New type of phenolic resin: Curing reaction of phenol-novolac based benzoxazine with bisoxazoline or epoxy resin using latent curing agent and the properties of the cured resin

2009 ◽  
Vol 112 (3) ◽  
pp. 1762-1770 ◽  
Author(s):  
Hajime Kimura ◽  
Akihiro Matsumoto ◽  
Keiko Ohtsuka
Keyword(s):  
Epoxy Resin ◽  
Phenolic Resin ◽  
Curing Agent ◽  
Curing Reaction ◽  
New Type ◽  
Resin Curing

Epoxy resin curing reaction studied by proton multiple-quantum NMR

2015 ◽  
Vol 53 (18) ◽  
pp. 1324-1332 ◽  
Author(s):  
Mario Martin-Gallego ◽  
Antonio González-Jiménez ◽  
Raquel Verdejo ◽  
Miguel Angel Lopez-Manchado ◽  
Juan Lopez Valentin
Keyword(s):  
Epoxy Resin ◽  
Multiple Quantum ◽  
Curing Reaction ◽  
Resin Curing ◽  
Multiple Quantum Nmr

HIGH TECHNIQUE FOR T-PEEL STRENGTH ENHANCEMENT OF Al/AFRP HYBRID COMPOSITE

2006 ◽  
Vol 20 (25n27) ◽  
pp. 4273-4278
Author(s):  
CHEOL-WOONG KIM ◽  
DONG-JOON OH
Keyword(s):  
Tensile Strength ◽  
Epoxy Resin ◽  
Hybrid Composite ◽  
Equivalence Ratio ◽  
Peel Strength ◽  
Aramid Fiber ◽  
Curing Agent ◽  
Mixture Ratio ◽  
Resin Mixture ◽  
Resin Curing

The interlaminar peel strength of Al / AFRP (Aluminum alloy/Aramid Fiber Reinforced Plastic) hybrid composite is affected by the adhesive strength between the Al alloy layer and the aramid fiber layer. The study of the tensile strength and the T-peel strength of the Al / AFRP should be accomplished first. Therefore, this study focused on the effect of the resin mixture ratio as the Al / AFRP on the tensile strength and T-peel strength. In conclusions, the resin mixture ratio by equivalence ratio of 〈epoxy resin : curing agent〉 equal to 〈1:1〉 of Al / AFRP -I and the resin mixture ratio by equivalence ratio of 〈epoxy resin : curing agent : accelerator〉 equal to 〈1:1:0.2〉 of Al / AFRP -II showed the highest ultimate tensile strength. After the T-peel test, it is found that the T-peel strength of Al / AFRP -II is approximately 1.5 times higher than that of Al / AFRP -I. Reviewing the characteristics of the tensile and T-peel strengths, the resin mixture ratio 〈1:1:0.2〉 of Al / AFRP -II showed the highest tensile strength and T-peel strength.

Studies on Mechanical and Thermal Properties of Epoxy Resin Modified by Fluorine-Containing Silicone

2013 ◽  
Vol 401-403 ◽  
pp. 713-716
Author(s):  
Cheng Fang ◽  
Dong Bo Guan ◽  
Wei Guo Yao ◽  
Shou Jun Wang ◽  
Hui An
Keyword(s):  
Glass Transition ◽  
Thermal Properties ◽  
Epoxy Resin ◽  
Bending Strength ◽  
Mechanical And Thermal Properties ◽  
Curing Agent ◽  
Epoxy System ◽  
Resin Curing ◽  
The Impact ◽  
Modified Epoxy

The epoxy resin was modified with the mixture of α,ω-dihydroxy poly-(3,3,3-trifluoropropyl) siloxane (PTFPMS), KH560 and stannous octoate. KH560 can react with PTFPMS and also epoxy resin curing agent. The two reactions were characterized by FI-IR. The modified epoxy resin was characterized by FI-IR. The result showed that fluorine-containing silicone had been successfully introduced into the epoxy system. The mechanical and thermal properties of the modified epoxy resin were analyzed. The results showed that with the increase of PTFPMS the impact strength of epoxy resin increased, hardness and bending strength correspondingly reduced, slight decrease in the glass transition temperature.

Curing study and evaluation of epoxy resin with amine functional chloroaniline acetaldehyde condensate

2015 ◽  
Vol 44 (1) ◽  
pp. 19-25
Author(s):  
T. Maity ◽  
B.C. Samanta
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Epoxy Resin ◽  
Ph Value ◽  
Kinetic Studies ◽  
Diglycidyl Ether ◽  
Curing Agent ◽  
Scanning Calorimetry ◽  
Content Type ◽  
Curing Reaction

Purpose – The purpose of this paper was to check effectiveness of amine functional chloroaniline acetaldehyde condensate (AFCAC) as a new curing agent for diglycidyl ether of bisphenol A (DGEBA) resin. For this purpose, first AFCAC was synthesised, characterised and then curing reaction was carried out. Design/methodology/approach – Equimolecular mixture of AFCAC and DGEBA was subjected to curing reaction, and the reaction was followed by differential scanning calorimetry (DSC) analysis. The kinetic studies of this curing reaction were also carried out from those DSC exotherms. The mechanical properties, dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) of cured epoxy were also reported. Findings – DSC results reflected the effective first order curing reaction of AFCAC with epoxy resin. Mechanical properties reflected appreciable rigidity of AFCAC cured epoxy matrix and TGA showed that the cured epoxy networks were thermally stable up to around 297°C. Research limitations/implications – The curing agent AFCAC was synthesised by using chloroaniline and acetaldehyde in acid medium. There are some limitations for this procedure. The synthetic procedure is pH dependent. So reaction cannot be done at any pH value. The reaction must also be carried out at room temperature without any heating. To obtain low molecular weight curing agent, chloroaniline and acetaldehyde cannot be taken in equimolecular ratio because the equimolecular mixture of them produces high molecular weight condensate. This was shown in our previous publication. Some implications are also there. By changing amine and aldehyde other curing agents could be synthesised and the curing efficiency of those for epoxy resin could also be studied. Originality/value – Experimental results revealed the greater suitability of AFCAC as curing agent for DGEBA resin and novelty of AFCAC cured matrix in the field of protective coating, casting, adhesives, etc.

Research on Synthesis and Properties of a Flexible Epoxy Curing Agent

2015 ◽  
Vol 744-746 ◽  
pp. 1463-1466
Author(s):  
Xi Wang
Keyword(s):  
Fracture Toughness ◽  
Impact Toughness ◽  
Epoxy Resin ◽  
Curing Agent ◽  
Pure Epoxy ◽  
Epoxy Curing ◽  
New Type ◽  
The Impact

This paper presents the synthesis of a new type of flexible epoxy curing agent and an approach to improve the toughness of epoxy resin by curing without reducing the strength and modulus of the resin-cured material. The results show that the degree of toughness reaches maximum values when the flexible curing agent is applied at weight percentages (wt.%) between 10% and 15%. When the amount of flexible curing agent added to epoxy resin weight is 10wt.%, the impact toughness and fracture toughness increases by 33.3% and 96.3%, respectively, compared with the pure epoxy resin. When the amount of flexible curing agent added to epoxy is 10wt.%, the resulting impact thoughness of the material is 19.5 kJ•m-2 at-50°C, the impact toughness of pure epoxy resin is only 7.96 kJ•m-2.

Study on the Preparation of 2-Phenyl Imidazole Microcapsule and its Effect on Curing Epoxy Resin

2013 ◽  
Vol 690-693 ◽  
pp. 1649-1652
Author(s):  
Ai Jie Ma ◽  
Qiu Yu Zhang ◽  
You Qiang Shi
Keyword(s):  
Epoxy Resin ◽  
Raw Materials ◽  
Curing Kinetics ◽  
Curing Temperature ◽  
Curing Agent ◽  
Thermal Analyzer ◽  
Epoxy Resin System ◽  
Curing Kinetic ◽  
Resin Curing ◽  
Micro Morphology

In this paper, 2-phenyl imidazole (2-PZ) microcapsule-type curing agent of epoxy resin were prepared through solvent volatilization with 2-PZ and polymethyl acrylic glycidyl ester (PGMA) as the raw materials. The micro-morphology, shape and structure of the microcapsules were studied by scanning electronic microscope (SEM) and fourier transform infrared spectrum (FT-IR). The curing kinetics of microcapsule curing agent/epoxy resin E-44 curing system were studied using TGA/DSC simultaneous thermal analyzer. Results showed that the preparation method is simple and effective and the prepared 2-PZ microcapsules have smooth surfaces and monodisperse size. And the curing kinetic study of epoxy resin system suggested epoxy resin curing temperature was rising with the increase of heating rate.

scholarly journals EPOXY RESIN CURING REACTION STUDIED BY DYNAMIC AND ISOTHERMAL MODEL FREE KINETICS

2010 ◽  
Vol 010 (8) ◽  
pp. 1016-1022 ◽  
Author(s):  
Li GAN ◽  
Zhijie SUN ◽  
Yizhuo GU ◽  
Min LI ◽  
Zuoguang ZHANG
Keyword(s):  
Epoxy Resin ◽  
Isothermal Model ◽  
Curing Reaction ◽  
Model Free ◽  
Model Free Kinetics ◽  
Resin Curing

Preparation of waterborne P-N containing epoxy resin curing and its performances

2016 ◽  
Vol 45 (5) ◽  
pp. 308-312 ◽  
Author(s):  
Wei Li ◽  
Guilong Xu ◽  
Buqin Xu ◽  
Yi Wang ◽  
Jin Yang ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Curing Agent ◽  
Flame Resistance ◽  
Pencil Hardness ◽  
Content Type ◽  
Coating Industry ◽  
Epoxy Curing ◽  
Resin Curing

Purpose The flammability of epoxy resin is a major disadvantage in applications that require flame resistance. Epoxy monomers and hardeners containing flame-retardant elements are molecularly incorporated in the resin network are expected to exhibit better flame resistance than those borne on an additive approach. In recent years, because of health and environmental regulation, the use of waterborne coatings has received many attentions. However, waterborne epoxy resin curing agent with excellent flame retardancy has been seldom reported. The paper aims to study the preparation of waterborne P-N-containing epoxy resin curing agent and its performances (P-N – phosphorous and nitrogen). Design/methodology/approach Waterborne P-N-containing epoxy curing agent was prepared in this study using reactive flame retardant 10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-xa-10-phosphaphenanthrene-10-oxide, liquid epoxy resin, triethylenetetramine and butyl glycidyl ether at the mole ratio of 1.0:2.0:2.0:2.0. Findings The results show that the epoxy thermoset from the prepared P-N-containing curing agent presents good flame retardancy and can pass the V-1 rating, and the cured epoxy thermoset film presents excellent performances such as water resistance, adhesion, impact resistance and pencil hardness. This study provides useful suggestions for the application of the water-borne flame retardancy epoxy resins in coating industry. Research limitations/implications Each step of products during the preparation of waterborne P-N-containing epoxy curing agent cannot be accurately tested. Originality/value This method for synthesis of waterborne P-N-containing epoxy curing agent is novel and could be used for various applications in epoxy coating industry.

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