Combined effect of relative humidity and temperature on dynamic viscoelastic properties and glass transition of poly(vinyl alcohol)

2013 ◽  
Vol 130 (5) ◽  
pp. 3161-3167 ◽  
Author(s):  
Hongjiu Hu ◽  
Xiaolong Zhang ◽  
Yaolong He ◽  
Zhan-sheng Guo ◽  
Junqian Zhang ◽  
...  
Polymer ◽  
1994 ◽  
Vol 35 (14) ◽  
pp. 3122-3126 ◽  
Author(s):  
Yingming Yao ◽  
Lizhi Liu ◽  
Hong Li ◽  
Tianru Fang ◽  
Enle Zhou

Langmuir ◽  
2009 ◽  
Vol 25 (15) ◽  
pp. 8656-8662 ◽  
Author(s):  
Emiliano Carretti ◽  
Scilla Grassi ◽  
Manuela Cossalter ◽  
Irene Natali ◽  
Gabriella Caminati ◽  
...  

1992 ◽  
Vol 24 (4) ◽  
pp. 395-404 ◽  
Author(s):  
Masakatsu Yonese ◽  
Kazuhiko Baba ◽  
Hiroshi Kishimoto

2006 ◽  
Vol 39 (19) ◽  
pp. 6537-6545 ◽  
Author(s):  
Suneel Bandi ◽  
David A. Schiraldi

1988 ◽  
Vol 135 ◽  
Author(s):  
Ke-Cheng Gong ◽  
Huang Shou-Cai

AbstractThe electrical properties of poly(vinyl alcohol) complexed with phosphoric acid have been studied. It is found that the conductivity increases with the concentration of the acid, and also increases with time if the sample is exposed to the air, which is interpreted in terms of glass transition temperature. A.C. impedance measurement and polarization experiment show that this proton-conducting polymer is a promising candidate for electrochromic display. It is also found that some plasticizers, such as glycerol and ethylene-glycol are effective for improving its conductivity.


Polymer ◽  
2004 ◽  
Vol 45 (16) ◽  
pp. 5543-5549 ◽  
Author(s):  
Rebeca Hernández ◽  
Aurélie Sarafian ◽  
Daniel López ◽  
Carmen Mijangos

2007 ◽  
Vol 15 (5) ◽  
pp. 371-377
Author(s):  
Kazuma Takeuchi ◽  
Akihiro Kamaguchi ◽  
Muneaki Nabeta ◽  
Syuji Fujii ◽  
Yoshinobu Nakamura ◽  
...  

The effects of the pre-mixing method and degree of saponification poly(vinyl alcohol) (PVA) on the morphology of poly(vinyl chloride) (PVC)/PVA blends were investigated. Two pre-mixing methods were employed: a powder method and an aqueous solution method. In the powder method, both components were blended in powder form before melt kneading using a mixing roll. In the aqueous solution method, the PVC powder was added to an as-prepared PVA aqueous solution, followed by drying and then pounding before melt kneading. In the case of PVA with a degree of saponification of 98 mol%, PVA domains several hundred μm across were dispersed in the PVC matrix in the powder method system, whereas finer PVA domains with sizes ranging from sub μm to several μm were observed in the aqueous solution method. In the cases of PVA with saponification degrees of 88 and 78 mol%, domain sizes of several tens of μm were observed for both powder and solution methods. This indicates that there was no apparent influence of pre-mixing method on the domain size. When poly(methyl methacrylate) (PMMA) was added to the PVC/PVA blend, smaller PVA domains (with sizes ranging from 5 to 10 μm) were observed in both powder and solution method systems than without the PMMA. Viscoelastic properties showed specific interactions between PVC and PMMA, and between PMMA and PVA.


2015 ◽  
Vol 26 (6) ◽  
pp. 4198-4201 ◽  
Author(s):  
Bruno B. Cunha ◽  
Márcia W. C. C. Greenshields ◽  
Messai A. Mamo ◽  
Neil J. Coville ◽  
Ivo A. Hümmelgen

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