Preparation of composite anion exchange membranes based on in‐situ copolymerization of N‐vinyl formamide and divinylbenzene in porous PTFE

2020 ◽  
Vol 138 (8) ◽  
pp. 49872
Author(s):  
Wanjie Luo ◽  
Lulu Wang ◽  
Ruijiang Feng ◽  
Chongfeng Zhao ◽  
Jilin Wang ◽  
...  
2017 ◽  
Vol 5 (8) ◽  
pp. 4003-4010 ◽  
Author(s):  
Jiangju Si ◽  
Haining Wang ◽  
Shanfu Lu ◽  
Xin Xu ◽  
Sikan Peng ◽  
...  

By modulating the amphiphilic architectures, 3D well-connected nano-channels are constructed and a trade-off between conductivity and stability in AEMs is achieved.


2016 ◽  
Vol 4 (6) ◽  
pp. 2340-2348 ◽  
Author(s):  
Zhen Li ◽  
Wenyu Wang ◽  
Yijing Chen ◽  
Chuanye Xiong ◽  
Guangwei He ◽  
...  

Construction of ion nanochannels by entrapping an in situ assembled ion-conductive poly(ionic liquid) in the highly ordered interconnected pores of MOFs.


2017 ◽  
Vol 1 (3) ◽  
pp. 583-592 ◽  
Author(s):  
Vaibhavee Bhadja ◽  
Souradeep Chakraborty ◽  
Sandip Pal ◽  
Rakhi Mondal ◽  
B. S. Makwana ◽  
...  

The present article describes the preparation of efficient and stable anion exchange membranes (AEMs) from the inter-polymer of polyethylene and polystyrene-co-polydivinylbenzene.


Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 469
Author(s):  
Elke Herrmann ◽  
Nico Dingenouts ◽  
Christina Roth ◽  
Frieder Scheiba ◽  
Helmut Ehrenberg

Commercially available anion exchange membranes were retrieved from VRFB field tests and their degradation due to the various operation conditions is analyzed by in-situ and ex-situ measurements. Ion exchange capacity, permeability and swelling power are used as direct criteria for irreversible changes. Small-angle X-ray scattering (SAXS) and Differential scanning calorimetry (DSC) analyses are used as fingerprint methods and provide information about the morphology and change of the structural properties. A decrease in crystallinity can be detected due to membrane degradation, and, in addition, an indication of reduced polymer chain length is found. While the proton diffusion either increase or decline significantly, the ion exchange capacity and swelling power both are reduced. The observed extent of changes was in good agreement with in-situ measurements in a test cell, where the coulombic and voltage efficiencies are reduced compared to a pristine reference material due to the degradation process.


2011 ◽  
Vol 36 (11) ◽  
pp. 1521-1557 ◽  
Author(s):  
Guillaume Couture ◽  
Ali Alaaeddine ◽  
Frédéric Boschet ◽  
Bruno Ameduri

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