Artificial muscle like behavior of polypyrrole polyethylene oxide independent of applied potential ranges

2021 ◽  
pp. 52039
Author(s):  
Rudolf Kiefer ◽  
Quoc Bao Le ◽  
Bharath Kumar Velmurugan ◽  
Toribio F. Otero
Keyword(s):  
Polyethylene Oxide ◽  
Artificial Muscle ◽  
Applied Potential

Structures Formed by Cryoprotective Agents Used in Freezc-Etching

1971 ◽  
Vol 29 ◽  
pp. 448-449
Author(s):  
G. G. Cocks ◽  
C. E. Cluthe
Keyword(s):  
Aqueous Solution ◽  
Polyethylene Oxide ◽  
Liquid Nitrogen Temperature ◽  
Ice Crystals ◽  
Etching Technique ◽  
Structural Constituent ◽  
Cryoprotective Agents ◽  
Quick Freezing ◽  
Freeze Etching ◽  
Fractured Surface

The freeze etching technique is potentially useful for examining dilute solutions or suspensions of macromolecular materials. Quick freezing of aqueous solutions in Freon or propane at or near liquid nitrogen temperature produces relatively large ice crystals and these crystals may damage the structures to be examined. Cryoprotective agents may reduce damage to the specimem, hut their use often results in the formation of a different set of specimem artifacts.In a study of the structure of polyethylene oxide gels glycerol and sucrose were used as cryoprotective agents. The experiments reported here show some of the structures which can appear when these cryoprotective agents are used.Figure 1 shows a fractured surface of a frozen 25% aqueous solution of sucrose. The branches of dendritic ice crystals surrounded hy ice-sucrose eutectic can be seen. When this fractured surface is etched the ice in the dendrites sublimes giving the type of structure shown in Figure 2. The ice-sucrose eutectic etches much more slowly. It is the smooth continuous structural constituent surrounding the branches of the dendrites.

Dynamic Analysis Method for Electromagnetic Artificial Muscle Actuator under PID Control

2011 ◽  
Vol 131 (2) ◽  
pp. 166-170 ◽  
Author(s):  
Yoshihiro Nakata ◽  
Hiroshi Ishiguro ◽  
Katsuhiro Hirata
Keyword(s):  
Dynamic Analysis ◽  
Pid Control ◽  
Artificial Muscle ◽  
Analysis Method

Harnessing Applied Potential: The Anti-Markovnikov Hydrocarboxylation of Substituted Olefins

2019 ◽  
Author(s):  
Anas Alkayal ◽  
Volodymyr Tabas ◽  
Andrei V. Malkov ◽  
Benjamin Buckley
Keyword(s):  
Carboxylic Acid ◽  
Applied Potential ◽  
Markovnikov Addition

<div>The construction of carboxylic acid compounds in a selective fashion, from low value materials such as alkenes remains a long-standing challenge to synthetic chemists. In particular, anti-Markovnikov addition to styrenes are underdeveloped. Herein we report a new electrosynthetic approach to the selective hydrocarboxylation of substituted alkenes.</div>

Harnessing Applied Potential: The Anti-Markovnikov Hydrocarboxylation of Substituted Olefins

2019 ◽  
Author(s):  
Anas Alkayal ◽  
Volodymyr Tabas ◽  
Andrei V. Malkov ◽  
Benjamin Buckley
Keyword(s):  
Carboxylic Acid ◽  
Applied Potential ◽  
Markovnikov Addition

<div>The construction of carboxylic acid compounds in a selective fashion, from low value materials such as alkenes remains a long-standing challenge to synthetic chemists. In particular, anti-Markovnikov addition to styrenes are underdeveloped. Herein we report a new electrosynthetic approach to the selective hydrocarboxylation of substituted alkenes.</div>

Modeling the Electrical Double Layer to Understand the Reaction Environment in a CO2 Electrocatalytic System

2019 ◽  
Author(s):  
Divya Bohra ◽  
Jehanzeb Chaudhry ◽  
Thomas Burdyny ◽  
Evgeny Pidko ◽  
wilson smith
Keyword(s):  
Electric Field ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Surface Reaction ◽  
Catalyst Surface ◽  
Local Reaction ◽  
Reaction Diffusion ◽  
Alkali Metal Cations ◽  
Applied Potential ◽  
Critical Aspect

<p>The environment of a CO<sub>2</sub> electroreduction (CO<sub>2</sub>ER) catalyst is intimately coupled with the surface reaction energetics and is therefore a critical aspect of the overall system performance. The immediate reaction environment of the electrocatalyst constitutes the electrical double layer (EDL) which extends a few nanometers into the electrolyte and screens the surface charge density. In this study, we resolve the species concentrations and potential profiles in the EDL of a CO<sub>2</sub>ER system by self-consistently solving the migration, diffusion and reaction phenomena using the generalized modified Poisson-Nernst-Planck (GMPNP) equations which include the effect of volume exclusion due to the solvated size of solution species. We demonstrate that the concentration of solvated cations builds at the outer Helmholtz plane (OHP) with increasing applied potential until the steric limit is reached. The formation of the EDL is expected to have important consequences for the transport of the CO<sub>2</sub> molecule to the catalyst surface. The electric field in the EDL diminishes the pH in the first 5 nm from the OHP, with an accumulation of protons and a concomitant depletion of hydroxide ions. This is a considerable departure from the results obtained using reaction-diffusion models where migration is ignored. Finally, we use the GMPNP model to compare the nature of the EDL for different alkali metal cations to show the effect of solvated size and polarization of water on the resultant electric field. Our results establish the significance of the EDL and electrostatic forces in defining the local reaction environment of CO<sub>2</sub> electrocatalysts.</p>

A Pneumatic Artificial Muscle Bionic Kangaroo Leg Suspension

2019 ◽  
Vol 12 (4) ◽  
pp. 357-366
Author(s):  
Yong Song ◽  
Shichuang Liu ◽  
Jiangxuan Che ◽  
Jinyi Lian ◽  
Zhanlong Li ◽  
...  
Keyword(s):  
Strong Shock ◽  
Artificial Muscle ◽  
Suspension System ◽  
Vehicle Body ◽  
Vehicle Suspension ◽  
Pneumatic Artificial Muscle ◽  
Advantages And Disadvantages ◽  
Road Excitation ◽  
Vehicle Suspension System ◽  
Suspension Structure

Background: Vehicles generally travel on different road conditions, and withstand strong shock and vibration. In order to reduce or isolate the strong shock and vibration, it is necessary to propose and develop a high-performance vehicle suspension system. Objective: This study aims to report a pneumatic artificial muscle bionic kangaroo leg suspension to improve the comfort performance of vehicle suspension system. Methods: In summarizing the existing vehicle suspension systems and analyzing their advantages and disadvantages, this paper introduces a new patent of vehicle suspension system based on the excellent damping and buffering performance of kangaroo leg, A Pneumatic Artificial Muscle Bionic Kangaroo Leg Suspension. According to the biomimetic principle, the pneumatic artificial muscles bionic kangaroo leg suspension with equal bone ratio is constructed on the basis of the kangaroo leg crural index, and two working modes (passive and active modes) are designed for the suspension. Moreover, the working principle of the suspension system is introduced, and the rod system equations for the suspension structure are built up. The characteristic simulation model of this bionic suspension is established in Adams, and the vertical performance is analysed. Results: It is found that the largest deformation happens in the bionic heel spring and the largest angle change occurs in the bionic ankle joint under impulse road excitation, which is similar to the dynamic characteristics of kangaroo leg. Furthermore, the dynamic displacement and the acceleration of the vehicle body are both sharply reduced. Conclusion: The simulation results show that the comfort performance of this bionic suspension is excellent under the impulse road excitation, which indicates the bionic suspension structure is feasible and reasonable to be applied to vehicle suspensions.

Chitosan/Polyethylene Oxide (PEO) Filled Carbonized Wood Fiber Conductive Composite Film

2020 ◽  
Vol 1010 ◽  
pp. 638-644
Author(s):  
Mohd Pisal Mohd Hanif ◽  
Abd Jalil Jalilah ◽  
Mohd Fadzil Hanim Anisah ◽  
Arumugam Tilagavathy
Keyword(s):  
Electrical Conductivity ◽  
Tensile Strength ◽  
Polyethylene Oxide ◽  
Biomedical Applications ◽  
Wood Fiber ◽  
Conductive Polymer ◽  
Renewable Resource ◽  
Blend Films ◽  
Conductive Composite Film ◽  
Carbonized Wood

Biopolymer-based conductive polymer composites (CPCs) would open up various possibilities in biomedical applications owing to ease of processing, renewable resource and environmentally friendly. However, low mechanical properties are a major issue for their applications. In this study, the investigated the conductivity of chitosan/ PEO blend films filled with carbonized wood fiber (CWF) prepared by solution casting. The effect of CWF was also investigated on tensile properties and their morphological surfaces. The tensile results from different ratios of chitosan/PEO blend films without CWF show that the tensile strength and modulus increased with the increase of chitosan content and chitosan/PEO blend film with 70/30 ratio exhibited the best combination of tensile strength and flexibility. However, a reduction of tensile strength was observed when CWF amount was increased while the modulus of the tensile shows an increment. The film also exhibited higher electrical conductivity as compared to low chitosan ratio. The addition of CWF greatly enhanced the conductivity three-fold from 10-10 to 10-6 S/cm. The electrical conductivity continued to increase with the increase of CWF up to 30wt%. The surface morphology by Scanning Electron Microscopy (SEM) exhibits the absence of phase separation for the blends indicating good miscibility between the PEO and chitosan. Incorporation of CWF into the blend films at 5wt% showed agglomeration. However, the increase of CWF created larger agglomerations that formed conductive pathways resulting in improved conductivity. FTIR analysis suggested that intermolecular interactions occurred between chitosan and PEO while CWF interacts more with the protons of PEO.

Development of A Small Clamper for Tendon-sheath Artificial Muscle

2018 ◽  
Author(s):  
Qi Zhang ◽  
Xiaopeng Shen ◽  
Xingsong Wang ◽  
Mengqian Tian ◽  
Mingxing Yang ◽  
...  
Keyword(s):  
Artificial Muscle ◽  
Tendon Sheath
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