ToF-SIMS investigation of epoxy resin curing reaction at different resin to hardener ratios

2008 ◽  
Vol 110 (5) ◽  
pp. 2711-2717 ◽  
Author(s):  
Firas Awaja ◽  
Grant van Riessen ◽  
Georgina Kelly ◽  
Bronwyn Fox ◽  
Paul J. Pigram
2015 ◽  
Vol 53 (18) ◽  
pp. 1324-1332 ◽  
Author(s):  
Mario Martin-Gallego ◽  
Antonio González-Jiménez ◽  
Raquel Verdejo ◽  
Miguel Angel Lopez-Manchado ◽  
Juan Lopez Valentin

2010 ◽  
Vol 010 (8) ◽  
pp. 1016-1022 ◽  
Author(s):  
Li GAN ◽  
Zhijie SUN ◽  
Yizhuo GU ◽  
Min LI ◽  
Zuoguang ZHANG

2017 ◽  
Vol 131 (2) ◽  
pp. 1499-1507 ◽  
Author(s):  
Jiaxun Lyu ◽  
Dongdong Hu ◽  
Tao Liu ◽  
Ling Zhao

2013 ◽  
Vol 634-638 ◽  
pp. 3008-3016
Author(s):  
Yan Li ◽  
Zhi Nan Zhou ◽  
Xiao Yan Xu ◽  
Long Xie

Two Novolac Resins Were Synthesized by the Reaction between Bisphenol A and Benzaldehyde (bis-BENR) or Bisphenol A and P-hydroxybenzaldehyde (bis-PHNR). Fourier Transform Infrared Spectroscopy (FTIR) and Nuclear Magnetic Resonance (NMR) Were Applied to Characterize the Molecular Structure of Bis-BENR (or Bis-PHNR). then the Two Novolac Resins Were Used as Curing Agent for Bisphenol A Type Epoxy Resin (DGEBA). the Curing Reaction and Curing Kinetics Were Studied by Dynamic FTIR and Differential Scanning Calorimetry (DSC). Dynamic FTIR Showed that the Two Novolac Resins Reacted with Epoxy Resins and Formed a Crosslinking Network Structure. DSC Results Show that the Optimum Mass Ratio between DGEBA and Bis-BENR (or Bis-PHNR) Was 7:3, under which the Curing Reaction Processed Completely. the Mechanical Properties and Sulfide Resistance of DGEBA/bis-BENR (or Bis-PHNR) System Were Also Investigated. the Results Showed that when the Mass Ratio between DGEBA and Bis-BENR (or Bis-PHNR) Was 7:3, the Curing Coatings Had Optimum Mechanical Properties and Sulfide Resistance.


AIP Advances ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 115021
Author(s):  
Ying Wu ◽  
Tian Xie ◽  
Wei Xiao ◽  
Wen Cong Zhang ◽  
Wei Quan Ma ◽  
...  

2015 ◽  
Vol 220-221 ◽  
pp. 380-384
Author(s):  
Egidijus Dragašius ◽  
Inga Skiedraite

The article discusses the results of experiments on the further development of the method for monitoring the state of the small samples of resin and polymers during curing. The applied method is based on a change in the structure of oscillating transducers leading to variations in the form and/or mode of oscillation. The thin layer of epoxy resin was placed between two piezoelectric transducers in the form of piezoceramic plates. Curing epoxy resin forms a bimorph and its characteristics change along with variations in viscosity or, after the gel point, stiffness. It is possible to establish the level of epoxy resin curing by monitoring changes in the resonance parameters of bimorph elements. The main purpose of cure monitoring of small samples is to develop a new method for evaluating the parameters of resin both before and after the gel point thus taking into consideration that the use of rheological data measured with reference to small samples will be applied for designing or interpreting bulk-flow processes where epoxy may be considered a continuum.


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