Amine/epoxy stoichiometric ratio dependence of crosslinked structure and ductility in amine‐cured epoxy thermosetting resins

2021 ◽  
Vol 138 (23) ◽  
pp. 50542
Author(s):  
Nobuyuki Odagiri ◽  
Keiichi Shirasu ◽  
Yoshiaki Kawagoe ◽  
Gota Kikugawa ◽  
Yutaka Oya ◽  
...  
2007 ◽  
Vol 134 ◽  
pp. 329-332 ◽  
Author(s):  
Jennie Macdougall ◽  
Chris Reid ◽  
Larry McGhee

The time and stoichiometric ratio dependence on dissolution of Cu from Cu(I)O and Cu(II)O and metallic Cu was investigated for a series of known Cu chelators. This was monitored by ICP-OES and UV-VIS. A notable difference in the rate of reaction for Cu(I)O vs Cu(II)O was observed and the impact of a copper adduct precipitating from solution discussed as this may present a redeposition issue for Cu surface cleaning. Additionally these chelators were found to selectively favour Cu0 and typically showed higher solution levels of Cu when exposed to the oxides.


Author(s):  
L.E. Murr

The production of void lattices in metals as a result of displacement damage associated with high energy and heavy ion bombardment is now well documented. More recently, Murr has shown that a void lattice can be developed in natural (colored) fluorites observed in the transmission electron microscope. These were the first observations of a void lattice in an irradiated nonmetal, and the first, direct observations of color-center aggregates. Clinard, et al. have also recently observed a void lattice (described as a high density of aligned "pores") in neutron irradiated Al2O3 and Y2O3. In this latter work, itwas pointed out that in order that a cavity be formed,a near-stoichiometric ratio of cation and anion vacancies must aggregate. It was reasoned that two other alternatives to explain the pores were cation metal colloids and highpressure anion gas bubbles.Evans has proposed that void lattices result from the presence of a pre-existing impurity lattice, and predicted that the formation of a void lattice should restrict swelling in irradiated materials because it represents a state of saturation.


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