High dielectric constant polyaniline/sulfonated poly(aryl ether ketone) composite membranes with good thermal and mechanical properties

2013 ◽  
Vol 130 (3) ◽  
pp. 1990-1995 ◽  
Author(s):  
Yunhe Zhang ◽  
Pengfei Huo ◽  
Xiao Liu ◽  
Changru Rong ◽  
Guibin Wang
Keyword(s):  
Mechanical Properties ◽  
Dielectric Constant ◽  
High Dielectric Constant ◽  
Composite Membranes ◽  
Thermal And Mechanical Properties ◽  
Aryl Ether ◽  
Aryl Ether Ketone ◽  
Ether Ketone ◽  
High Dielectric ◽  
Sulfonated Poly

The preparation of novel sulfonated poly(aryl ether ketone sulfone)/TiO2 composite membranes with low methanol permeability for direct methanol fuel cells

2020 ◽  
pp. 095400832095804
Author(s):  
Chengyun Yuan ◽  
Yinghan Wang
Keyword(s):  
Sulfonic Acid ◽  
Direct Methanol Fuel Cells ◽  
Composite Membranes ◽  
Methanol Permeability ◽  
Aryl Ether ◽  
Direct Methanol ◽  
Aryl Ether Ketone ◽  
Ether Ketone ◽  
Sulfonic Acid Groups ◽  
Sulfonated Poly

A sulfonated poly(aryl ether ketone sulfone) (SPAEKS) with locally dense sulfonic acid groups is synthesized and different amounts of TiO2 is doped into SPAEKS matrix to prepare composite membranes (SPAEKS/TiO2-x). SEM shows that TiO2 in the composite membranes has good dispersibility when TiO2 content is not higher than 3%. The composite membranes show good mechanical properties, dimensional stability and oxidative stability. The proton conductivity of composite membranes is near to that of Nafion 117 membrane and methanol permeability of composite membranes is much lower than that of Nafion 117 membrane. Therefore, the proton selectivity of composite membranes is higher than that of Nafion 117 membrane. In particular, proton selectivity of SPAEKS/TiO2-3% (12.8 × 104 S s cm−3) is four times higher than that of Nafion 117 membrane (3.2 × 104 S s cm−3).

scholarly journals Improved electromechanical properties of brominated butyl rubber filled with modified barium titanate

RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 37148-37157 ◽  
Author(s):  
Mengnan Ruan ◽  
Dan Yang ◽  
Wenli Guo ◽  
Shuo Huang ◽  
Yibo Wu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dielectric Constant ◽  
Barium Titanate ◽  
High Dielectric Constant ◽  
Dielectric Elastomer ◽  
Butyl Rubber ◽  
Electromechanical Properties ◽  
Brominated Butyl Rubber ◽  
High Dielectric

Barium titanate (BT) particles, BT-KH570 particles, and polar plasticizer tri-n-butyl phosphate (TBP) were added into BIIR matrix to form a dielectric elastomer composite, which had a high dielectric constant, good mechanical properties, and large actuated strain.

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