Gas-phase photoinduced graft polymerization of acrylic acid onto polyacrylonitrile ultrafiltration membranes

1995 ◽  
Vol 55 (13) ◽  
pp. 1707-1723 ◽  
Author(s):  
Mathias Ulbricht ◽  
Annett Oechel ◽  
Claudia Lehmann ◽  
Georg Tomaschewski ◽  
Hans-Georg Hicke
Keyword(s):  
Acrylic Acid ◽  
Gas Phase ◽  
Graft Polymerization ◽  
Ultrafiltration Membranes ◽  
Photoinduced Graft Polymerization

The kinetics of radiation graft polymerization of acrylic acid from the gas phase on kaolin

1979 ◽  
Vol 21 (3) ◽  
pp. 555-563 ◽  
Author(s):  
V.A. Polushkin ◽  
A.V. Vlasov ◽  
V.V. Lapin ◽  
B.L. Tsetlin
Keyword(s):  
Acrylic Acid ◽  
Gas Phase ◽  
Graft Polymerization ◽  
Kinetics Of

The kinetics of radiation graft polymerization of acrylic acid from the gas phase on polypropylene fibre

1972 ◽  
Vol 14 (4) ◽  
pp. 835-839
Author(s):  
L.I. Malakhova ◽  
A.V. Vlasov ◽  
N.V. Mikhailov ◽  
B.L. Tsetlin
Keyword(s):  
Acrylic Acid ◽  
Gas Phase ◽  
Graft Polymerization ◽  
Polypropylene Fibre ◽  
Kinetics Of

scholarly journals Radiation-Induced Asymmetric Grafting of Different Monomers into Base Films to Prepare Novel Bipolar Membranes

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2028
Author(s):  
Shin-ichi Sawada ◽  
Yasunari Maekawa
Keyword(s):  
Acrylic Acid ◽  
Anion Exchange ◽  
Graft Polymerization ◽  
The Other ◽  
Practical Applications ◽  
Bipolar Membranes ◽  
Graft Polymers ◽  
Grafting Reactions ◽  
Radiation Induced

We prepared novel bipolar membranes (BPMs) consisting of cation and anion exchange layers (CEL and AEL) using radiation-induced asymmetric graft polymerization (RIAGP). In this technique, graft polymers containing cation and anion exchange groups were introduced into a base film from each side. To create a clear CEL/AEL boundary, grafting reactions were performed from each surface side using two graft monomer solutions, which are immiscible in each other. Sodium p-styrenesulfonate (SSS) and acrylic acid (AA) in water were co-grafted from one side of the base ethylene-co-tetrafluoroethylene film, and chloromethyl styrene (CMS) in xylene was simultaneously grafted from the other side, and then the CMS units were quaternized to afford a BPM. The distinct SSS + AA- and CMS-grafted layers were formed owing to the immiscibility of hydrophilic SSS + AA and hydrophobic CMS monomer solutions. This is the first BPM with a clear CEL/AEL boundary prepared by RIAGP. However, in this BPM, the CEL was considerably thinner than the AEL, which may be a problem in practical applications. Then, by using different starting times of the first SSS+AA and second CMS grafting reactions, the CEL and AEL thicknesses was found to be controlled in RIAGP.

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