
Author(s):  
Olaf Cussó ◽  
Michael W. Giuliano ◽  
Xavi Ribas ◽  
Scott J. Miller ◽  
Miquel Costas
Keyword(s):  
Hydrogen Peroxide ◽  
Coordination Complexes ◽  
Asymmetric Epoxidation ◽  
Coordination Complex ◽  
High Yield ◽  
Aqueous Hydrogen Peroxide ◽  
Bottom Up ◽  
Iron Coordination

The combination of peptides and a chiral iron coordination complex catalyzes high yield highly asymmetric epoxidation with aqueous hydrogen peroxide.

Catalytic behaviour of a novel Fe(iii) Schiff base complex in the mild oxidation of cyclohexane

2015 ◽  
Vol 5 (3) ◽  
pp. 1801-1812 ◽  
Author(s):  
Dmytro S. Nesterov ◽  
Oksana V. Nesterova ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Hydrogen Peroxide ◽  
Schiff Base ◽  
Coordination Compound ◽  
Schiff Base Complex ◽  
Mild Oxidation ◽  
Coordination Environment ◽  
Base Complex ◽  
Catalytic Behaviour ◽  
Iron Coordination

An iron coordination compound, possessing an unsaturated coordination environment, has been prepared by reaction of FeCl3 with a polydentate Schiff base revealing a complex catalytic behaviour in the mild oxidation of cyclohexane by hydrogen peroxide.

scholarly journals Prochelators triggered by hydrogen peroxide provide hexadentate iron coordination to impede oxidative stress

2011 ◽  
Vol 105 (9) ◽  
pp. 1161-1172 ◽  
Author(s):  
Marina G.D. Leed ◽  
Natalie Wolkow ◽  
David M. Pham ◽  
Catherine L. Daniel ◽  
Joshua L. Dunaief ◽  
...  
Keyword(s):  
Oxidative Stress ◽  
Hydrogen Peroxide ◽  
Iron Coordination

scholarly journals Tracking excited-state charge and spin dynamics in iron coordination complexes

Nature ◽  
2014 ◽  
Vol 509 (7500) ◽  
pp. 345-348 ◽  
Author(s):  
Wenkai Zhang ◽  
Roberto Alonso-Mori ◽  
Uwe Bergmann ◽  
Christian Bressler ◽  
Matthieu Chollet ◽  
...  
Keyword(s):  
Excited State ◽  
Spin Dynamics ◽  
Coordination Complexes ◽  
Iron Coordination ◽  
State Charge

scholarly journals Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites

2018 ◽  
Vol 141 (1) ◽  
pp. 323-333 ◽  
Author(s):  
Zoel Codolà ◽  
Ilaria Gamba ◽  
Ferran Acuña-Parés ◽  
Carla Casadevall ◽  
Martin Clémancey ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Coordination Complexes ◽  
Oxidation Catalysts ◽  
Highly Active ◽  
Iron Coordination

pH Dependence of Heme Iron Coordination, Hydrogen Peroxide Reactivity, and Cyanide Binding in CytochromecPeroxidase(H52K)†

Biochemistry ◽  
2004 ◽  
Vol 43 (17) ◽  
pp. 5065-5072 ◽  
Author(s):  
Miriam C. Foshay ◽  
Lidia B. Vitello ◽  
James E. Erman
Keyword(s):  
Hydrogen Peroxide ◽  
Ph Dependence ◽  
Heme Iron ◽  
Cyanide Binding ◽  
Iron Coordination

scholarly journals Biologically inspired oxidation catalysis using metallopeptides

2018 ◽  
Vol 47 (6) ◽  
pp. 1755-1763 ◽  
Author(s):  
Laia Vicens ◽  
Miquel Costas
Keyword(s):  
High Efficiency ◽  
Coordination Complexes ◽  
Oxidation Catalysis ◽  
Metal Coordination ◽  
Oxidation Reactions ◽  
Biologically Inspired ◽  
Promising Strategy ◽  
Oxidation Of Hydrocarbons

Metalloenzymes can catalyze the oxidation of hydrocarbons with high efficiency and selectivity. For this reason, they are taken as inspiration for the development of new catalyst. A promising strategy is the combination of metal coordination complexes and peptide chains. The use of metallopeptides in oxidation reactions is discussed.

Sign in / Sign up

Export Citation Format

Share Document