Preparation of acrylic acid grafted polypropylene nonwoven fabric by photoinduced graft polymerization with preabsorption of monomer solution

2009 ◽  
Vol 114 (1) ◽  
pp. 387-397 ◽  
Author(s):  
Choon-Ki Na ◽  
Hyun-Ju Park
1995 ◽  
Vol 55 (13) ◽  
pp. 1707-1723 ◽  
Author(s):  
Mathias Ulbricht ◽  
Annett Oechel ◽  
Claudia Lehmann ◽  
Georg Tomaschewski ◽  
Hans-Georg Hicke

2014 ◽  
Vol 94 ◽  
pp. 129-132 ◽  
Author(s):  
Hanzhou Liu ◽  
Ming Yu ◽  
Hongjuan Ma ◽  
Ziqiang Wang ◽  
Linfan Li ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2028
Author(s):  
Shin-ichi Sawada ◽  
Yasunari Maekawa

We prepared novel bipolar membranes (BPMs) consisting of cation and anion exchange layers (CEL and AEL) using radiation-induced asymmetric graft polymerization (RIAGP). In this technique, graft polymers containing cation and anion exchange groups were introduced into a base film from each side. To create a clear CEL/AEL boundary, grafting reactions were performed from each surface side using two graft monomer solutions, which are immiscible in each other. Sodium p-styrenesulfonate (SSS) and acrylic acid (AA) in water were co-grafted from one side of the base ethylene-co-tetrafluoroethylene film, and chloromethyl styrene (CMS) in xylene was simultaneously grafted from the other side, and then the CMS units were quaternized to afford a BPM. The distinct SSS + AA- and CMS-grafted layers were formed owing to the immiscibility of hydrophilic SSS + AA and hydrophobic CMS monomer solutions. This is the first BPM with a clear CEL/AEL boundary prepared by RIAGP. However, in this BPM, the CEL was considerably thinner than the AEL, which may be a problem in practical applications. Then, by using different starting times of the first SSS+AA and second CMS grafting reactions, the CEL and AEL thicknesses was found to be controlled in RIAGP.


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