Reactive extrusion for the synthesis of nylon 12 and maleated low-density polyethylene blends via the anionic ring-opening polymerization of lauryllactam

2009 ◽  
Vol 114 (5) ◽  
pp. 2662-2672 ◽  
Author(s):  
Libo Du ◽  
Guisheng Yang
Keyword(s):  
Ring Opening ◽  
Reactive Extrusion ◽  
Ring Opening Polymerization ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Polyethylene Blends ◽  
Nylon 12 ◽  
Anionic Ring

scholarly journals Enhanced Tensile Properties of Multi-Walled Carbon Nanotubes Filled Polyamide 6 Composites Based on Interface Modification and Reactive Extrusion

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 997
Author(s):  
Min Park ◽  
Ji-un Jang ◽  
Jong Hyuk Park ◽  
Jaesang Yu ◽  
Seong Yun Kim
Keyword(s):  
Carbon Nanotubes ◽  
Tensile Properties ◽  
Ring Opening ◽  
Reactive Extrusion ◽  
Polyamide 6 ◽  
Ring Opening Polymerization ◽  
Uniform Dispersion ◽  
Multi Walled Carbon Nanotubes ◽  
Anionic Ring ◽  
Walled Carbon Nanotubes

To induce uniform dispersion and excellent interfacial properties, we adopted a strategy of combining both polyamide 6 (PA6) grafting for multi-walled carbon nanotubes (MWCNTs) and reactive extrusion of PA6 matrix, based on anionic ring-opening polymerization of ε-caprolactam (CL). Compared to –COOH and –NCO treatments of MWCNTs, enhanced MWCNT dispersion and tensile properties of the composites were achieved using the applied strategy, and the tensile strength and modulus of the PA6-grafted MWCNT-filled PA6 composites were 5.3% and 20.5% higher than those of the purified MWCNT-filled PA6 composites, respectively. In addition, they were almost similar to the theoretical ones calculated by the modified Mori–Tanaka method (MTM) assuming a perfect interface, indicating that the tensile properties of MWCNT-filled PA6 composites can be optimized by PA6 grafting and reactive extrusion based on the anionic ring-opening polymerization of CL due to uniform MWCNT dispersion and excellent interfacial property.

scholarly journals Development of Inherently Flame—Retardant Phosphorylated PLA by Combination of Ring-Opening Polymerization and Reactive Extrusion

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 13 ◽  
Author(s):  
Rosica Mincheva ◽  
Hazar Guemiza ◽  
Chaimaa Hidan ◽  
Sébastien Moins ◽  
Olivier Coulembier ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Ring Opening ◽  
Coupling Reaction ◽  
Reactive Extrusion ◽  
Ring Opening Polymerization ◽  
Hexamethylene Diisocyanate ◽  
Cone Calorimetry ◽  
Loss Cone ◽  
Ul 94

In this study, a highly efficient flame-retardant bioplastic poly(lactide) was developed by covalently incorporating flame-retardant DOPO, that is, 9,10-dihydro-oxa-10-phosphaphenanthrene-10-oxide. To that end, a three-step strategy that combines the catalyzed ring-opening polymerization (ROP) of L,L-lactide (L,L-LA) in bulk from a pre-synthesized DOPO-diamine initiator, followed by bulk chain-coupling reaction by reactive extrusion of the so-obtained phosphorylated polylactide (PLA) oligomers (DOPO-PLA) with hexamethylene diisocyanate (HDI), is described. The flame retardancy of the phosphorylated PLA (DOPO-PLA-PU) was investigated by mass loss cone calorimetry and UL-94 tests. As compared with a commercially available PLA matrix, phosphorylated PLA shows superior flame-retardant properties, that is, (i) significant reduction of both the peak of heat release rate (pHRR) and total heat release (THR) by 35% and 36%, respectively, and (ii) V0 classification at UL-94 test. Comparisons between simple physical DOPO-diamine/PLA blends and a DOPO-PLA-PU material were also performed. The results evidenced the superior flame-retardant behavior of phosphorylated PLA obtained by a reactive pathway.

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